US4032578A
Expired / Lapsed
US
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Process for the manufacture of aldehydes and hda and other alcohols by aldol condensation
Assignee: ExxonMobil Technology and Engineering Co
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Filing: 1976-01-07
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Granted: 1977-06-28
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Expires: 1996-01-07
Abstract
Abstract A new process for the manufacture of aldehydes by aldol condensation using a feed consisting of crude, high conversion, demetalled conventional oxo product is described. In another embodiment a new process for the manufacture of hexadecyl alcohol and related alcohols using the above-described feed is also set forth. The process is a uniphase aldol condensation process utilizing small quantities of basic catalyst and operating above certain minimum threshold temperatures. The process is operable with crude oxo feeds that contain as much as 40% by weight acetals. Process conditions are described which enable reversion of the acetals to aldehydes and alcohols thereby allowing concurrent condensation of reactive components with high selectivities to the product alcohols and aldehydes. The products of the process, such as hexadecyl alcohol, are well known and have many uses, such as in the formulation of cosmetic products.
Inventors
- 👤 Charles G. Savini
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-04 01:12
CPC Classifications
C; C07; C07C; C07C45/00; C07C45/49; C07C45/50; C07C29/00; C07C29/132; C07C29/136; C07C29/14; C07C29/141; C07C45/61; C07C45/67; C07C45/68; C07C45/72; C07C45/74
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
86 words
An aldolization process which comprises contacting an aldehyde-containing feed with a catalyst, in an amount ranging from about 0.01 to about 3 weight percent based on the aldehyde-containing feed, selected from the group consisting of hydroxides, soaps, alkoxides and phenoxides of Groups I-A and II-A metals, quaternary ammonium hydroxides and choline in the presence of water in an amount substantially within the solubility limit of the aldehyde-containing feed at a temperature ranging from about 300° F. to about 1,000° F. to achieve a uniphase aldolization mixture.
Claim 2
Dependent Claim
86 words
An aldolization process which comprises contacting an aldehyde-containing feed with a catalyst, in an amount ranging from about 0.01 to about 3 weight percent based on the aldehyde-containing feed, selected from the group consisting of hydroxides, soaps, alkoxides and phenoxides of Groups I-A and II-A metals, quaternary ammonium hydroxides and choline in the presence of water in an amount substantially within the solubility limit of the aldehyde-containing feed at a temperature ranging from about 300° F. to about 1,000° F. to achieve a uniphase aldolization mixture.
Claim 3
Dependent Claim
29 words
The process of claim 1 wherein said basic catalyst is selected from the group consisting of sodium hydroxide, potassium hydroxide, sodium stearate, sodium acetate and benzyl trimethyl ammonium hydroxide.
Claim 4
Dependent Claim
12 words
The process of claim 2 wherein said basic catalyst is sodium hydroxide.
Claim 5
Dependent Claim
14 words
The process of claim 1 wherein said aldehyde-containing feed is a crude-demetalled oxo product.
Claim 6
Dependent Claim
12 words
The process of claim 4 wherein said oxo product comprises an acetal.
Claim 7
Dependent Claim
18 words
The process of claim 1 wherein said aldolization temperature ranges from about 500° F. to about 700° F.
Claim 8
Dependent Claim
114 words
A process for producing an aliphatic alcohol which comprises: a. contacting an aldehyde-containing feed with a catalyst, in an amount ranging from about 0.01 to about 3 weight percent based on the aldehyde-containing feed, selected from the group consisting of hydroxides, soaps, alkoxides and phenoxides of Groups I-A and II-A metals, quaternary ammonium hydroxides and choline in the presence of water in an amount substantially within the solubility limit of the aldehyde-containing feed at a temperature ranging from about 300° F. to about 1000° F. to achieve a uniphase aldolization mixture; and, thereafter, b. hydrogenating the aldol product produced in (a) above under conventional conditions and using conventional catalysts to produce said aliphatic alcohol.
Claim 9
Dependent Claim
114 words
A process for producing an aliphatic alcohol which comprises: a. contacting an aldehyde-containing feed with a catalyst, in an amount ranging from about 0.01 to about 3 weight percent based on the aldehyde-containing feed, selected from the group consisting of hydroxides, soaps, alkoxides and phenoxides of Groups I-A and II-A metals, quaternary ammonium hydroxides and choline in the presence of water in an amount substantially within the solubility limit of the aldehyde-containing feed at a temperature ranging from about 300° F. to about 1000° F. to achieve a uniphase aldolization mixture; and, thereafter, b. hydrogenating the aldol product produced in (a) above under conventional conditions and using conventional catalysts to produce said aliphatic alcohol.
Claim 10
Dependent Claim
13 words
The process of claim 7 wherein said aliphatic alcohol product comprises hexadecyl alcohol.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-06-27 | 1980-12-27 | 1981-06-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-06-27 | 1984-12-27 | 1985-06-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-06-27 | 1988-12-27 | 1989-06-28 | $7700.00 | Window Closed / Lapsed |