US4035469A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Pretreatment of brine for boron removal
Assignee: Martin Marietta Magnesia Specialties LLC
•
Filing: 1975-12-05
•
Granted: 1977-07-12
•
Expires: 1995-12-05
Abstract
Abstract A process for removing boron contaminant from magnesium halide-containing brine wherein the brine is contacted with active magnesia to precipitate boron-containing magnesium hydrate and to remove at least 50%, and up to at least 95%, by weight of the total boron content of the untreated brine, without reduction of the magnesium halide content of said brine. The active magnesia is employed in an amount of from about 0.1% to about 10% by weight, preferably from about 2% to about 6% by weight, of the untreated brine, which may be heated e.g., from about 140 DEG F to the boiling point thereof, prior to contact with said active magnesia. Subsequently, the treated brine can be used, by reacting it with dolime, to form magnesium hydroxide which, in turn, can be calcined to produce MgO, each of which is a high-purity-low-boron product, i.e., less than 150 ppm boron on an oxide basis, and preferably less than 75 ppm. In addition, the MgO will contain less than 1.5% CaO and can contain, under proper processing conditions, less than 0.8% CaO impurity.
Inventors
- 👤 Alvin Richmond
- 👤 John Francis Bent
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-06 04:33
CPC Classifications
C; C01; C01F; C01F5/00; C01F5/26; C01F5/30; C01F5/02; C01F5/06; C01F5/08
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
208 words
A process for producing, from boron contaminated magnesium halide-containing brine, magnesium hydroxide having a low boron and low-calcium oxide content comprising: (a) contacting the boron contaminated, magnesium halide-containing brine with finely divided active magnesia, which has been formed by light or soft burn calcination of magnesia at a temperature of less than 2700° F. and which is in an amount of from about 0.1% to about 10% by weight based upon the weight of the untreated brine, said brine being at a temperature in the range of from about 32° F. to the boiling point of the mixture of the brine and the activated magnesia, to precipitate boron-containing magnesium hydrate which contains at least 75% by weight of the total boron content of the untreated brine; (b) separating said precipitated boron-containing magnesium hydrate from the remainder of said brine, whereby the boron content of the brine is reduced while not materially reducing the magnesium halide content of the brine; (c) recovering said low boron content brine; and (d) reacting said recovered brine with dolime so as to form magnesium hydroxide, said magnesium hydroxide having a CaO content of less than 1.5% CaO (MgO basis) and a boron content of less than 150 ppm boron on an oxide basis.
Claim 2
Dependent Claim
208 words
A process for producing, from boron contaminated magnesium halide-containing brine, magnesium hydroxide having a low boron and low-calcium oxide content comprising: (a) contacting the boron contaminated, magnesium halide-containing brine with finely divided active magnesia, which has been formed by light or soft burn calcination of magnesia at a temperature of less than 2700° F. and which is in an amount of from about 0.1% to about 10% by weight based upon the weight of the untreated brine, said brine being at a temperature in the range of from about 32° F. to the boiling point of the mixture of the brine and the activated magnesia, to precipitate boron-containing magnesium hydrate which contains at least 75% by weight of the total boron content of the untreated brine; (b) separating said precipitated boron-containing magnesium hydrate from the remainder of said brine, whereby the boron content of the brine is reduced while not materially reducing the magnesium halide content of the brine; (c) recovering said low boron content brine; and (d) reacting said recovered brine with dolime so as to form magnesium hydroxide, said magnesium hydroxide having a CaO content of less than 1.5% CaO (MgO basis) and a boron content of less than 150 ppm boron on an oxide basis.
Claim 3
Dependent Claim
42 words
The process of claim 1 wherein the boron contaminated brine contains from about 40 to 50 ppm boron, and said magnesium hydroxide formed and recovered from said recovered brine has a boron content of less than 150 ppm on an oxide basis.
Claim 4
Dependent Claim
24 words
The process of claim 2 in which the boron content of said magnesium hydroxide is less than about 100 ppm on an oxide basis.
Claim 5
Dependent Claim
24 words
The process of claim 2 in which the boron content of said magnesium hydroxide is less than about 75 ppm on an oxide basis.
