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US4028295A Expired / Lapsed US ⏱️ 0.0 years remaining

Hydrophilic polymer and contact lens

Assignee: W-J (DELAWARE) Inc
•
Filing: 1976-01-08
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Granted: 1977-06-07
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Expires: 1996-01-08
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Abstract

Abstract A hydrophilic polymer and contact lens made therefrom, said polymer consisting essentially of a diester-free glycol monoester of acrylic or methacrylic acid and a comonomer having the formula: <IMAGE> wherein R is a C1 to C4 straight or branched chain alkoxy group, R' is a C2 to C3 straight or branched chain alkylene group, X is hydrogen or a methyl group, m is either 1 or 0, and n is an integer from 1 to 20.

Inventors

  • 👤 Samuel Loshaek

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 20:08
CPC Classifications
G; G02; G02B; G02B1/00; G02B1/04; G02B1/041; G02B1/043; C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/26; C08F220/28; C08F220/282

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 136 words
A contact lens consisting essentially of hydrated polymer consisting essentially of, for each 100% by weight, about 70 to 90% by weight of a hydroxy C 2 -C 4 alkyl monoester of acrylic or methacrylic acid containing less than 0.1% by weight of a diester and 10 to 30% by weight of a comonomer having the general formula: ##STR4## wherein R is a C 1 to C 4 straight or branched chain alkoxy group, R' is a C 2 to C 3 straight or branched chain alkylene group, X is hydrogen or a methyl group, m is 0, and n is 1 or 2, said polymer having a water content of about 25 to 40% by weight, a linear swelling index of about 10 to 18%, and a Shore A hardness of about 20 to 65.
Claim 2
Dependent Claim 136 words
A contact lens consisting essentially of hydrated polymer consisting essentially of, for each 100% by weight, about 70 to 90% by weight of a hydroxy C 2 -C 4 alkyl monoester of acrylic or methacrylic acid containing less than 0.1% by weight of a diester and 10 to 30% by weight of a comonomer having the general formula: ##STR4## wherein R is a C 1 to C 4 straight or branched chain alkoxy group, R' is a C 2 to C 3 straight or branched chain alkylene group, X is hydrogen or a methyl group, m is 0, and n is 1 or 2, said polymer having a water content of about 25 to 40% by weight, a linear swelling index of about 10 to 18%, and a Shore A hardness of about 20 to 65.
Claim 3
Dependent Claim 31 words
The lens of claim 1 wherein the monoester is a hydroxyethyl or hydroxypropyl acrylate or methacrylate and the comonomer is selected from alkoxyalkyl acrylates, alkoxyalkyl methacrylates, alkylcarbitol acrylates, or alkylcarbitol methacrylates.
Claim 4
Dependent Claim 18 words
The lens of claim 1 wherein the monoester is hydroxyethyl methacrylate and the comonomer is an alkoxyalkyl methacrylate.
Claim 5
Dependent Claim 11 words
The lens of claim 1 wherein the comonomer is ethoxyethyl methacrylate.
Claim 6
Dependent Claim 139 words
A corneal contact lens consisting essentially of a hydrated polymer consisting essentially of, for each 100% by weight, about 70 to 90% by weight of a hydroxy C 2 14 C 4 alkyl monoester of acrylic or methacrylic acid containing less than 0.1% by weight of a diester and 10 to 30% by weight of a comonomer having the general formula: ##STR5## wherein R is a C 1 to C 4 straight or branched chain alkoxy group, R' is a C 2 to C 3 straight or branched chain alkylene group, X is hydrogen or a methyl group, m is 0 and n is 1 or 2, said polymer having a water content of about 25 to 40% by weight, a linear swelling index of about 10 to 18%, and a Shore A hardness of about 20 to 65.
Claim 7
Dependent Claim 139 words
A corneal contact lens consisting essentially of a hydrated polymer consisting essentially of, for each 100% by weight, about 70 to 90% by weight of a hydroxy C 2 14 C 4 alkyl monoester of acrylic or methacrylic acid containing less than 0.1% by weight of a diester and 10 to 30% by weight of a comonomer having the general formula: ##STR5## wherein R is a C 1 to C 4 straight or branched chain alkoxy group, R' is a C 2 to C 3 straight or branched chain alkylene group, X is hydrogen or a methyl group, m is 0 and n is 1 or 2, said polymer having a water content of about 25 to 40% by weight, a linear swelling index of about 10 to 18%, and a Shore A hardness of about 20 to 65.
Claim 8
Dependent Claim 19 words
The contact lens of claim 5 wherein the monoester is hydroxyethyl methacrylate and the comonomer is an alkoxyalkyl methacrylate.
Claim 9
Dependent Claim 24 words
The contact lens of claim 6 wherein the polymer comprises from about 70 to 90% hydroxyethyl methacrylate and about 10 to 30% ethoxyethyl methacrylate.
Claim 10
Dependent Claim 65 words
A corneal contact lens consisting essentially of a hydrated polymer consisting essentially of 70 to 90% hydroxyethyl methacrylate containing less than 0.1% by weight of diester and about 10 to 30% ethoxyethyl methacrylate, said polymer having a water content of about 25 to 40% by weight, a linear swelling index of about 10 to 18%, and a Shore A hardness of about 20 to 65.
Claim 11
Dependent Claim 65 words
A corneal contact lens consisting essentially of a hydrated polymer consisting essentially of 70 to 90% hydroxyethyl methacrylate containing less than 0.1% by weight of diester and about 10 to 30% ethoxyethyl methacrylate, said polymer having a water content of about 25 to 40% by weight, a linear swelling index of about 10 to 18%, and a Shore A hardness of about 20 to 65.

References Cited (Backward Citations)

US2440092A Cited
US3822089A Cited
US3893988A Cited
US3784540A Cited
US3850892A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-06-06 1980-12-06 1981-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-06-06 1984-12-06 1985-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-06-06 1988-12-06 1989-06-07 $7700.00 Window Closed / Lapsed

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