US4029708A
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Linear surfactant polymers formed from substituted amines and difunctional reactants
Assignee: ChampionX LLC
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Filing: 1975-02-10
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Granted: 1977-06-14
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Expires: 1995-02-10
Abstract
Abstract Linear surfactant polymers, useful in waterflooding processes and as emulsion breakers, can be prepared by reacting various amines, such as hexamethylene diamine, with monofunctional pendant groups, such as propylene oxide, and then further reacting the substituted amines with a difunctional reactant, such as epichlorohydrin, to produce the polymer. The polymers may be combined with certain water-soluble metal salts to improve their efficiency as emulsion breakers and as coagulants.
Inventors
- 👤 Paul L. Seitz
- 👤 Robert K. Gabel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 16:00
CPC Classifications
C; C08; C08G; C08G65/00; C08G65/02; C08G65/26; C08G65/2618; C08G65/2621; C08G65/2624
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
136 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is the reaction product of hexamethylene triamine and propylene oxide, said hexamethylene triamine being reacted with propylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is a glycol adduct of epichlorohdyrin formed by the reaction of one mole of polyethylene glycol of molecular weight 250 with two moles of epichlorohydrin said reaction being conducted at temperatures in the range of 60°-110° C. for 1-3 hours under reflux, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 2
Dependent Claim
136 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is the reaction product of hexamethylene triamine and propylene oxide, said hexamethylene triamine being reacted with propylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is a glycol adduct of epichlorohdyrin formed by the reaction of one mole of polyethylene glycol of molecular weight 250 with two moles of epichlorohydrin said reaction being conducted at temperatures in the range of 60°-110° C. for 1-3 hours under reflux, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 3
Dependent Claim
136 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant, wherein said substituted amine is the reaction product of hexamethylene triamine and ethylene oxide, said hexamethylene triamine being reacted with ethylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is a glycol adduct of epichlorohydrin formed by the reaction of one mole of polyethylene glycol of molecular weight 250 with two moles of epichlorohydrin said reaction being conducted at temperatures in the range of 60°-110° C. for 1-3 hours under reflux, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 4
Dependent Claim
136 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant, wherein said substituted amine is the reaction product of hexamethylene triamine and ethylene oxide, said hexamethylene triamine being reacted with ethylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is a glycol adduct of epichlorohydrin formed by the reaction of one mole of polyethylene glycol of molecular weight 250 with two moles of epichlorohydrin said reaction being conducted at temperatures in the range of 60°-110° C. for 1-3 hours under reflux, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 5
Dependent Claim
119 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant, wherein said substituted amine is the reaction product of dipropylene triamine and propylene oxide, said dipropylene triamine being reacted with propylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is a glycol adduct of polyglycol and epichlorohydrin said reaction being conducted at temperatures in the range of 60°-110° C. for 1-3 hours under reflux, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 6
Dependent Claim
119 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant, wherein said substituted amine is the reaction product of dipropylene triamine and propylene oxide, said dipropylene triamine being reacted with propylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is a glycol adduct of polyglycol and epichlorohydrin said reaction being conducted at temperatures in the range of 60°-110° C. for 1-3 hours under reflux, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 7
Dependent Claim
109 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant, wherein said substituted amine is the reaction product of hexamethylene diamine and a polyglycol adduct of epichlorohydrin formed by the reaction of four moles of mixed polyglycol with four moles of epichlorohydrin, said hexamethylene diamine being reacted with a polyglycol adduct of epichlorohydrin at a temperature of from 30°-220° C. for from 1-4 hours, said difunctional reactant is ethylene dichloride said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 8
Dependent Claim
109 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant, wherein said substituted amine is the reaction product of hexamethylene diamine and a polyglycol adduct of epichlorohydrin formed by the reaction of four moles of mixed polyglycol with four moles of epichlorohydrin, said hexamethylene diamine being reacted with a polyglycol adduct of epichlorohydrin at a temperature of from 30°-220° C. for from 1-4 hours, said difunctional reactant is ethylene dichloride said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 9
Dependent Claim
142 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is a reaction product of a mixture of hexamethylene diamine and hexamethylene triamine with a mixture of crude tall oil and a polyglycol reacted with one mole of epichlorohydrin, said hexamethylene diamine and hexamethylene triamine mixture being reacted with the tall oil and a polyglycol adduct formed by reacting a polyglycol with one mole of epichlorohydrin in a molar ratio of amine mixture to tall oil and polyglycol adduct of from 5:1 to 1:5 at a temperature of from 30°-220° C. for 1-4 hours, and said difunctional reactant is ethylene dichloride which is reacted with said substituted amine in a molar ratio of 5:1 to 1:5 at a temperature ranging from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 10
Dependent Claim
142 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is a reaction product of a mixture of hexamethylene diamine and hexamethylene triamine with a mixture of crude tall oil and a polyglycol reacted with one mole of epichlorohydrin, said hexamethylene diamine and hexamethylene triamine mixture being reacted with the tall oil and a polyglycol adduct formed by reacting a polyglycol with one mole of epichlorohydrin in a molar ratio of amine mixture to tall oil and polyglycol adduct of from 5:1 to 1:5 at a temperature of from 30°-220° C. for 1-4 hours, and said difunctional reactant is ethylene dichloride which is reacted with said substituted amine in a molar ratio of 5:1 to 1:5 at a temperature ranging from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 11
Dependent Claim
115 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is the reaction product of a mixture of hexamethylene diamine and hexamethylene triamine and crude tall oil, said hexamethylene diamine and hexamethylene triamine mixture being reacted with the crude tall oil in a molar ratio of tall oil to amine of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional amine is ethylene dichloride, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 12
Dependent Claim
115 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is the reaction product of a mixture of hexamethylene diamine and hexamethylene triamine and crude tall oil, said hexamethylene diamine and hexamethylene triamine mixture being reacted with the crude tall oil in a molar ratio of tall oil to amine of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional amine is ethylene dichloride, said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 13
Dependent Claim
96 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is the reaction product of ethylene diamine and propylene oxide, said ethylene diamine being reacted with propylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is 1,4-dichlorobutene-2 said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
Claim 14
Dependent Claim
96 words
A linear surfactant polymer formed by the reaction of a substituted amine with a difunctional reactant wherein said substituted amine is the reaction product of ethylene diamine and propylene oxide, said ethylene diamine being reacted with propylene oxide in a molar ratio of 5:1 to 1:5 at a temperature of from 30°-220° C. for from 1-4 hours, and said difunctional reactant is 1,4-dichlorobutene-2 said difunctional reactant being reacted with the substituted amine in a molar ratio of 5:1 to 1:5 at a temperature of from 100°-250° C. for a period of time ranging from 1-6 hours.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-06-13 | 1980-12-13 | 1981-06-14 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-06-13 | 1984-12-13 | 1985-06-14 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-06-13 | 1988-12-13 | 1989-06-14 | $7700.00 | Window Closed / Lapsed |