Claim 6
Dependent Claim
24 words
The process of claim 2 wherein the boron content of said magnesium hydroxide is less than about 35 ppm boron on an oxide basis.
Claim 7
Dependent Claim
30 words
A process as in claim 1 further including the step of calcining said magnesium hydroxide at a temperature of above about 2700° F. to produce a dead burned MgO product.
Claim 8
Dependent Claim
47 words
The process of claim 6 in which the boron content of said contaminated brine is from about 40 to about 50 ppm, said magnesium hydroxide formed and recovered and the MgO product produced therefrom having a boron content of less than 150 ppm on an oxide basis.
Claim 9
Dependent Claim
161 words
A process for removing boron contaminants from a magnesium halide-containing brine comprising: (a) contacting the boron contaminated, magnesium halide-containing brine with finely divided active magnesia, which has been formed by light or soft burn calcination of magnesia at a temperature of less than 2700° F. and which is in an amount of from about 0.1% to about 10% by weight based upon the weight of the untreated brine, said brine being at a temperature in the range of from about 32° F. to the boiling point of the mixture of the brine and the activated magnesia, to precipitate boron-containing magnesium hydrate containing at least about 75% by weight of the total boron content of the untreated brine; (b) separating said precipitated boron-containing magnesium hydrate from the remainder of said brine, whereby the boron content of the brine is reduced while not materially reducing the magnesium halide content of the brine; and (c) recovering said low boron content brine for further processing.
Claim 10
Dependent Claim
161 words
A process for removing boron contaminants from a magnesium halide-containing brine comprising: (a) contacting the boron contaminated, magnesium halide-containing brine with finely divided active magnesia, which has been formed by light or soft burn calcination of magnesia at a temperature of less than 2700° F. and which is in an amount of from about 0.1% to about 10% by weight based upon the weight of the untreated brine, said brine being at a temperature in the range of from about 32° F. to the boiling point of the mixture of the brine and the activated magnesia, to precipitate boron-containing magnesium hydrate containing at least about 75% by weight of the total boron content of the untreated brine; (b) separating said precipitated boron-containing magnesium hydrate from the remainder of said brine, whereby the boron content of the brine is reduced while not materially reducing the magnesium halide content of the brine; and (c) recovering said low boron content brine for further processing.
Claim 11
Dependent Claim
19 words
The process of claim 8 in which said boron-containing magnesium hydrate precipitate separated from said brine contains unreacted magnesia.
Claim 12
Dependent Claim
28 words
The process of claim 9 wherein the boron content of said precipitate is at least about 95% by weight of the total boron content of the untreated brine.
Claim 13
Dependent Claim
22 words
The process of claim 8 wherein the boron content of said recovered brine has been reduced at least about 95% by weight.
Claim 14
Dependent Claim
30 words
The process of claim 8 in which said active magnesia is employed in an amount from about 2% to about 6% by weight based on the weight of untreated brine.
Claim 15
Dependent Claim
25 words
The process of claim 8 wherein said contacting is performed at a temperature of from about 150° F. to the boiling point of said mixture.
Claim 16
Dependent Claim
22 words
The process of claim 8 wherein said contacting is performed at a temperature of from about 180° F. to about 200° F.
Claim 17
Dependent Claim
27 words
The process of claim 8 wherein said boron-containing magnesium hydrate precipitate separated from said brine contains between about 1000 and 2000 ppm boron on an oxide basis.
Claim 18
Dependent Claim
44 words
The process of claim 8 wherein the magnesium hydroxide formed and recovered from the treated brine has a boron content of less than 75 ppm on an oxide basis and a Ca(OH) 2 contamination of less than 1.0% as CaO on an MgO basis.
References Cited (Backward Citations)
US2402959A
Cited
US2405055A
Cited
US2398743A
Cited
US3393976A
Cited
US3447899A
Cited
US3425804A
Cited
US3482938A
Cited
US3787558A
Cited
US3689218A
Cited
DE2060089A1
Cited
US3980536A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-07-11 | 1981-01-10 | 1981-07-12 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-07-11 | 1985-01-10 | 1985-07-12 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-07-11 | 1989-01-10 | 1989-07-12 | $7700.00 | Window Closed / Lapsed |