Photographic supports and elements utilizing photobleachable O-nitroarylidene dyes

Claim 2

A photographic element comprising a support and, coated thereon, a radiation-sensitive image recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein a photobleachable dye which has the following formula: ##STR25## wherein: a. K represents 0 or 1; b. m represents 0 or 1; c. each L represents a methine group; d. A represents oxygen, sulfur or N-R 1 ; e. R 1 represents an alkyl group, an alkenyl group or an aryl group; f. Z 1 represets the nonmetallic atoms necessary to complete a cyanine dye type heterocyclic ring whose skeletal atoms consist of the oxygen, sulfur or nitrogen atom of A, carbon atoms and one other atom chosen from the group consisting of carbon, oxygen, nitrogen, selenium and sulfur atoms; and g. Y represents the atoms necessary to complete a phenyl or naphthyl group.

Claim 3

A photographic element according to claim 1 in which said support is comprised of, in addition to said photobleachable dye, a transparent polymer.

Claim 4

A photographic element according to claim 2 in which said photobleachable dye is homogeneously blended with said transparent polymer.

Claim 5

A photographic element according to claim 2 in which said support is comprised of polyethylene or poly(ethylene terephthalate).

Claim 6

A photographic element according to claim 2 wherein said radiation-sensitive image-recording means is a photographic silver halide image-recording means.

Claim 7

A photographic element according to claim 2 wherein said radiation-sensitive image-recording means is an image-recording photothermographic means.

Claim 8

A photothermographic element according to claim 1 in which said radiation-sensitive image-recording means is an image-recording photothermographic layer comprising a. an oxidation-reduction image-forming combination comprising i. a reducing agent and ii. a heavy metal salt oxidizing agent, b. a catalyst for the oxidation-reduction image-forming combination, and c. a binder.

Claim 9

A photographic element according to claim 1 in which R 1 is an akyl group chosen from the class consisting of a sulfoalkyl group, a sulfatoalkyl group, an alkoxyakyl group, an acyloxyalkyl group, a dialkylaminoalkylene group and a cycloaminoalkylene group.

Claim 10

A photographic element according to claim 1 in which R 1 is an aryl group which is alkyl substituted.

Claim 11

A photographic element according to claim 1 wherein Z 1 represents the nonmetallic atoms necessary to complete a thiazole nucleus, an oxazole nucleus, a selenazole nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, an indolenine nucleus, an imidazo[4,5-b]quinoxaline nucleus, a 3H-pyrrolo[2,3-b]pyridine nucleus or a thiazolo[4,5-b]quinoline nucleus.

Claim 12

A photographic element according to claim 10 wherein said dye is selected from: a. 2-(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline; b. 2-(2,4-dinitrobenzylidene)-3-ethyl-2,3-dihydrothiazolo[4,5-b]quinoline; c. 2-(2,4-dinitrobenzylidene)-3-ethyl-6-nitrobenzothiazoline; d. 2-(2,4-dinitrobenzylidene)-1,3,3-trimethylindolenine; and e. 4-(2,4-dinitrobenzylidene)-1-ethylquinoline.

Claim 13

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein 6-chloro-2-(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline.

Claim 14

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein 6-chloro-2-(2,4-dinitrobenzylidene)-1,3-diethyl-2,3-dihydro-1H-imidazo[4,5-b]quinoxaline.

Claim 15

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 4-(2,4-dinitrobenzylidene)-2,6-diphenyl-4H-pyran.

Claim 16

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 4-(2,4-dinitrobenzylidene)-2,6-diphenyl-4H-pyran.

Claim 17

In a photographic element comprising a support and, coated thereon, radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 2-(2,4-dinitrobenzylidene)-4,6-diphenyl-2H-pyran.

Claim 18

In a photographic element comprising a support and, coated thereon, radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 2-(2,4-dinitrobenzylidene)-4,6-diphenyl-2H-pyran.

Claim 19

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 2-(2,4-dinitrobenzylidene)-1,3-dithiolane.

Claim 20

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein as a photobleachable dye 2-(2,4-dinitrobenzylidene)-1,3-dithiolane.

Claim 21

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein a photobleachable dye having the following formula: ##STR26## wherein: a. k represents 0 or 1; b. m represents 0 or 1; c. each L represents a methine group; d. R 1 represents an alkyl group, an alkenyl group or an aryl group; e. Z 1 represents the nonmetallic atoms necessary to complete a cyanine dye type nucleus comprising a 5- to 6-membered heretocyclic nucleus selected from the group consisting of an oxazole nucleus, a thiazole nucleus, a selenazole nucleus, a 3,3-dialkylindolenine nucleus, and imidazo[4,5-b]quinoxaline nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, a 3H-pyrrolo-[2,3-b]pyridine nucleus and a thiazolo[4,5-b]quinoline nucleus; and f. Y represents the atoms necessary to complete a nitro-substituted phenyl or naphthyl group, a nitro-substituted phenyl or 1-naphthyl group having a 4-ring position electron-withdrawing group, a nitro-substituted phenyl group having 4- and 6-position electron-withdrawing groups, or a nitro-substituted phenyl group having a 6-position electron-withdrawing group.

Claim 22

In a photographic element comprising a support and, coated thereon, a radiation-sensitive image-recording means, the improvement comprising an otherwise transparent photographic film support having incorporated therein a photobleachable dye having the following formula: ##STR26## wherein: a. k represents 0 or 1; b. m represents 0 or 1; c. each L represents a methine group; d. R 1 represents an alkyl group, an alkenyl group or an aryl group; e. Z 1 represents the nonmetallic atoms necessary to complete a cyanine dye type nucleus comprising a 5- to 6-membered heretocyclic nucleus selected from the group consisting of an oxazole nucleus, a thiazole nucleus, a selenazole nucleus, a 3,3-dialkylindolenine nucleus, and imidazo[4,5-b]quinoxaline nucleus, a thiazoline nucleus, a pyridine nucleus, an imidazole nucleus, a quinoline nucleus, a 3H-pyrrolo-[2,3-b]pyridine nucleus and a thiazolo[4,5-b]quinoline nucleus; and f. Y represents the atoms necessary to complete a nitro-substituted phenyl or naphthyl group, a nitro-substituted phenyl or 1-naphthyl group having a 4-ring position electron-withdrawing group, a nitro-substituted phenyl group having 4- and 6-position electron-withdrawing groups, or a nitro-substituted phenyl group having a 6-position electron-withdrawing group.

Claim 23

A photographic element according to claim 16 in which said electron-withdrawing groups are chosen from the class consisting of nitro, ethoxycarbonyl and trifluoromethyl groups.

Claim 24

A photographic element according to claim 1 in which said dye is present in an amount sufficient to impart an optical density to said support of 0.20.

Claim 25

A photographic element according to claim 16 in which said dye is present in an amount sufficient to impart an optical density to said support of 0.50.