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US4035441A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyester filament having excellent antistatic properties and process for preparing the same

Assignee: Toray Industries Inc
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Filing: 1974-06-24
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Granted: 1977-07-12
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Expires: 1994-06-24
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Abstract

Abstract A polyester filament in which a polyether-polyester block copolymer is dispersed as fine striae along the filament axis, at least one of which is substantially endless. Process for preparing the same includes a melt spinning apparatus with static mixing elements interposed between separate molten polymer feed passageways and spinneret holes.

Inventors

  • 👤 Tadakazu Endo
  • 👤 Masanori Takeuchi
  • 👤 Tuneo Hanada
  • 👤 Kiyoshi Nakagawa
  • 👤 Hideo Komatsu
  • 👤 Itaru Nakamura

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 18:00
CPC Classifications
D; D01; D01F; D01F8/00; D01F8/04; D01F8/14; D01D; D01D1/00; D01D1/06; D01D1/065; D01F6/00; D01F6/88; D01F6/92; Y; Y10; Y10S; Y10S260/00; Y10S260/15; Y10S260/17; Y10S264/00; Y10S264/29

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 220 words
A polyester filament having excellent antistatic properties which comprises a composition of (1) a polyester selected from one group consisting of polyethylene terephthalate, polytetramethylene terephthalate, polyethylene-2, 6-napthalene dicarboxylate, poly-1,44-cyclohexanedimethylene terephthalate poly[ethylene-1,2-bis(phenoxy)ethane-p, p'-dicarboxylate] and poly-p-ethylene oxybenzoate, and (2) a polyether-polyester block copolymer consisting of polyalkylene glycol and polyester wherein at least 40 mol % of the polyester segment of said polyether-polyester block copolymer comprises polyester constituents synthesized from at least one member selected from the group consisting of: A. an aliphatic or alicyclic oxycarboxylic acid having at least 2 carbon atoms and ester-forming derivatives thereof, B. an aliphatic or alicyclic dicarboxylic acid having at least 3 carbon atoms and ester-forming derivatives thereof, C. an aromatic dicarboxylic acid or oxycarboxylic acid having a group ether-linked with an aromatic ring having a carboxyl group and ester-forming derivatives thereof, D. an aromatic dicarboxylic acid or oxycarboxylic acid having a substituent group at the orthoposition toward a carboxyl group and ester-forming derivatives thereof, and E. an aliphatic or alicyclic glycol having at least 3 carbon atoms, wherein said polyester filament includes 0.01-5.0% of said polyalkylene glycol by weight of said polyester filament, and has a specific resistance less than 10 11 Ω.cm and said polyether-polyester block copolymer is dispersed as fine striae along the filament axis, at least one of said striae being substantially endless.
Claim 2
Dependent Claim 220 words
A polyester filament having excellent antistatic properties which comprises a composition of (1) a polyester selected from one group consisting of polyethylene terephthalate, polytetramethylene terephthalate, polyethylene-2, 6-napthalene dicarboxylate, poly-1,44-cyclohexanedimethylene terephthalate poly[ethylene-1,2-bis(phenoxy)ethane-p, p'-dicarboxylate] and poly-p-ethylene oxybenzoate, and (2) a polyether-polyester block copolymer consisting of polyalkylene glycol and polyester wherein at least 40 mol % of the polyester segment of said polyether-polyester block copolymer comprises polyester constituents synthesized from at least one member selected from the group consisting of: A. an aliphatic or alicyclic oxycarboxylic acid having at least 2 carbon atoms and ester-forming derivatives thereof, B. an aliphatic or alicyclic dicarboxylic acid having at least 3 carbon atoms and ester-forming derivatives thereof, C. an aromatic dicarboxylic acid or oxycarboxylic acid having a group ether-linked with an aromatic ring having a carboxyl group and ester-forming derivatives thereof, D. an aromatic dicarboxylic acid or oxycarboxylic acid having a substituent group at the orthoposition toward a carboxyl group and ester-forming derivatives thereof, and E. an aliphatic or alicyclic glycol having at least 3 carbon atoms, wherein said polyester filament includes 0.01-5.0% of said polyalkylene glycol by weight of said polyester filament, and has a specific resistance less than 10 11 Ω.cm and said polyether-polyester block copolymer is dispersed as fine striae along the filament axis, at least one of said striae being substantially endless.
