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US4035527A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of providing a phototropic layer on a carrier

Assignee: American Optical Corp
•
Filing: 1974-11-29
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Granted: 1977-07-12
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Expires: 1994-11-29
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Abstract

Abstract A laminated optical or ophthalmic element is produced comprised of an amorphous and/or crystalline material possessing phototropic or photochromic properties as a result of applying a thin layer over at least one surface thereof, which layer includes a combination of cations and anions including silver or copper bromide and/or chloride.

Inventors

  • 👤 Emil W. Deeg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 20:33
CPC Classifications
C; C03; C03C; C03C3/00; C03C3/32; C03C4/00; C03C4/04; C03C4/06; G; G02; G02C; G02C7/00; G02C7/10; G02C7/102; Y; Y10; Y10S; Y10S501/00; Y10S501/90; Y10S501/905

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 154 words
That method of rendering at least one major surface of an optical or ophthalmic organic or inorganic lens phototropic comprised of the steps: (a) preparing a clean lens surface to be treated; (b) preparing a liquid temporary-carrier of a stable solution of a mixture of silicon containing metal organic compound and a metal organic compound containing boron and phosphorous with nitric acid and copper nitrate and silver nitrate, said mixture being pyrolyzable to form a glassy matrix comprising SiO 2 , P 2 O 5 , and B 2 O 3 and mixtures thereof for the phototropic material to be placed on the lens; (c) exposing the said clean lens surface to said temporary-carrier and phototropic-layer-forming material under conditions capable of depositing a thin, hard, scratch-resistant glass layer over said lens surface, said layer having substantially uniformly distributed therewith color centers which, when subjected to ultraviolet or shortwave visible light exhibit reversible absorption thereof.
Claim 2
Dependent Claim 154 words
That method of rendering at least one major surface of an optical or ophthalmic organic or inorganic lens phototropic comprised of the steps: (a) preparing a clean lens surface to be treated; (b) preparing a liquid temporary-carrier of a stable solution of a mixture of silicon containing metal organic compound and a metal organic compound containing boron and phosphorous with nitric acid and copper nitrate and silver nitrate, said mixture being pyrolyzable to form a glassy matrix comprising SiO 2 , P 2 O 5 , and B 2 O 3 and mixtures thereof for the phototropic material to be placed on the lens; (c) exposing the said clean lens surface to said temporary-carrier and phototropic-layer-forming material under conditions capable of depositing a thin, hard, scratch-resistant glass layer over said lens surface, said layer having substantially uniformly distributed therewith color centers which, when subjected to ultraviolet or shortwave visible light exhibit reversible absorption thereof.
Claim 3
Dependent Claim 48 words
The method of claim 1 wherein said temporary-carrier is the solution of: 13 volume parts of ethanol 4 volume parts of butanol 1 volume part of 40% HNO 3 2 volume parts of tetra-ethyl-ortho-silicate 1 volume part of 0.1 molar aqueous solution of copper nitrate and silver nitrate.
Claim 4
Dependent Claim 31 words
The method of claim 1 including the step of exposing said lens coated with said temporary-carrier and ingredients for forming a phototropic layer to a halogen to form said phototropic layer.
Claim 5
Dependent Claim 21 words
The method of claim 1 wherein said layer is hardened in a furnace having a halogen atmosphere at an elevated temperature.

References Cited (Backward Citations)

US3208860A Cited
US3875321A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-11 1981-01-10 1981-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-11 1985-01-10 1985-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-11 1989-01-10 1989-07-12 $7700.00 Window Closed / Lapsed

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