US4035527A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method of providing a phototropic layer on a carrier
Assignee: American Optical Corp
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Filing: 1974-11-29
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Granted: 1977-07-12
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Expires: 1994-11-29
Abstract
Abstract A laminated optical or ophthalmic element is produced comprised of an amorphous and/or crystalline material possessing phototropic or photochromic properties as a result of applying a thin layer over at least one surface thereof, which layer includes a combination of cations and anions including silver or copper bromide and/or chloride.
Inventors
- 👤 Emil W. Deeg
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 20:33
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/32; C03C4/00; C03C4/04; C03C4/06; G; G02; G02C; G02C7/00; G02C7/10; G02C7/102; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/905
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
154 words
That method of rendering at least one major surface of an optical or ophthalmic organic or inorganic lens phototropic comprised of the steps: (a) preparing a clean lens surface to be treated; (b) preparing a liquid temporary-carrier of a stable solution of a mixture of silicon containing metal organic compound and a metal organic compound containing boron and phosphorous with nitric acid and copper nitrate and silver nitrate, said mixture being pyrolyzable to form a glassy matrix comprising SiO 2 , P 2 O 5 , and B 2 O 3 and mixtures thereof for the phototropic material to be placed on the lens; (c) exposing the said clean lens surface to said temporary-carrier and phototropic-layer-forming material under conditions capable of depositing a thin, hard, scratch-resistant glass layer over said lens surface, said layer having substantially uniformly distributed therewith color centers which, when subjected to ultraviolet or shortwave visible light exhibit reversible absorption thereof.
Claim 2
Dependent Claim
154 words
That method of rendering at least one major surface of an optical or ophthalmic organic or inorganic lens phototropic comprised of the steps: (a) preparing a clean lens surface to be treated; (b) preparing a liquid temporary-carrier of a stable solution of a mixture of silicon containing metal organic compound and a metal organic compound containing boron and phosphorous with nitric acid and copper nitrate and silver nitrate, said mixture being pyrolyzable to form a glassy matrix comprising SiO 2 , P 2 O 5 , and B 2 O 3 and mixtures thereof for the phototropic material to be placed on the lens; (c) exposing the said clean lens surface to said temporary-carrier and phototropic-layer-forming material under conditions capable of depositing a thin, hard, scratch-resistant glass layer over said lens surface, said layer having substantially uniformly distributed therewith color centers which, when subjected to ultraviolet or shortwave visible light exhibit reversible absorption thereof.
Claim 3
Dependent Claim
48 words
The method of claim 1 wherein said temporary-carrier is the solution of: 13 volume parts of ethanol 4 volume parts of butanol 1 volume part of 40% HNO 3 2 volume parts of tetra-ethyl-ortho-silicate 1 volume part of 0.1 molar aqueous solution of copper nitrate and silver nitrate.
Claim 4
Dependent Claim
31 words
The method of claim 1 including the step of exposing said lens coated with said temporary-carrier and ingredients for forming a phototropic layer to a halogen to form said phototropic layer.
Claim 5
Dependent Claim
21 words
The method of claim 1 wherein said layer is hardened in a furnace having a halogen atmosphere at an elevated temperature.
References Cited (Backward Citations)
US3208860A
Cited
US3875321A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-07-11 | 1981-01-10 | 1981-07-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-07-11 | 1985-01-10 | 1985-07-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-07-11 | 1989-01-10 | 1989-07-12 | $7700.00 | Window Closed / Lapsed |