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US4036825A Expired / Lapsed US ⏱️ 0.0 years remaining

Monoazo reactive dyestuffs

Assignee: Hoechst AG
•
Filing: 1976-10-07
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Granted: 1977-07-19
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Expires: 1996-10-07
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Abstract

Abstract Fiber-reactive monoazo dyestuffs which, in form of free acids, correspond to the general formula ##STR1## in which Z represents one of the groupings --CH.sub.2 --CH.sub.2 --OSO.sub.3 H or --CH=CH.sub.2 a stands for benzene, naphthalene or pyrazole unsubstituted or substituted by alkyl, alkoxy or by a phenyl group which is unsubstituted or may be substituted by alkyl, alkoxy, hydroxy, cyano, nitro, sulfonic acid, sulfonic acid amide, carboxylic acid amide, chlorine, bromine, carboxylic acid, acetylamino, benzoylamino, trifluoromethyl, carbalkoxy, B-sulfatoethylsulfonyl or vinylsulfonyl, and wherein, if A represents a benzene or naphthalene radical the azo group and the amino group of the formula --NR 1 R 2 standing in ortho or para position to each other, and if A is pyrazole, the group --NR 1 R 2 is standing in 5-position and the azo group in 4-position of the pyrazole, R 1 and R 2 are different or the same and each stand for hydrogen or alkyl which may be substituted by chlorine, hydroxy, cyano, alkanoyloxy, benzoyloxy, nitrobenzoyloxy, chlorobenzoyloxy, phenyl or phenyl substituted by alkyl, alkoxy, alkyl-sulfone, sulfonic acid, sulfonic acid amide, carboxylic acid amide, nitro, trifluoromethyl, chlorine or bromine, which are suitable for the dyeing and printing of native and regenerated cellulose fibers, but especially advantageous for dyeing or printing fibers or fabrics of nitrogen - containing fibers of native or synthetic origin.

Inventors

  • 👤 Hermann Fuchs
  • 👤 Fritz Meininger

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 12:57
CPC Classifications
C; C09; C09B; C09B62/00; C09B62/44; C09B62/503; C09B62/507; C09B62/51

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 127 words
A monoazo dyestuff in the free acid form of the formula ##STR33## wherein Z is --CH 2 --CH 2 --OSO 3 H or --CH=CH 2 , A is phenylene, naphthylene or either phenylene or naphthylene substituted by hydroxy, sulfonic acid, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen, acetylamino, carboxylic acid, carboxylic acid amide, sulfonic acid amide, benzoylamino or trifluoromethyl, the azo and the --NR 1 R 2 groups being in ortho- or para- position to each other on A, and R 1 and R 2 each is hydrogen, alkyl of 1 to 4 carbon atoms, alkyl of 1 to 4 carbon atoms substituted by hydroxy, cyano, acetoxy, benzoyloxy or phenyl, phenyl or phenyl substituted by halogen or lower alkyl.
Claim 2
Dependent Claim 127 words
A monoazo dyestuff in the free acid form of the formula ##STR33## wherein Z is --CH 2 --CH 2 --OSO 3 H or --CH=CH 2 , A is phenylene, naphthylene or either phenylene or naphthylene substituted by hydroxy, sulfonic acid, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, halogen, acetylamino, carboxylic acid, carboxylic acid amide, sulfonic acid amide, benzoylamino or trifluoromethyl, the azo and the --NR 1 R 2 groups being in ortho- or para- position to each other on A, and R 1 and R 2 each is hydrogen, alkyl of 1 to 4 carbon atoms, alkyl of 1 to 4 carbon atoms substituted by hydroxy, cyano, acetoxy, benzoyloxy or phenyl, phenyl or phenyl substituted by halogen or lower alkyl.
Claim 3
Dependent Claim 39 words
A dyestuff according to claim 1 of the formula ##STR34## wherein R is hydrogen, methyl, methoxy, ethyl, ethoxy or chlorine, and R 1 and R 2 each is hydrogen, methyl, ethyl, propyl, butyl, hydroxyethyl, hydroxypropyl, cyanoethyl, acetoxyethyl or phenyl.
Claim 4
Dependent Claim 40 words
A dyestuff according to claim 1 of the formula ##STR35## wherein Naphth is naphthylene, R' is hydrogen, hydroxy, methyl or sulfo, R" is hydrogen or sulfo, and R 1 and R 2 each is hydrogen, methyl, ethyl, phenyl or tolyl.
Claim 5
Dependent Claim 11 words
A dyestuff as claimed in claim 1 having the formula ##STR36##
Claim 6
Dependent Claim 11 words
A dyestuff as claimed in claim 1 having the formula ##STR37##
Claim 7
Dependent Claim 11 words
A dyestuff as claimed in claim 1 having the formula ##STR38##
Claim 8
Dependent Claim 11 words
A dyestuff as claimed in claim 1 having the formula ##STR39##
Claim 9
Dependent Claim 11 words
A dyestuff as claimed in claim 1 having the formula ##STR40##

References Cited (Backward Citations)

US2973351A Cited
US3126368A Cited
US3413280A Cited
US3637648A Cited
US3360524A Cited
US3435023A Cited
GB1166913A Cited
US3642765A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-18 1981-01-17 1981-07-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-18 1985-01-17 1985-07-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-18 1989-01-17 1989-07-19 $7700.00 Window Closed / Lapsed

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