Ternary polyblends prepared from polybutylene terephthalates, polyurethanes and aromatic polycarbonates

Claim 2

A ternary polyblend consisting essentially of an intimate mixture of between about 10 and 40 parts by weight of an aromatic polycarbonate possessing the repetitive carbonate group ##STR8## and having the ##STR9## radical attached to the carbonate group; from about 35 to 60 parts by weight of polybutylene terephthalate composed of recurring structural units of the formula ##STR10## and from about 20 to 40 parts by weight of a polyurethane that is a reaction product of a diisocyanate, a polyester or polyether and a chain extender characteristically containing the urethane structure ##STR11## wherein more than about 20 parts by weight of polyurethane are used if more than about 55 parts of polybutylene terephthalate are used.

Claim 3

A ternary polyblend composition consisting essentially of a melt-extruded intimate mixture of between about 10 and 40 parts by weight of an aromatic polycarbonate possessing recurring structural units of the formula ##STR12## wherein Z is a single bond, an alkylene or alkylidene radical with 1-7 carbon atoms, a cycloalkylene or cycloalkylidene radical with 5-12 carbon atoms, --O--, --S--, --CO--, --SO-- or --SO 2 --; R 1 and R 2 are hydrogen, halogen or an alkylene or alkylidene radical having 1-7 carbon atoms; and n equals 0 to 4; from about 35 to 60 parts by weight of polybutylene terephthalate composed of recurring structural units of the formula ##STR13## and from about 20 to 40 parts by weight of a polyurethane resin characteristically containing the urethane structure ##STR14## and selected from the group consisting of polyester and polyether based polyurethanes wherein more than about 20 parts by weight of polyurethane are used if more than about 55 parts by weight of polybutylene terephthalate are used.

Claim 4

A ternary polyblend composition consisting essentially of a melt-extruded intimate mixture of between about 10 and 40 parts by weight of an aromatic polycarbonate possessing recurring structural units of the formula ##STR12## wherein Z is a single bond, an alkylene or alkylidene radical with 1-7 carbon atoms, a cycloalkylene or cycloalkylidene radical with 5-12 carbon atoms, --O--, --S--, --CO--, --SO-- or --SO 2 --; R 1 and R 2 are hydrogen, halogen or an alkylene or alkylidene radical having 1-7 carbon atoms; and n equals 0 to 4; from about 35 to 60 parts by weight of polybutylene terephthalate composed of recurring structural units of the formula ##STR13## and from about 20 to 40 parts by weight of a polyurethane resin characteristically containing the urethane structure ##STR14## and selected from the group consisting of polyester and polyether based polyurethanes wherein more than about 20 parts by weight of polyurethane are used if more than about 55 parts by weight of polybutylene terephthalate are used.

Claim 5

A ternary polyblend composition consisting essentially of a melt-extruded intimate mixture of between about 10 and 40 parts by weight of a bisphenol-A polycarbonate; from about 35 to 60 parts by weight of a polybutylene terephthalate resin; and from about 20 to 40 parts by weight of a polyurethane resin characteristically containing the urethane structure ##STR15## and selected from the group consisting of polyester and polyether based polyurethanes wherein more than about 20 parts by weight of polyurethane are used if more than about 55 parts by weight of polybutylene terephthalate are used.

Claim 6

A ternary polyblend composition consisting essentially of a melt-extruded intimate mixture of between about 10 and 40 parts by weight of a bisphenol-A polycarbonate; from about 35 to 60 parts by weight of a polybutylene terephthalate resin; and from about 20 to 40 parts by weight of a polyurethane resin characteristically containing the urethane structure ##STR15## and selected from the group consisting of polyester and polyether based polyurethanes wherein more than about 20 parts by weight of polyurethane are used if more than about 55 parts by weight of polybutylene terephthalate are used.

Claim 7

The composition of claim 1 wherein the polybutylene terephthalate is present in from about 45 to 55 parts by weight.

Claim 8

The composition of claim 4 wherein the polybutylene terephthalate is present in from about 47 to 52 parts by weight.

Claim 9

The composition of claim 1 wherein the aromatic polycarbonate is present in from about 20 to 35 parts by weight.

Claim 10

The composition of claim 6 wherein the aromatic polycarbonate is present in from about 20 to 30 parts by weight.

Claim 11

The composition of claim 7 in which the aromatic polycarbonate is a bisphenol-A polycarbonate.

Claim 12

The composition of claim 1 wherein the polyurethane is present in from about 20 to 30 parts by weight.

Claim 13

The composition of claim 9 wherein the polyurethane is present from about 20 to 25 parts by weight.

Claim 14

The composition of claim 1 wherein the aromatic polycarbonate has a melt flow rate range of about 1 to 24 gms/10 min. (ASTM D-1238).

Claim 15

The composition of claim 1 wherein the polybutylene terephthalate has an intrinsic viscosity of at least about 0.95.

Claim 16

The composition of claim 1 wherein the polyurethane has a Shore hardness of between about 70 on the "A" scale and 60 on the "D" scale (ASTM D-2240).

Claim 17

The composition of claim 2 wherein the polybutylene terephthalate is present in from about 45 to 55 parts by weight.

Claim 18

The composition of claim 14 wherein the polybutylene terephthalate is present in from about 47 to 52 parts by weight.

Claim 19

The composition of claim 2 wherein the aromatic polycarbonate is present in from about 20 to 35 parts by weight.

Claim 20

The composition of claim 16 wherein the aromatic polycarbonate is present in from about 20 to 30 parts by weight.

Claim 21

The composition of claim 17 in which the polycarbonate is a bisphenol-A polycarbonate.

Claim 22

The composition of claim 2 wherein the polyurethane is present from about 20 to 30 parts by weight.

Claim 23

The composition of claim 19 wherein the polyurethane is present from about 20 to 25 parts by weight.

Claim 24

The composition of claim 2 wherein the aromatic polycarbonate has a melt flow rate range of about 1 to 24 gms/10 min. (ASTM D-1238).

Claim 25

The composition of claim 2 wherein the polybutylene terephthalate has an intrinsic viscosity of at least about 0.95 .

Claim 26

The composition of claim 2 wherein the polyurethane has a Shore hardness of between about 70 on the "A" scale and 60 on the "D" scale.