US4030926A
Expired / Lapsed
US
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Light-sensitive material containing a dye-forming combination of a heterocyclic compound and a cyclic dihalodicarbonyl compound in a polymeric binder
Assignee: Agfa Gevaert AG
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Filing: 1975-07-07
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Granted: 1977-06-21
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Expires: 1995-07-07
Abstract
Abstract A storage medium for optical data recording comprises a dye-forming combination which on exposure to light within a first range of wavelengths reacts irreversibly to form a dye, but is substantially insensitive to light within a second range of wavelengths which is capable of energizing the dye to produce luminescence. The dye-forming combination consists of a heterocyclic compound of the formula I and of a cyclic dihalodicarbonyl compound of the formula II ##STR1## The symbols are defined in the specification. An example of formula I is benzofuran and an example of formula II is dibromomaleic anhydride.
Inventors
- 👤 Kurt-Rainer Stahlke
- 👤 Werner Krafft
- 👤 Rudolf Meyer
- 👤 Hans Jurgen Rosenkranz
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 20:20
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/675
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
278 words
A light sensitive storage material for optical data recording comprising in a supported or self-supporting layer comprised of a polymeric hydrophobic binder selected from the group consisting of homopolymers and copolymers of monomers which have copolymerizable olefinic double bonds, polyvinyl acetals and cellulose esters and a dye-forming combination of a heterocyclic compound of the formula ##STR5## X represents oxygen, sulfur or the group >N--R 3 , Y represents nitrogen or the group ≧C--R 4 , R 1 and R 2 , which may be the same or different represent hydrogen or an alkyl or aryl group of may together represent the group required for completing a condensed benzene or naphthalene ring which may be substituted, R 3 represents hydrogen or an alkyl or aryl group and R 4 represents hydrogen or an alkyl group; and of a cyclic dihalodicarbonyl compound of the formula ##STR6## in which Z represents oxygen or the group >N--R 6 or ##STR7## R 5 represents chlorine or bromine, R 6 represents hydrogen or an alkyl group and R 7 and R 8 , which may be the same or different represent hydrogen or an alkyl group said heterocyclic compound of formula I and said cyclic dihalodicarbonyl compound of formula II being in amounts effective to provide said dye-forming combination upon exposure to ultraviolet light in a first range of wavelengths with capability of forming an image which is in a state of luminescence upon exposure to ultraviolet light in a second range of wavelengths not including said first range, and in a proportion of said heterocyclic compound of formula I being in at least double the molar quantity of the compound of formula II.
Claim 2
Dependent Claim
278 words
A light sensitive storage material for optical data recording comprising in a supported or self-supporting layer comprised of a polymeric hydrophobic binder selected from the group consisting of homopolymers and copolymers of monomers which have copolymerizable olefinic double bonds, polyvinyl acetals and cellulose esters and a dye-forming combination of a heterocyclic compound of the formula ##STR5## X represents oxygen, sulfur or the group >N--R 3 , Y represents nitrogen or the group ≧C--R 4 , R 1 and R 2 , which may be the same or different represent hydrogen or an alkyl or aryl group of may together represent the group required for completing a condensed benzene or naphthalene ring which may be substituted, R 3 represents hydrogen or an alkyl or aryl group and R 4 represents hydrogen or an alkyl group; and of a cyclic dihalodicarbonyl compound of the formula ##STR6## in which Z represents oxygen or the group >N--R 6 or ##STR7## R 5 represents chlorine or bromine, R 6 represents hydrogen or an alkyl group and R 7 and R 8 , which may be the same or different represent hydrogen or an alkyl group said heterocyclic compound of formula I and said cyclic dihalodicarbonyl compound of formula II being in amounts effective to provide said dye-forming combination upon exposure to ultraviolet light in a first range of wavelengths with capability of forming an image which is in a state of luminescence upon exposure to ultraviolet light in a second range of wavelengths not including said first range, and in a proportion of said heterocyclic compound of formula I being in at least double the molar quantity of the compound of formula II.
Claim 3
Dependent Claim
20 words
Storage material according to claim 1, characterised in that the heterocyclic compound of formula I contained in it is benzofuran.
Claim 4
Dependent Claim
24 words
Storage material according to claim 1, characterised in that the cyclic dihalodicarbonyl compound contained in it is dibromomaleic acid anhydride or dibromomaleic acid imide.
Claim 5
Dependent Claim
43 words
Storage material according to claim 1, characterised in that it contains, as binder for the dye forming combination of formulas I and II, a homopolymer or copolymer of methacrylic acid alkyl esters in which the alkyl group contains 1 to 4 carbon atoms.
Claim 6
Dependent Claim
17 words
Storage material according to claim 4, characterised in that it contains polyacrylamide or polycarbonate as additional binder.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-06-20 | 1980-12-20 | 1981-06-21 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-06-20 | 1984-12-20 | 1985-06-21 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-06-20 | 1988-12-20 | 1989-06-21 | $7700.00 | Window Closed / Lapsed |