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US4033854A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrical insulating oils

Assignee: Eneos Corp
•
Filing: 1975-12-01
•
Granted: 1977-07-05
•
Expires: 1995-12-01
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Abstract

Abstract An electrical insulating oil having excellent oxidation stability, thermal stability and/or hydrogen absorbability consisting essentially of (A) a base hydrocarbon oil obtained by hydrofining and then dewaxing a fraction boiling at 280 DEG -400 DEG derived from a paraffin or mixed base crude oil, (B) a highly aromatic hydrocarbon oil obtained by hydrofining and/or distilling a heavy hydrocarbon fraction boiling at 250 DEG -400 DEG C produced as a by-product at the time of catalytically reforming naphtha or the like and, if desired, (C) an oil obtained by treating a lubricating oil fraction boiling at 230 DEG -500 DEG C derived from a crude petroleum oil.

Inventors

  • 👤 Tadashi Ohmori
  • 👤 Tokuo Fujisou

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 21:32
CPC Classifications
H; H01; H01B; H01B3/00; H01B3/18; H01B3/20; H01B3/22; C; C10; C10G; C10G25/00; C10G45/00; C10G45/02; C10M; C10M101/00; C10M101/02; C10G2400/00; C10G2400/12; C10M2203/00; C10M2203/10; C10M2203/1006; C10M2203/102; C10M2203/1025; C10M2203/104; C10M2203/1045; C10M2203/106; C10M2203/1065; C10M2203/108; C10M2203/1085; C10N; C10N2040/00; C10N2040/14; C10N2040/16; C10N2040/17

