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US4033673A Expired / Lapsed US ⏱️ 0.0 years remaining

Erasable visual image display device

Assignee: International Business Machines Corp
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Filing: 1976-05-17
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Granted: 1977-07-05
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Expires: 1996-05-17
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Abstract

Abstract An erasable visual image display device contains a pair of conductive electrodes in spaced relationship. One electrode has a cation permselective membrane thereon and the other electrode has an anion permselective membrane thereon. Positioned between the two membranes is a recording medium having the properties of being both photoionizable and capable of electrochemically producing colored species. The medium contains an electrochemically reversible acceptor molecule, for example, 1, 2, 4, 5 tetracyanobenzene and an electrochemically reversible donor molecule, for example, 1-phenyl-3 diethylaminostyrl 5-diethylaminophenyl Δ 2 pyrazoline.

Inventors

  • 👤 Hajime Seki

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 16:32
CPC Classifications
C; C09; C09K; C09K9/00; C09K9/02; G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; G02F1/1514; G02F1/1516

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 78 words
A visual image display device comprising: a first and a second conductive electrode in spaced-relationship; a cation permselective membrane on said first electrode, an anion permselective membrane on said second electrode, a voltage source and means for selectively applying this voltage between the electrodes to produce an electric field; and a normally light transmitting recording medium occupying the space between said electrodes, said medium having the properties of being both photo-ionizable and capable of electrochemically producing colored species.
Claim 2
Dependent Claim 78 words
A visual image display device comprising: a first and a second conductive electrode in spaced-relationship; a cation permselective membrane on said first electrode, an anion permselective membrane on said second electrode, a voltage source and means for selectively applying this voltage between the electrodes to produce an electric field; and a normally light transmitting recording medium occupying the space between said electrodes, said medium having the properties of being both photo-ionizable and capable of electrochemically producing colored species.
Claim 3
Dependent Claim 14 words
A device as described in claim 1 wherein said medium contains an organic solvent.
Claim 4
Dependent Claim 16 words
A device as described in claim 1 wherein said first and said second electrodes are semitransparent.
Claim 5
Dependent Claim 92 words
A visual image display device comprising: a first and a second conductive electrode in spaced-relationship; a cation permselective membrane on said first electrode, an anion permselective membrane on said second electrode, a voltage source and means for selectively applying this voltage between the electrodes to produce an electric field; and a normally light transmitting recording medium occupying the space between said electrodes, said medium having the properties of being both photo-ionizable and capable of electrochemically producing colored species; said medium contains an electrochemically reversible donor molecule and an electrochemically reversible acceptor molecule.
Claim 6
Dependent Claim 92 words
A visual image display device comprising: a first and a second conductive electrode in spaced-relationship; a cation permselective membrane on said first electrode, an anion permselective membrane on said second electrode, a voltage source and means for selectively applying this voltage between the electrodes to produce an electric field; and a normally light transmitting recording medium occupying the space between said electrodes, said medium having the properties of being both photo-ionizable and capable of electrochemically producing colored species; said medium contains an electrochemically reversible donor molecule and an electrochemically reversible acceptor molecule.
Claim 7
Dependent Claim 28 words
A device as described in claim 4 wherein said donor molecule forms a radical ion adapted to absorb light in the visible spectrum to form the desired color.
Claim 8
Dependent Claim 28 words
A device as described in claim 4 wherein said acceptor molecule forms a radical ion adapted to absorb light in the visible spectrum to form the desired color.
Claim 9
Dependent Claim 32 words
A device as described in claim 4 wherein said acceptor molecule is taken from the group consisting of: 1, 2, 4, 5 tetracyanobenzene, 1, 2 dicyanobenzene; 1, 4, dicyanobenzene and furmaric nitrile.
Claim 10
Dependent Claim 26 words
A device as described in claim 4 wherein said donor molecule is taken from the group consisting of triaryl - Δ 2 - pyrazoline and spiropyrans.
Claim 11
Dependent Claim 17 words
A device as described in claim 4 wherein said donor molecule is 1-phenyl-3-diethylaminostyrl-5-diethylaminophenyl - Δ 2 -pyrazoline.

References Cited (Backward Citations)

US3453038A Cited
US3589896A Cited
US3840288A Cited
US3986771A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-07-04 1981-01-03 1981-07-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-07-04 1985-01-03 1985-07-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-07-04 1989-01-03 1989-07-05 $7700.00 Window Closed / Lapsed

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