Process for producing unsaturated resin emulsion

Claim 2

A process for producing an aqueous emulsion of unsaturated resin which comprises the steps of: synthesizing polyvinyl resin having an acid value of 50 to 230 and a number average molecular weight of 10,000 to 200,000 by means of solution copolymerization of at least one acid monomer selected from the group consisting of acrylic acid, methacrylic acid, orthophosphoric acid monoacrylate ester and orthophosphoric acid monomethacrylate ester with at least one compound selected from the group consisting of styrene; methyl, ethyl, n-butyl, isobutyl, 2-ethylhexyl, 2-hydroxyethyl, 2-hyroxypropyl and lauryl ester of acrylic acid; methyl, ethyl, n-butyl, isobutyl, 2-ethylhexyl, 2-hydroxyethyl, 2-hydroxypropyl and lauryl ester of methacrylic acid; acrylonitrile; methacrylonitrile; acrylamide; methacrylamide; N-methylol acrylamide; N-methylol methacrylamide; diacetone acrylamide; and diacetone methacrylamide; adding at least one monomer having epoxy group and reactive unsaturated group selected from the group consisting of glycidyl acrylate, glycidyl methacrylate and allylglycidyl ether to said polyvinyl resin to produce unsaturated resin having an acid value of 20 to 60 and an unsaturation degree of 0.5 to 3.0, removing the polymerization solvent under reduced pressure, neutralizing residual acid groups with 0.4 to 1.2 equivalent of base and dispersing the neutralized product into water.

Claim 3

A process for producing an aqueous emulsion of unsaturated resin as claimed in claim 1, in which the number average molecular weight of the polyvinyl resin is 40,000 to 100,000.

Claim 4

A process for producing an aqueous emulsion of unsaturated resin as claimed in claim 1, in which a photosensitizer is added to said emulsion.

Claim 5

A process for producing an aqueous emulsion of unsaturated resin as claimed in claim 1, in which said polyvinyl resin is produced by copolymerizing methyl methacrylate, styrene, n-butyl acrylate, methacrylic acid and 2-hydroxyethyl acrylate, and wherein said monomer having an epoxy group and reactive unsaturated group is glycidyl acrylate.

Claim 6

A process for producing an aqueous emulsion of unsaturated resin as claimed in claim 1, in which said polyvinyl resin is produced by copolymerizing acrylamide, isobutyl acrylate, 2-ethylhexyl methylate, and acrylic acid, and wherein said monomer having epoxy group and reactive unsaturated group is a mixture of glycidyl acrylate and allylglycidyl ether.

Claim 7

A process for producing an aqueous emulsion of unsaturated resin which comprises the steps of: synthesizing polyvinyl resin having an acid value of 50 to 230 and a number average molecular weight of 10,000 to 200,000 by means of solution copolymerization of at least one acid monomer selected from the group consisting of acrylic acid, methacrylic acid, orthophosphoric acid monoacrylate ester and orthophosphoric acid monomethacrylate ester with at least one compound selected from the group consisting of styrene; methyl, ethyl, n-butyl, isobutyl, 2-ethylhexyl, 2-hydroxyethyl, 2-hydroxpropyl and lauryl ester of acrylic acid; methyl, ethyl, n-butyl, isobutyl, 2-ethylhexyl, 2-hydroxyethyl, 2-hydroxypropyl and lauryl ester of methacrylic acid; acrylonitrile; methacrylonitrile; acrylamide; methacrylamide; N-methylol acrylamide; N-methylol methacrylamide; diacetone acrylamide; and diacetone methacrylamide; adding at least one monomer having epoxy group and reactive unsaturated group selected from the group consisting of glycidyl acrylate, glycidyl methacrylate and allylglycidyl ether to said polyvinyl resin to produce unsaturated resin having an acid value of 20 to 60 and an unsaturation degree of 0.5 to 3.0, mixing 5 to 60 parts of at least one monomer of above 190° C. in boiling point having reactive unsaturated group selected from the group consisting of 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxpropyl, 2-ethylhexyl and lauryl ester of acrylic acid; 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, 2-ethylhexyl and lauryl ester of methacrylic acid; diacrylate of ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, polypropylene glycol, neopentyl glycol, and 1,6-hexanediol; dimethacrylate of ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, polypropylene glycol, neopentyl glycol and 1,6-hexandiol; triacrylate of trimethylolpropane and trimethylolethane; and trimethacrylate of trimethylolpropane and trimethylolethane; to 100 parts of above unsaturated resin, removing the polymerization solvent under reduced pressure, neutralizing residual acid groups with 0.4 to 1.2 equivalent of base and dispersing the neutralized product into water.

Claim 8

A process for producing an aqueous emulsion of unsaturated resin which comprises the steps of: synthesizing polyvinyl resin having an acid value of 50 to 230 and a number average molecular weight of 10,000 to 200,000 by means of solution copolymerization of at least one acid monomer selected from the group consisting of acrylic acid, methacrylic acid, orthophosphoric acid monoacrylate ester and orthophosphoric acid monomethacrylate ester with at least one compound selected from the group consisting of styrene; methyl, ethyl, n-butyl, isobutyl, 2-ethylhexyl, 2-hydroxyethyl, 2-hydroxpropyl and lauryl ester of acrylic acid; methyl, ethyl, n-butyl, isobutyl, 2-ethylhexyl, 2-hydroxyethyl, 2-hydroxypropyl and lauryl ester of methacrylic acid; acrylonitrile; methacrylonitrile; acrylamide; methacrylamide; N-methylol acrylamide; N-methylol methacrylamide; diacetone acrylamide; and diacetone methacrylamide; adding at least one monomer having epoxy group and reactive unsaturated group selected from the group consisting of glycidyl acrylate, glycidyl methacrylate and allylglycidyl ether to said polyvinyl resin to produce unsaturated resin having an acid value of 20 to 60 and an unsaturation degree of 0.5 to 3.0, mixing 5 to 60 parts of at least one monomer of above 190° C. in boiling point having reactive unsaturated group selected from the group consisting of 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxpropyl, 2-ethylhexyl and lauryl ester of acrylic acid; 2-hydroxyethyl, 2-hydroxypropyl, 3-hydroxypropyl, 2-ethylhexyl and lauryl ester of methacrylic acid; diacrylate of ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, polypropylene glycol, neopentyl glycol, and 1,6-hexanediol; dimethacrylate of ethylene glycol, diethylene glycol, propylene glycol, polyethylene glycol, polypropylene glycol, neopentyl glycol and 1,6-hexandiol; triacrylate of trimethylolpropane and trimethylolethane; and trimethacrylate of trimethylolpropane and trimethylolethane; to 100 parts of above unsaturated resin, removing the polymerization solvent under reduced pressure, neutralizing residual acid groups with 0.4 to 1.2 equivalent of base and dispersing the neutralized product into water.

Claim 9

A process for producing an aqueous emulsion of unsaturated resin as claimed in claim 6, in which a photosensitizer is added to said emulsion.

Claim 10

A process for producing an aqueous emulsion of unsaturated resin as claimed in claim 6, in which the number average molecular weight of the polyvinyl resin is 40,000 to 100,000, and in which the amount of monomer of above 190° C. in boiling point is 10 to 30 parts.