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US4029622A Expired / Lapsed US ⏱️ 0.0 years remaining

Non-aqueous polymer dispersions of water-soluble monomers

Assignee: Bayer AG
•
Filing: 1975-04-21
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Granted: 1977-06-14
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Expires: 1995-04-21
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Abstract

Abstract Stable non-aqueous dispersion of water-soluble polymers of extremely high molecular weight coupled with relatively low viscosity and rapid dilutability with water to form a polymer solution are obtained by polymerization of at least one water-soluble alpha , beta -monoolefinically unsaturated monomer such as acrylamide and dimethyl aminoethyl methacrylate in water-in-oil emulsion with the aid of at least one photo-initiator and UV-light, and azeotropical distillation from water, before or after the addition of a water-soluble wetting agent, to a residual water content of less than 5% by weight, based on polymer. The dispersions are eminently suitable for the preparation of aqueous solution, as retention agents for fillers and water-removal accelerators in the production of paper.

Inventors

  • 👤 Wilfried Keller
  • 👤 Friedhelm Muller

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 11:19
CPC Classifications
C; C08; C08J; C08J3/00; C08J3/02; C08J3/09; D; D21; D21H; D21H17/00; D21H17/20; D21H17/33; D21H17/34; C08J2300/00; C08J2300/14

Claims Analysis

Total Claims: 2
Claim 1
Independent Claim 185 words
A stable, storable, non-aqueous dispersion which is rapidly dilutable with water to form a polymer solution and whose average particle size of the dispersed phase is from 0.01 to 1μ, said dispersion consisting essentially of a. at least one water-soluble polymer having an average molecular weight of at least 5,000,000, b. a liquid aliphatic or aromatic hydrocarbon selected from the group consisting of toluene, decalin, n-paraffins, iso-paraffins and mixtures thereof and c. 5 to 20% by weight, based on the weight of the dispersion, of a water-soluble wetting agent selected from the group consisting of ethoxylated alkyl phenols and ethoxylated aralkyl phenols having from 8 to 20 carbon atoms in the alkyl and aralkyl moieties thereof, said dispersion having been obtained by polymerizing at least one water-soluble α,β-monoolefinically unsaturated monomer in a water-in-oil emulsion by means of at least one photo-initiator and UV light and subsequently removing water from said product of polymerization, either before or after the addition of said water-soluble wetting agent, to a residual water content of less than 5% by weight, based on the weight of the polymer in said dispersion.
Claim 2
Dependent Claim 185 words
A stable, storable, non-aqueous dispersion which is rapidly dilutable with water to form a polymer solution and whose average particle size of the dispersed phase is from 0.01 to 1μ, said dispersion consisting essentially of a. at least one water-soluble polymer having an average molecular weight of at least 5,000,000, b. a liquid aliphatic or aromatic hydrocarbon selected from the group consisting of toluene, decalin, n-paraffins, iso-paraffins and mixtures thereof and c. 5 to 20% by weight, based on the weight of the dispersion, of a water-soluble wetting agent selected from the group consisting of ethoxylated alkyl phenols and ethoxylated aralkyl phenols having from 8 to 20 carbon atoms in the alkyl and aralkyl moieties thereof, said dispersion having been obtained by polymerizing at least one water-soluble α,β-monoolefinically unsaturated monomer in a water-in-oil emulsion by means of at least one photo-initiator and UV light and subsequently removing water from said product of polymerization, either before or after the addition of said water-soluble wetting agent, to a residual water content of less than 5% by weight, based on the weight of the polymer in said dispersion.

References Cited (Backward Citations)

US2982749A Cited
US3284393A Cited
US3278506A Cited
US3258453A Cited
US3507840A Cited
US3826771A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-13 1980-12-13 1981-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-13 1984-12-13 1985-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-13 1988-12-13 1989-06-14 $7700.00 Window Closed / Lapsed

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