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US4028483A Expired / Lapsed US ⏱️ 0.0 years remaining

EPDM interpolymers formed with unsaturated organosilanes

Assignee: DSM Copolymer Inc
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Filing: 1975-09-08
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Granted: 1977-06-07
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Expires: 1995-09-08
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Abstract

Abstract An interpolymer of ethylene, a monoolefin containing from 3-20 carbon atoms, a polyene, and an unsaturated organosilane in which the interpolymer is prepared by interpolymerization reaction in the presence of a Ziegler type catalyst.

Inventors

  • 👤 William C. Bond, Jr.
  • 👤 Harold J. Wahlborg

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 19:24
CPC Classifications
C; C08; C08F; C08F210/00; C08F210/16; C08F210/18; Y; Y10; Y10S; Y10S526/00; Y10S526/916

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 213 words
An interpolymer which is the product of the interpolymerization in the presence of a Ziegler type catalyst of monomers consisting essentially of (1) ethylene, (2) a monoolefin having from 3 to 20 carbon atoms, (3) a polyene selected from the group consisting of an open chain polyunsaturated hydrocarbon having from 4 to 20 carbon atoms and a polyunsaturated bridged ring hydrocarbon, and (4) an ethylenically unsaturated organosilane having the general formula R n SiX 4 -n in which X is a highly hydrolyzable group selected from the group consisting of a halogen and a tertiary amine, n is an integer from 1 to 3, and R is a group selected from the group consisting of hydrogen, alkyl, aryl, alkaryl, arylalkyl, cyclic or heterocyclic group, in which at least one of the R groups is a norbornenyl group, in which the ethylene and monoolefin are present in the interpolymer in the mole ratio of 20-95 moles ethylene to 80-5 moles monoolefin, the polyene is chemically bound in the interpolymer in an amount within the range of 0.1 to 10 mole percent of the total number of moles of ethylene, monoolefin and polyene, and the unsaturated organosilane is present in the polymer in an amount of more than 0.01% but less than 1.0% by weight.
Claim 2
Dependent Claim 213 words
An interpolymer which is the product of the interpolymerization in the presence of a Ziegler type catalyst of monomers consisting essentially of (1) ethylene, (2) a monoolefin having from 3 to 20 carbon atoms, (3) a polyene selected from the group consisting of an open chain polyunsaturated hydrocarbon having from 4 to 20 carbon atoms and a polyunsaturated bridged ring hydrocarbon, and (4) an ethylenically unsaturated organosilane having the general formula R n SiX 4 -n in which X is a highly hydrolyzable group selected from the group consisting of a halogen and a tertiary amine, n is an integer from 1 to 3, and R is a group selected from the group consisting of hydrogen, alkyl, aryl, alkaryl, arylalkyl, cyclic or heterocyclic group, in which at least one of the R groups is a norbornenyl group, in which the ethylene and monoolefin are present in the interpolymer in the mole ratio of 20-95 moles ethylene to 80-5 moles monoolefin, the polyene is chemically bound in the interpolymer in an amount within the range of 0.1 to 10 mole percent of the total number of moles of ethylene, monoolefin and polyene, and the unsaturated organosilane is present in the polymer in an amount of more than 0.01% but less than 1.0% by weight.
Claim 3
Dependent Claim 31 words
An interpolymer as claimed in claim 1 in which the ethylene and monoolefin are present in the interpolymer in the mole ratio of 45-90 moles ethylene to 55-10 moles of monoolefin.
Claim 4
Dependent Claim 28 words
An interpolymer as claimed in claim 1 in which the polyene is present in the interpolymer in an amount within the range of 0.1 to 3 mole percent
Claim 5
Dependent Claim 13 words
An interpolymer as claimed in claim 1 in which the monoolefin is propylene.
Claim 6
Dependent Claim 25 words
An interpolymer as claimed in claim 1 in which the interpolymerization is carried out in solvent solution in the presence of a Ziegler type catalyst.
Claim 7
Dependent Claim 15 words
An interpolymer as claimed in claim 1 in which the polyene is an alkylidene norbornene.
Claim 8
Dependent Claim 13 words
An interpolymer as claimed in claim 1 in which the polyene is 5-ethylidene-2-norbornene.
Claim 9
Dependent Claim 200 words
An interpolymer formed in the presence of a Ziegler type catalyst of monomers consisting essentially of ethylene, a monoolefin containing 3 to 20 carbon atoms, a polyene selected from the group consisting of an open chain polyunsaturated hydrocarbon containing 4 to 20 carbon atoms and a polyunsaturated bridged ring hydrocarbon, and an ethylenically unsaturated organosilane having the general formula R n SiX 4 -n in which X is a highly hydrolzable group selected from the group consisting of a halogen and a tertiary amine, n is an integer from 1 to 3 and R is a group selected from the group consisting of hydrogen, alkyl, aryl, alkaryl, arylalkyl, cyclic or heterocyclic groups in which at least one of the R groups is a norbornenyl group, in which the ethylene and monoolefin are present in the interpolymer in the mole ratio of 20-95 moles ethylene to 80-5 moles monoolefin, the polyene is chemically bound in the interpolymer in an amount within the range of 0.1 to 10 mole percent of the total number of moles of ethylene, monoolefin and polyene, and the unsaturated organosilane is present in the interpolymer in an amount more than 0.01% but less than 1.0% by weight.
