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US4029509A Expired / Lapsed US ⏱️ 0.0 years remaining

Positive process using a low coating weight silver halide

Assignee: EIDP Inc
•
Filing: 1975-11-17
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Granted: 1977-06-14
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Expires: 1995-11-17
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Abstract

Abstract A process for obtaining camera speed direct positive images which employs a photographic element comprising a film support, a layer of photosensitive silver halide, and a layer containing a colorant (e.g. colloidal silver). The silver halide layer is first imagewise exposed, and the latent image developed in the presence of a compound capable of producing sulfide ions e.g. thiourea, and then the photographic element is immersed in a chemical bleach which removes the silver image generated in the silver halide layer and removes the colorant in the areas corresponding to the exposed areas of the silver halide layer, leaving a direct positive image in those areas of the colorant-containing layer which are directly under the unexposed nonimage areas of the silver halide layer.

Inventors

  • 👤 Ralph Kingsley Blake, deceased

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 02:59
CPC Classifications
G; G03; G03C; G03C7/00; G03C7/28; G03C5/00; G03C5/26; G03C5/50

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 186 words
A process of forming an image in a photosensitive element that comprises a film support, a photosensitive silver halide layer, and an underlayer containing a chemically bleachable colorant selected from the group consisting of colloidal silver, colloidal mercury, colloidal palladium, colloidal copper, a copper film, a zinc film, a lead film, and a silver film; which process comprises: 1. imagewise exposing said photosensitive silver halide layer to actinic radiation, 2 developing the resulting latent image in said silver halide layer, 3. no sooner than step (2), treating said photosensitive element with a compound capable of generating sulfide ions under the conditions of treatment said compound selected from the group consisting of thiourea, substituted thioureas, mono-or di-N- substituted thioacetamides, dialkyl substituted dithiocarbamates, and 4. immersing said photosensitive element in a chemical bleach bath so as to chemically bleach the image in the silver halide layer and to bleach those areas of the colorant-containing layer which are under the image in the silver halide layer, leaving an image in those areas of the colorant-containing layer which are directly under the unexposed nonimage areas of the silver halide layer.
Claim 2
Dependent Claim 186 words
A process of forming an image in a photosensitive element that comprises a film support, a photosensitive silver halide layer, and an underlayer containing a chemically bleachable colorant selected from the group consisting of colloidal silver, colloidal mercury, colloidal palladium, colloidal copper, a copper film, a zinc film, a lead film, and a silver film; which process comprises: 1. imagewise exposing said photosensitive silver halide layer to actinic radiation, 2 developing the resulting latent image in said silver halide layer, 3. no sooner than step (2), treating said photosensitive element with a compound capable of generating sulfide ions under the conditions of treatment said compound selected from the group consisting of thiourea, substituted thioureas, mono-or di-N- substituted thioacetamides, dialkyl substituted dithiocarbamates, and 4. immersing said photosensitive element in a chemical bleach bath so as to chemically bleach the image in the silver halide layer and to bleach those areas of the colorant-containing layer which are under the image in the silver halide layer, leaving an image in those areas of the colorant-containing layer which are directly under the unexposed nonimage areas of the silver halide layer.
Claim 3
Dependent Claim 26 words
The process of claim 1 containing the additional step, not sooner than the step of chemically bleaching, of removing the bleached areas of said colorant-containing layer.
Claim 4
Dependent Claim 18 words
The process of claim 1 wherein said chemically bleachable colorant is a silver film deposited on the support.
Claim 5
Dependent Claim 11 words
The process of claim 1 wherein said colorant is colloidal silver.
Claim 6
Dependent Claim 15 words
The process of claim 4 wherein said compound capable of generating sulfide ions is thiourea.
Claim 7
Dependent Claim 19 words
The process of claim 4 wherein said bleach is an oxidizing bleach selected from potassium ferricyanide and cupric nitrate.
Claim 8
Dependent Claim 17 words
The process of claim 11 wherein said photosensitive silver halide layer is exposed through a half-tone screen.
Claim 9
Dependent Claim 159 words
A process of forming an image in a photosensitive element that comprises a clear polyester film support, a layer containing colloidal silver, and a photosensitive silver halide layer, which process comprises: 1. imagewise exposing said photosensitive silver halide layer to actinic radiation, 2. developing the resulting latent image in said silver halide layer, 3. treating said photosensitive element with thiourea, and 4. immersing said photosensitive element in a chemical bleach bath so as to chemically bleach the image in the silver halide layer and to bleach those areas of the colloidal silver-containing layer which are under the image in the silver halide layer, leaving an image in those areas of the colloidal silver-containing layer which are directly under the unexposed nonimage areas of the silver halide layer, 5. fixing the aforesaid image in the colloidal silver-containing layer by removal of the undeveloped silver halide and any bleach-generated silver salt, leaving a high density direct positive remaining on the support.
Claim 10
Dependent Claim 159 words
A process of forming an image in a photosensitive element that comprises a clear polyester film support, a layer containing colloidal silver, and a photosensitive silver halide layer, which process comprises: 1. imagewise exposing said photosensitive silver halide layer to actinic radiation, 2. developing the resulting latent image in said silver halide layer, 3. treating said photosensitive element with thiourea, and 4. immersing said photosensitive element in a chemical bleach bath so as to chemically bleach the image in the silver halide layer and to bleach those areas of the colloidal silver-containing layer which are under the image in the silver halide layer, leaving an image in those areas of the colloidal silver-containing layer which are directly under the unexposed nonimage areas of the silver halide layer, 5. fixing the aforesaid image in the colloidal silver-containing layer by removal of the undeveloped silver halide and any bleach-generated silver salt, leaving a high density direct positive remaining on the support.

References Cited (Backward Citations)

US2322001A Cited
US2875052A Cited
US2856284A Cited
US3178282A Cited
US3501298A Cited
US3737317A Cited
US3933496A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-13 1980-12-13 1981-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-13 1984-12-13 1985-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-13 1988-12-13 1989-06-14 $7700.00 Window Closed / Lapsed

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