US4028476A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Transparent polyamide armor
Assignee: Phillips Petroleum Co
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Filing: 1975-10-22
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Granted: 1977-06-07
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Expires: 1995-10-22
Abstract
Abstract A lightweight, transparent armor shield formed from a transparent, polymeric material formed by the polymerization of A. at least one compound having the general formula ##STR1## wherein each R is individually selected from the group consisting of --H and --CH 3 ; and B. at least one polycarboxylic acid having from 6 to 26 carbon atoms.
Inventors
- 👤 Roger F. Kleinschmidt
- 👤 Robert W. Campbell
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-27 19:24
CPC Classifications
F; F41; F41H; F41H5/00; F41H5/02; C; C08; C08G; C08G69/00; C08G69/02; C08G69/26; C08G69/265; Y; Y10; Y10S; Y10S428/00; Y10S428/911; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31725
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
217 words
A lightweight, transparent armor shield having a thickness of about 1/32 inch to about 2 inches, consisting essentially of a transparent, substantially amonphouse polymeric material having an inherent viscosity of at least about 0.6 formed by the polymerization of: A. at least one compound having the general formula ##STR7## wherein each R is individually selected from the group consisting of hydrogen and --CH 3 ; and b. at least one polycarboxylic acid having from 6 to 26 carbon atoms per molecule selected from the group consisting of: a. straight chain dicarboxylic acids having from 6 to 18 carbon atoms, b. phenylidane dicarboxylic acids having the general formula ##STR8## wherein each R' is selected from the group consisting of hydrogen and alkyl radicals having from 1 to 3 carbon atoms; c. tricarboxylic acids having the general formula R"(CO 2 H) 3 , wherein R" is a trivalent saturated or aromatic hydrocarbon radical having from 3 to 12 carbon atoms, d. bis(carboxyphenyl)methanes having the general formula ##STR9## wherein R is --H or --CH 3 , and e. mixtures thereof wherein an armor shield having a thickness of about 1/4 inch is capable of having a V 50 rating of at least about 878 fps, as determined according to MID-STD-662A, when fired at by a .22 califre 17-grain fragment-simulating projectile.
Claim 2
Dependent Claim
217 words
A lightweight, transparent armor shield having a thickness of about 1/32 inch to about 2 inches, consisting essentially of a transparent, substantially amonphouse polymeric material having an inherent viscosity of at least about 0.6 formed by the polymerization of: A. at least one compound having the general formula ##STR7## wherein each R is individually selected from the group consisting of hydrogen and --CH 3 ; and b. at least one polycarboxylic acid having from 6 to 26 carbon atoms per molecule selected from the group consisting of: a. straight chain dicarboxylic acids having from 6 to 18 carbon atoms, b. phenylidane dicarboxylic acids having the general formula ##STR8## wherein each R' is selected from the group consisting of hydrogen and alkyl radicals having from 1 to 3 carbon atoms; c. tricarboxylic acids having the general formula R"(CO 2 H) 3 , wherein R" is a trivalent saturated or aromatic hydrocarbon radical having from 3 to 12 carbon atoms, d. bis(carboxyphenyl)methanes having the general formula ##STR9## wherein R is --H or --CH 3 , and e. mixtures thereof wherein an armor shield having a thickness of about 1/4 inch is capable of having a V 50 rating of at least about 878 fps, as determined according to MID-STD-662A, when fired at by a .22 califre 17-grain fragment-simulating projectile.
Claim 3
Dependent Claim
11 words
The shield of claim 1 wherein said compound (A) is 2,2-bis(4-aminocyclohexyl)propane.
Claim 4
Dependent Claim
24 words
The shield of claim 2 wherein said acid (B) is at least one straight chain dicarboxylic acid having from 6 to 18 carbon atoms.
Claim 5
Dependent Claim
29 words
The shield of claim 3 wherein said acid (B) is a mixture of azelaic acid and adipic acid in a mole ratio of azelaic to adipic of about 60:40.
Claim 6
Dependent Claim
12 words
The shield of claim 3 wherein said acid (B) is azelaic acid.
Claim 7
Dependent Claim
11 words
The shield of claim 1 wherein said compound (A) is bis(4-aminocyclohexyl)methane.
Claim 8
Dependent Claim
53 words
The shield of claim 6 wherein said acid (B) is a mixture of at least one straight chain dicarboxylic acid having from 6 to 18 carbon atoms and at least one bis(carboxyphenyl)methane having the general formula ##STR10## wherein each R is individually selected from the group consisting of hydrogen and --CH 3 .
Claim 9
Dependent Claim
33 words
The shield of claim 7 wherein said straight chain dicarboxylic acid is present in said acid mixture in an approximate amount ranging from 15 to 85 mole percent of the total carboxylic acids.
Claim 10
Dependent Claim
53 words
The shield of claim 6 wherein said acid (B) is a mixture of straight chain dicarboxylic acids, wherein the average number of carbon atoms per molecule of said acid is at least 7, and wherein said compound (A) has a trans,trans isomer content of less than 40 percent of its total geometric isomers.
Claim 11
Dependent Claim
53 words
The shield of claim 6 wherein said compound (A) has a trans,trans isomer content of at least 40 percent of its total geometric isomers and said acid (B) is a mixture of acids comprising about 50 to 70 mole percent dodecanedioic acid and about 30 to 50 mole percent suberic and/or azelaic acid.
Claim 12
Dependent Claim
59 words
The shield of claim 6 wherein said acid (B) is a mixture of at least one phenylindanedicarboxylic acid having the general formula ##STR11## wherein each R' is individually selected from the group consisting of hydrogen and alkyl having from 1 to 3 carbon atoms, and at least one straight chain dicarboxylic acid having from 6 to 18 carbon atoms.
Claim 13
Dependent Claim
33 words
The shield of claim 11 wherein said straight chain dicarboxylic acid is present in said acid mixture in an approximate amount ranging from 15 to 85 mole percent of the total carboxylic acids.
Claim 14
Dependent Claim
40 words
The shield of claim 6 wherein said acid (B) is a mixture of at least one straight chain dicarboxylic acid having from 6 to 18 carbon atoms and at least one tricarboxylic acid having from 6 to 15 carbon atoms.
Claim 15
Dependent Claim
31 words
The shield of claim 13 wherein said tricarboxylic acid is present in said acid mixture in an approximate amount ranging from 5 to 60 mole percent of the total carboxylic acids.
Claim 16
Dependent Claim
17 words
The shield of claim 1 wherein said thickness ranges from about 1/16 inch to about 1 inch.
Claim 17
Dependent Claim
23 words
The shield of claim 4 having a thickness of about 1/4 inch and an areal density of about 22 ounces per square foot.
Claim 18
Dependent Claim
23 words
The shield of claim 5 having a thickness of about 1/4 inch and an areal density of about 122 ounces per square foot.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-06-06 | 1980-12-06 | 1981-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-06-06 | 1984-12-06 | 1985-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-06-06 | 1988-12-06 | 1989-06-07 | $7700.00 | Window Closed / Lapsed |