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US4031168A Expired / Lapsed US ⏱️ 0.0 years remaining

Copolymers of isobutylene and a vinylbenzene and graft polymers thereof with pivalolactone

Assignee: EIDP Inc
•
Filing: 1975-09-25
•
Granted: 1977-06-21
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Expires: 1995-09-25
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Abstract

Abstract Graft copolymers of the formula X.sub.m Y.sub.n Y'.sub.p (Z.sub.q).sub.r wherein X is an isobutylene monomer unit, Y is a non-carboxylated vinylbenzene monomer unit of the formula ##STR1## in which Q is hydrogen or lower alkyl, R is halogen, lower alkyl, chloro lower alkyl, lower alkoxy, or two adjacent R's together are methylenedioxy, and s is an integer from 0 to 5, Y' is a carboxylated Y unit, Z is a pivalolactone monomer unit, m represents the number of isobutylene monomer units in the copolymer, n represents the number of non-carboxylated vinylbenzene monomer units in the copolymer, p represents the number of carboxylated vinylbenzene monomer units in the copolymer and is about 5 to 100% of n + p, m and (n + p) are in an m:(n + p) ratio of about 2:1 to 1000:1, q represents the number of pivalolactone monomer units per polypivalolactone side chain graft and is in the range of about 2 to 500, r represents the number of polypivalolactone side chain grafts in the graft copolymer and is substantially equal to p, X, y and Y' are randomly interconnected through carbon to carbon linkages with single Y and Y' units predominantly connected only to X units, Z q is a single polypivalolactone side chain grafted to a Y' unit through the carboxyl group, and (Z q ) r is about 3 to 80% of the total weight of the graft copolymer, And the copolymer has an X m Y n Y' p equivalent weight per carboxyl group of about 200 to 1 × 10 5 .

Inventors

  • 👤 William Henry Sharkey
  • 👤 John Ferguson Harris, Jr.

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 17:29
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/02; C08G63/06; C08G63/08; C08F; C08F210/00; C08F210/04; C08F210/08; C08F210/10; C08F8/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31692

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 255 words
A graft copolymer of the formula X.sub.m Y.sub.n Y'.sub.p (Z.sub.q).sub.r wherein X is an isobutylene monomer unit, Y is a vinylbenzene monomer unit of the formula ##STR6## in which Q is hydrogen or lower alkyl R is halogen, lower alkyl, chloro lower alkyl, lower alkoxy, or two adjacent R's together are methylenedioxy, and s is an integer from 0 to 5, Y' is a carboxylated Y unit, Z is a pivalolactone monomer unit, m represents the number of isobutylene monomer units in the copolymer, n represents the number of non-carboxylated vinylbenzene monomer units in the copolymer, p represents the number of carboxylated vinylbenzene monomer units in the copolymer and is 5 to 100% of (n + p), m and (n + p) are in an m: (n + p) ratio of 2:1 to 1000:1, q represents the number of pivalolactone monomer units per polypivalolactone side chain graft and is in the range of 2 to 500, r represents the number of polypivalolactone side chain grafts in the graft copolymer and is substantially equal to p, X, y and Y' are randomly interconnected through carbon to carbon linkages with single Y and Y' units predominantly connected only to X units, Z q is a single polypivalolactone side chain grafted to a Y' unit through the carboxyl group, and (Z q ) r is 3 to 80% by weight of the graft copolymer, and the copolymer has an X m Y n Y' p equivalent weight per carboxyl group of 200 to 1 × 10 5 .
Claim 2
Dependent Claim 255 words
A graft copolymer of the formula X.sub.m Y.sub.n Y'.sub.p (Z.sub.q).sub.r wherein X is an isobutylene monomer unit, Y is a vinylbenzene monomer unit of the formula ##STR6## in which Q is hydrogen or lower alkyl R is halogen, lower alkyl, chloro lower alkyl, lower alkoxy, or two adjacent R's together are methylenedioxy, and s is an integer from 0 to 5, Y' is a carboxylated Y unit, Z is a pivalolactone monomer unit, m represents the number of isobutylene monomer units in the copolymer, n represents the number of non-carboxylated vinylbenzene monomer units in the copolymer, p represents the number of carboxylated vinylbenzene monomer units in the copolymer and is 5 to 100% of (n + p), m and (n + p) are in an m: (n + p) ratio of 2:1 to 1000:1, q represents the number of pivalolactone monomer units per polypivalolactone side chain graft and is in the range of 2 to 500, r represents the number of polypivalolactone side chain grafts in the graft copolymer and is substantially equal to p, X, y and Y' are randomly interconnected through carbon to carbon linkages with single Y and Y' units predominantly connected only to X units, Z q is a single polypivalolactone side chain grafted to a Y' unit through the carboxyl group, and (Z q ) r is 3 to 80% by weight of the graft copolymer, and the copolymer has an X m Y n Y' p equivalent weight per carboxyl group of 200 to 1 × 10 5 .
Claim 3
Dependent Claim 38 words
The graft copolymer of claim 1 in which the non-carboxylated isobutylene/vinylbenzene copolymer from which the graft copolymer is obtained by carboxylation and grafting has a molecular weight in the range of 1000 to 5 × 10 6 .
Claim 4
Dependent Claim 21 words
The graft copolymer of claim 2 in which the vinylbenzene is selected from the group consisting of vinyltoluene, styrene and α-methylstyrene.
Claim 5
Dependent Claim 82 words
The graft copolymer of claim 3 in which the non-carboxylated substrate copolymer has a molecular weight in the range of 2000 to 2 × 10 6 , m: (n + p) is in a ratio of 5:1 to 600:1, there are 3 to 250 pivalolactone monomer units per polypivalolactone side chain graft, the pivalolactone is 5 to 60% by weight of the graft copolymer, and the copolymer has an equivalent weight per carboxyl group of 600 to 6 × 10 4 .
Claim 6
Dependent Claim 84 words
The graft copolymer of claim 3 in which the noncarboxylated substrate copolymer has a molecular weight in the range of 5000 to 1 × 10 6 , m: (n + p) is in a ratio of 8:1 to 440:1, there are 5 to 200 pivalolactone monomer units per polypivalolactone side chain graft, the amount of pivalolactone in the graft copolymer is 10 to 50% by weight, and the copolymer has an equivalent weight per carboxyl group of 1000 to 5 × 10 4 .
Claim 7
Dependent Claim 12 words
The graft copolymer of claim 5 in which the vinylbenzene is vinyltoluene.
Claim 8
Dependent Claim 12 words
The graft copolymer of claim 5 in which the vinylbenzene is styrene.
Claim 9
Dependent Claim 12 words
The graft copolymer of claim 5 in which the vinylbenzene is α-methylstyrene.

References Cited (Backward Citations)

US3562360A Cited
NL7003074A Cited
US3897513A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-20 1980-12-20 1981-06-21 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-20 1984-12-20 1985-06-21 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-20 1988-12-20 1989-06-21 $7700.00 Window Closed / Lapsed

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