Resins for use as coating material and process for preparing same

Claim 2

Resins suitable for use as a coating material, consisting essentially of an esterified copolymer of (1) a copolymer of (i) at least one cyclopentadiene compound selected from the group consisting of cyclopentadiene, dicyclopentadiene, tricyclopentadiene, tetracyclopentadiene and lower alkyl substitution products thereof wherein the lower alkyl has 1-3 carbon atoms and (ii) at least one α, β-unsaturated monomer selected from the group consisting of hydroxyalkyl acrylate, hydroxyalkyl methacrylate, glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether and methallyl glycidyl ether and (2) at least one of acrylic and methacrylic acids.

Claim 3

Resins according to claim 1, wherein the copolymer (1) has a softening point of 50°-200° C. and the esterified copolymer has a softening point of 30°-150° C.

Claim 4

Resins according to claim 1, wherein the hydroxyalkyl of the hydroxyalkyl acrylate and methacrylate is 2-hydroxyethyl or 2-hydroxypropyl.

Claim 5

Resins suitable for use as a coating material, consisting essentially of (A) an esterified copolymer of (1) a copolymer of (i) at least one cyclopentadiene compound selected from the group consisting of cyclopentadiene, dicyclopentadiene, tricyclopentadiene, tetracyclopentadiene and lower alkyl substitution products thereof wherein the lower alkyl has 1-3 carbon atoms and (ii) at least one α,β-unsaturated monomer selected from the group consisting of hydroxyalkyl acrylate, hydroxyalkyl methacrylate, glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether and methallyl glycidyl ether and (2) at least one of acrylic and methacrylic acids and (B) at least one reactive solvent.

Claim 6

Resins suitable for use as a coating material, consisting essentially of (A) an esterified copolymer of (1) a copolymer of (i) at least one cyclopentadiene compound selected from the group consisting of cyclopentadiene, dicyclopentadiene, tricyclopentadiene, tetracyclopentadiene and lower alkyl substitution products thereof wherein the lower alkyl has 1-3 carbon atoms and (ii) at least one α,β-unsaturated monomer selected from the group consisting of hydroxyalkyl acrylate, hydroxyalkyl methacrylate, glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether and methallyl glycidyl ether and (2) at least one of acrylic and methacrylic acids and (B) at least one reactive solvent.

Claim 7

Resins according to claim 4, wherein the reactive solvent is a member selected from the group consisting of pentaerithritol tetra(meth)acrylate, pentaerithritol tri(meth)acrylate, trimethylolpropane tri(meth)acrylate, ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, 1,3-butanediol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, 1,2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, an alkyl (meth)acrylate in which the alkyl is a C 1 -C 18 one, and glycidyl (meth)acrylate.

Claim 8

Resins according to claim 5, wherein the hydroxyalkyl of the hydroxyalkyl acrylate and methacrylate is 2-hydroxyl or 2-hydroxypropyl.

Claim 9

A process for preparing a resin suitable for use as a coating material, comprising the steps of: reacting a cyclopentadiene compound selected from the group consisting of cyclopentadiene, dicyclopentadiene, tricyclopentadiene, tetracyclopentadiene and lower alkyl substitution products thereof wherein the lower alkyl has 1-3 carbon atoms with an α,β-unsaturated monomer selected from the group consisting of hydroxyalkyl acrylate, hydroxyalkyl methacrylate, glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether and methallyl glycidyl ether in molar ratios of from 30:70 to 95 : 5 at 150°-350° C. in the presence or absence of a known radical catalyst and/or a solvent for a time sufficient to produce a copolymer having a softening point of 50°-200° C., and esterifying the thus produced copolymer resin with at least one of acrylic acid and methacrylic acid in amount of at least 0.5-1 mol of the acid per mol equivalent of the carboxyl or epoxy group of the copolymer in the presence or absence of a known esterifying catalyst thereby to prepare an esterified copolymer having a softening point of 30°-150° C. for use as the resinous coating material.

Claim 10

A process for preparing a resin suitable for use as a coating material, comprising the steps of: reacting a cyclopentadiene compound selected from the group consisting of cyclopentadiene, dicyclopentadiene, tricyclopentadiene, tetracyclopentadiene and lower alkyl substitution products thereof wherein the lower alkyl has 1-3 carbon atoms with an α,β-unsaturated monomer selected from the group consisting of hydroxyalkyl acrylate, hydroxyalkyl methacrylate, glycidyl acrylate, glycidyl methacrylate, allyl glycidyl ether and methallyl glycidyl ether in molar ratios of from 30:70 to 95 : 5 at 150°-350° C. in the presence or absence of a known radical catalyst and/or a solvent for a time sufficient to produce a copolymer having a softening point of 50°-200° C., and esterifying the thus produced copolymer resin with at least one of acrylic acid and methacrylic acid in amount of at least 0.5-1 mol of the acid per mol equivalent of the carboxyl or epoxy group of the copolymer in the presence or absence of a known esterifying catalyst thereby to prepare an esterified copolymer having a softening point of 30°-150° C. for use as the resinous coating material.

Claim 11

A process according to claim 7, wherein the hydroxyalkyl of the hydroxyalkyl acrylate and methacrylate is 2-hydroxyethyl or hydroxypropyl.

Claim 12

A process according to claim 7, wherein the esterifying reaction is effected in the presence of at least one additional reactant selected from the group consisting of higher fatty acids and rosin.