Claim 3
Dependent Claim 23 words
A polyester filament according to claim 1 wherein the maximum diameter of said substantially endless stria is within the range of 0.01-5 microns.
Claim 4
Dependent Claim 17 words
A polyester filament according to claim 1 wherein polyalkyleneglycol comprises 0.01-5.0% by weight of said polyester filament.
Claim 5
Dependent Claim 17 words
A polyester filament according to claim 1 wherein said specific resistance is less than 10 9 Ω.cm.
Claim 6
Dependent Claim 30 words
A polyester filament according to claim 1 wherein said polyether-polyester block copolymer is obtained by copolymerizing 10.0-97.5% polyalkylene glycol having an average degree of polymerization of 10-1000 with a polyester.
Claim 7
Dependent Claim 89 words
A polyester filament according to claim 1 wherein said polyether-polyester block copolymer contains at least one ionic substance selected from the group consisting of the following formulae: ______________________________________ MeX, RCOOMe, ROSO.sub.3 M3, RSO.sub.3 Me, ROPO.sub.3 Me.sub.2, ##STR2## ##STR3## ______________________________________ (wherein R, R.sub.1, R.sub.2, R.sub.3, R.sub.4 stand for alkyl, aralkyl, alkaryl groups each having 1- 30 carbon atoms, Me stands for a metal ion of a metal of Group I of the Periodic Table, and X stands for a halogen ion or an alkyl sulfate ion having 1-30 carbon atoms).
Claim 8
Dependent Claim 14 words
A polyester filament according to claim 3 wherein said polyalkylene glycol is polyethylene glycol.
Claim 9
Dependent Claim 18 words
A polyester filament according to claim 1 wherein the polyester segment constituting said polyether-polyester block copolymer is amorphous.
Claim 10
Dependent Claim 24 words
A polyester filament according to claim 1 wherein the polyester segment constituting said polyether-polyester block copolymer has a melting point less than 240° C.
Claim 11
Dependent Claim 16 words
A polyester filament according to claim 1 which has an elongation at break less than 250%.
Claim 12
Dependent Claim 38 words
A polyester filament according to claim 1 wherein said polyether-polyester block copolymer is dispersed in the central portion of the cross section of said filament and the surface layer of said filament is substantially composed of polyester only.
Claim 13
Dependent Claim 30 words
A polyester filament according to claim 1 whose specific resistance after it is heat treated in circulating air at 180° C. for 5 minutes is less than 10 11 Ω.cm.
Claim 14
Dependent Claim 32 words
A polyester filament according to claim 1 whose specific resistance after at least 5% of its weight is decreased by being treated with an alkali solution is less than 10 11 Ω.cm.
Claim 15
Dependent Claim 13 words
A polyester filament according to claim 1 which contains at least one antioxidant.
Claim 16
Dependent Claim 12 words
Woven or knitted fabrics comprised of the filament obtained in claim 1.
Claim 17
Dependent Claim 26 words
A polyester filament mixed yarn consisting of a filament as defined in claim 1 combined with a filament which is substantially free of polyether-polyester block copolymer.
Claim 18
Dependent Claim 20 words
A polyester filament as defined in claim 1 wherein a plurality of said striae in said filament are substantially endless.
Claim 19
Dependent Claim 13 words
A yarn composed of a plurality of filaments as defined in claim 1.

References Cited (Backward Citations)

US3329557A Cited
US3381057A Cited
US3410927A Cited
US3577308A Cited
US3652713A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-11 1981-01-10 1981-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-11 1985-01-10 1985-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-11 1989-01-10 1989-07-12 $7700.00 Window Closed / Lapsed

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