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US4032440A Expired / Lapsed US ⏱️ 0.0 years remaining

Semipermeable membrane

Assignee: United States Department of the Interior
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Filing: 1975-11-18
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Granted: 1977-06-28
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Expires: 1995-11-18
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Abstract

Abstract A semipermeable composite membrane is prepared by glow discharge polymerization of a combination of an organic monomer and an inorganic monomer in the presence of a porous support, the polymerization resulting in deposition of a thin film of copolymer on the surface of the support.

Inventors

  • 👤 Hirotsugu Yasuda

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 17:07
CPC Classifications
B; B01; B01D; B01D69/00; B01D69/12; B01D69/125; B01D69/127

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 111 words
A process for preparation of a composite semipermeable membrane comprising: (1) positioning a porous support in an atmosphere comprising a polymerizable admixture of (a) an organic monomer from the group consisting of acetylene, ethylene, allene, benzene, pyridine and furfurylamine and (b) an inorganic monomer consisting of water or a mixture of water with nitrogen or carbon monoxide, said admixture being in vapor form, and (2) subjecting said admixture to the influence of electromagnetic energy of a frequency of about 50 Hz to 3000 mHz to produce an electric glow discharge, thereby causing copolymerization of the monomers and deposition of the resulting copolymer as a film on the surface of the support.
Claim 2
Dependent Claim 111 words
A process for preparation of a composite semipermeable membrane comprising: (1) positioning a porous support in an atmosphere comprising a polymerizable admixture of (a) an organic monomer from the group consisting of acetylene, ethylene, allene, benzene, pyridine and furfurylamine and (b) an inorganic monomer consisting of water or a mixture of water with nitrogen or carbon monoxide, said admixture being in vapor form, and (2) subjecting said admixture to the influence of electromagnetic energy of a frequency of about 50 Hz to 3000 mHz to produce an electric glow discharge, thereby causing copolymerization of the monomers and deposition of the resulting copolymer as a film on the surface of the support.
Claim 3
Dependent Claim 16 words
The process of claim 1 in which the porous support consists of an organic polymeric material.
Claim 4
Dependent Claim 21 words
The process of claim 2 in which the organic polymeric material is a mixed polymer of cellulose acetate and cellulose nitrate.
Claim 5
Dependent Claim 13 words
The process of claim 2 in which the organic polymeric material is polysulfone.
Claim 6
Dependent Claim 12 words
The process of claim 1 in which the organic monomer is acetylene.
Claim 7
Dependent Claim 12 words
The process of claim 1 in which the organic monomer is ethylene.
Claim 8
Dependent Claim 12 words
The process of claim 1 in which the organic monomer is allene.
Claim 9
Dependent Claim 12 words
The process of claim 1 in which the organic monomer is benzene.
Claim 10
Dependent Claim 12 words
The process of claim 1 in which the organic monomer is pyridine.
Claim 11
Dependent Claim 12 words
The process of claim 1 in which the organic monomer is furfurylamine.
Claim 12
Dependent Claim 12 words
The process of claim 1 in which the inorganic monomer is water.
Claim 13
Dependent Claim 23 words
The process of claim 1 in which the electromagnetic energy has a frequency in the range of about 50 Hz to 1000 mHz.
Claim 14
Dependent Claim 11 words
A composite semipermeable membrane prepared by the process of claim 1.
Claim 15
Dependent Claim 38 words
In a process for desalination of saline water by reverse osmosis comprising contacting the saline water under pressure with a reverse osmosis membrane, the improvement comprising using the composite membrane of claim 13 as the reverse osmosis membrane.

References Cited (Backward Citations)

US3775308A Cited
US3847652A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-27 1980-12-27 1981-06-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-27 1984-12-27 1985-06-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-27 1988-12-27 1989-06-28 $7700.00 Window Closed / Lapsed

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