Claim 10
Dependent Claim 200 words
An interpolymer formed in the presence of a Ziegler type catalyst of monomers consisting essentially of ethylene, a monoolefin containing 3 to 20 carbon atoms, a polyene selected from the group consisting of an open chain polyunsaturated hydrocarbon containing 4 to 20 carbon atoms and a polyunsaturated bridged ring hydrocarbon, and an ethylenically unsaturated organosilane having the general formula R n SiX 4 -n in which X is a highly hydrolzable group selected from the group consisting of a halogen and a tertiary amine, n is an integer from 1 to 3 and R is a group selected from the group consisting of hydrogen, alkyl, aryl, alkaryl, arylalkyl, cyclic or heterocyclic groups in which at least one of the R groups is a norbornenyl group, in which the ethylene and monoolefin are present in the interpolymer in the mole ratio of 20-95 moles ethylene to 80-5 moles monoolefin, the polyene is chemically bound in the interpolymer in an amount within the range of 0.1 to 10 mole percent of the total number of moles of ethylene, monoolefin and polyene, and the unsaturated organosilane is present in the interpolymer in an amount more than 0.01% but less than 1.0% by weight.
Claim 11
Dependent Claim 207 words
An interpolymer which is the product of the interpolymerizarion in the presence of a Ziegler type catalyst of monomers consisting essentially of (1) ethylene, (2) a monoolefin having from 3 to 20 carbon atoms, (3) a polyene selected from the group consisting of an open chain polyunsaturated hydrocarbon having from 4 to 20 carbon atoms and a polyunsaturated bridged ring hydrocarbon, and (4) a norbornenyl silane having the general formula R n SiX 4 -n in which X is a highly hydrolyzable group selected from the group consisting of a halogen and a tertiary amine, n is an integer from 1 to 3 and R is a group selected from the group consisting of hydrogen, alkyl, aryl, alkaryl, arylalkyl, cyclic or heterocyclic group in which at least one of the R groups is a norbornenyl group, in which the ethylene and monoolefin are present in the interpolymer in the mole percent of 20-95 moles ethylene to 80-5 moles monoolefin, the polyene is chemically bound in the interpolymer in an amount within the range of 0.1 to 10 mole percent of the total number of moles of ethylene, monoolefin and polyene, and the norbornenyl silane is present in the polymer in an amount up to 20% by weight.
Claim 12
Dependent Claim 207 words
An interpolymer which is the product of the interpolymerizarion in the presence of a Ziegler type catalyst of monomers consisting essentially of (1) ethylene, (2) a monoolefin having from 3 to 20 carbon atoms, (3) a polyene selected from the group consisting of an open chain polyunsaturated hydrocarbon having from 4 to 20 carbon atoms and a polyunsaturated bridged ring hydrocarbon, and (4) a norbornenyl silane having the general formula R n SiX 4 -n in which X is a highly hydrolyzable group selected from the group consisting of a halogen and a tertiary amine, n is an integer from 1 to 3 and R is a group selected from the group consisting of hydrogen, alkyl, aryl, alkaryl, arylalkyl, cyclic or heterocyclic group in which at least one of the R groups is a norbornenyl group, in which the ethylene and monoolefin are present in the interpolymer in the mole percent of 20-95 moles ethylene to 80-5 moles monoolefin, the polyene is chemically bound in the interpolymer in an amount within the range of 0.1 to 10 mole percent of the total number of moles of ethylene, monoolefin and polyene, and the norbornenyl silane is present in the polymer in an amount up to 20% by weight.
Claim 13
Dependent Claim 20 words
An interpolymer as claimed in claim 9 in which the norbornenyl silane is in the form of the corresponding silanol.
Claim 14
Dependent Claim 14 words
An interpolymer as claimed in claim 9 in which the norbornenyl silane is 7-isopropylidene-5-trichlorosilyl-2-norbornene.
Claim 15
Dependent Claim 28 words
An interpolymer as claimed in claim 11 in which the 7-isopropylidene-5-trichlorosilyl-2-norbornene is present in the interpolymer in an amount within the range of 0.05 to 20% by weight.
Claim 16
Dependent Claim 28 words
An interpolymer as claimed in claim 11 in which the 7-isopropylidene-5-trichlorosilyl-2-norbornene is present in the interpolymer in an amount within the range of 0.1 to 10% by weight.
Claim 17
Dependent Claim 13 words
An interpolymer as claimed in claim 9 in which the monoolefin is propylene.
Claim 18
Dependent Claim 15 words
An interpolymer as claimed in claim 9 in which the polyene is an alkylidene norbornene.
Claim 19
Dependent Claim 13 words
An interpolymer as claimed in claim 9 in which the polyene is 5-ethylidene-2-norbornene.

References Cited (Backward Citations)

US2847409A Cited
US3240768A Cited
US3375236A Cited
US3644306A Cited
US3577399A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-06 1980-12-06 1981-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-06 1984-12-06 1985-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-06 1988-12-06 1989-06-07 $7700.00 Window Closed / Lapsed

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