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 189 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.5 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at at least to hydrofining and solvent dewaxing a fraction containing a distillate having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil and (II) 5- 100 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of a catalyst selected from the group consisting of the Platinum Group metals and combinations of each of the Platinum Group metals with at least one of Ge, Sn, Re, Fe, Ni, Pb and halogens.
Claim 2
Dependent Claim 189 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.5 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at at least to hydrofining and solvent dewaxing a fraction containing a distillate having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil and (II) 5- 100 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of a catalyst selected from the group consisting of the Platinum Group metals and combinations of each of the Platinum Group metals with at least one of Ge, Sn, Re, Fe, Ni, Pb and halogens.
Claim 3
Dependent Claim 211 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.2 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at least to hydrofining and solvent dewaxing a fraction having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil, (II) 5- 30 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of a catalyst selected from the group consisting of the Platinum Group metals and combinations of each of the Platinum Group metals with at least one of Ge, Sn, Re, Fe, Ni, Pb and halogens, and (III) 1- 15 parts by weight of a refined oil (C) prepared by treating the lubricating oil fraction of a mineral oil with a solid absorbent.
Claim 4
Dependent Claim 211 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.2 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at least to hydrofining and solvent dewaxing a fraction having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil, (II) 5- 30 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of a catalyst selected from the group consisting of the Platinum Group metals and combinations of each of the Platinum Group metals with at least one of Ge, Sn, Re, Fe, Ni, Pb and halogens, and (III) 1- 15 parts by weight of a refined oil (C) prepared by treating the lubricating oil fraction of a mineral oil with a solid absorbent.
Claim 5
Dependent Claim 29 words
An electrical insulating oil according to claim 1, wherein the hydrocarbons to be subjected to the reforming reaction are those boiling in the range of 60° - 200° C.
Claim 6
Dependent Claim 29 words
An electrical insulating oil according to claim 2, wherein the hydrocarbons to be subjected to the reforming reaction are those boiling in the range of 60° - 200° C.
Claim 7
Dependent Claim 32 words
An electrical insulating oil according to claim 2, wherein the lubricating oil fraction as the material for the refined oil (C) is one having a boiling range of 230° - 500° C.
Claim 8
Dependent Claim 36 words
An electrical insulating oil according to claim 1, wherein the highly aromatic hydrocarbon oil (B) contains not less than about 50% by weight of about C 10 to about C 18 bicyclic and monocyclic aromatic hydrocarbon.
Claim 9
Dependent Claim 36 words
An electrical insulating oil according to claim 1, wherein the highly aromatic hydrocarbon oil (B) contains not less than about 90% by weight of about C 10 to about C 18 bicyclic and monocyclic aromatic hydrocarbon.
Claim 10
Dependent Claim 36 words
An electrical insulating oil according to claim 2, wherein the highly aromatic hydrocarbon oil (B) contains not less than about 50% by weight of about C 10 to about C 18 bicyclic and monocyclic aromatic hydrocarbon.
Claim 11
Dependent Claim 36 words
An electrical insulating oil according to claim 2, wherein the highly aromatic hydrocarbon oil (B) contains not less than about 90% by weight of about C 10 to about C 18 bicyclic and monocyclic aromatic hydrocarbon.
Claim 12
Dependent Claim 41 words
An electrical insulating oil according to claim 6, wherein the highly aromatic hydrocarbon oil (B) has a specific gravity of d 4 20 0.980- 1.000, a refractive index of n d 20 1.56- 1.60 and a specific dispersion of 220- 240.
Claim 13
Dependent Claim 41 words
An electrical insulating oil according to claim 7, wherein the highly aromatic hydrocarbon oil (B) has a specific gravity of d 4 20 0.980- 1.000, a refractive index of n d 20 1.56- 1.60 and a specific dispersion of 220- 240.
Claim 14
Dependent Claim 41 words
An electrical insulating oil according to claim 8, wherein the highly aromatic hydrocarbon oil (B) has a specific gravity of d 4 20 0.980- 1.000, a refractive index of n d 20 1.56- 1.60 and a specific dispersion of 220- 240.
Claim 15
Dependent Claim 41 words
An electrical insulating oil according to claim 9, wherein the highly aromatic hydrocarbon oil (B) has a specific gravity of d 4 20 0.980- 1.000, a refractive index of n d 20 1.56- 1.60 and a specific dispersion of 220- 240.
Claim 16
Dependent Claim 29 words
An electrical insulating oil according to claim 1, containing 8- 50 parts by weight of highly aromatic hydrocarbon oil (B) per 100 parts by weight of mineral oil (A).
Claim 17
Dependent Claim 21 words
An electrical insulating oil according to claim 1, wherein mineral oil (A) has a sulphur content higher than 0.2 wt. %.
Claim 18
Dependent Claim 23 words
An electrical insulating oil according to claim 2, wherein the refined oil (C) has a sulphur content of about 0.1- 2 wt. %.
Claim 19
Dependent Claim 23 words
An electrical insulating oil according to claim 2, wherein the refined oil (C) has a sulphur content of about 0.2- 1.5 wt. %.
Claim 20
Dependent Claim 16 words
An electrical insulating oil according to claim 2, containing not higher than 0.35 wt. % sulphur.
Claim 21
Dependent Claim 15 words
An electrical insulating oil according to claim 18, containing 0.05 to 0.3 wt. % sulphur.
Claim 22
Dependent Claim 160 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.5 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at least to hydrofining and solvent dewaxing a fraction containing a distillate having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil and (II) 5- 100 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of a Group VIII noble metal catalyst.
Claim 23
Dependent Claim 160 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.5 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at least to hydrofining and solvent dewaxing a fraction containing a distillate having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil and (II) 5- 100 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of a Group VIII noble metal catalyst.
Claim 24
Dependent Claim 182 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.2 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at least to hydrofining and solvent dewaxing a fraction having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil, (II) 5- 30 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of Group VIII noble metal catalyst, and (III) 1- 15 parts by weight of a refined oil (C) prepared by treating the lubricating oil fraction of a mineral oil with a solid adsorbent.
Claim 25
Dependent Claim 182 words
An electrical insulating oil consisting essentially of (I) 100 parts by weight of a mineral oil (A) having a sulphur content of not higher than 0.2 wt. %, a pour point of from -10° to -25° C. and a nitrogen content of not more than 100 p.p.m., the mineral oil (A) being prepared by subjecting at least to hydrofining and solvent dewaxing a fraction having a boiling range of 280° - 400° C. at atmospheric pressure, the fraction being obtained by the distillation of a paraffin base crude oil or a mixed base crude oil, (II) 5- 30 parts by weight of a highly aromatic hydrocarbon oil (B) prepared by hydrofining a fraction having a boiling range of 250° - 400° C. at atmospheric pressure, the fraction being produced as a by-product of subjecting naphtha hydrocarbons to reforming reaction at temperatures of 400° - 600° C. in the presence of Group VIII noble metal catalyst, and (III) 1- 15 parts by weight of a refined oil (C) prepared by treating the lubricating oil fraction of a mineral oil with a solid adsorbent.

References Cited (Backward Citations)

US2846372A Cited
US2921011A Cited
US3617473A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-04 1981-01-03 1981-07-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-04 1985-01-03 1985-07-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-04 1989-01-03 1989-07-05 $7700.00 Window Closed / Lapsed

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