US4026361A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Treating wells with a temporarily thickening cellulose ether solution
Assignee: Shell USA Inc
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Filing: 1976-06-14
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Granted: 1977-05-31
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Expires: 1996-06-14
Abstract
Abstract In well treatments such as workovers, fracturing processes, etc., permeable subterranean earth formations are temporarily plugged by contacting them with self thickening-and-thinning liquid systems. The systems initially contain unhydrated cellulose ether dispersed in aqueous liquid solutions of buffering agents, pH-increasing reactants and pH-decreasing reactants. The system components are arranged so that the cellulose ether hydration is first delayed by a buffer-maintained acidity, then is accelerated by an increasing pH and, subsequently, the high viscosity due to the dissolved hydrated cellulose ether is reduced by an acid-induced hydrolysis of the ether.
Inventors
- 👤 Randolph H. Knapp
- 👤 Edwin A. Richardson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 18:22
CPC Classifications
E; E21; E21B; E21B43/00; E21B43/25; E21B43/26; E21B43/261; C; C09; C09K; C09K8/00; C09K8/50; C09K8/504; C09K8/506; C09K8/508; C09K8/514
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
225 words
A process for temporarily plugging a subterranean earth formation in or around the borehole of a well, comprising: buffering an aqueous solution to retain a pH of from about 2 to 6 while a selected amount of hydroxyl ions are being added to the solution; dissolving in the aqueous solution a reactive compound that gradually yields enough hydroxyl ions to overcome the buffering and make the solution at least substantially alkaline; dissolving in the aqueous solution a reactive compound that reacts more slowly than the hydroxyl ion-yielding reactant but yields enough hydrogen ions to subsequently make the solution significantly acidic; dispersing in the aqueous solution an unhydrated cellulose ether which hydrates relatively slowly in a significantly acidic aqueous liquid, hydrates relatively rapidly in a substantially alkaline aqueous liquid and, when hydrated, dissolves in an aqueous liquid to form a relatively viscous solution; adjusting the compositions and concentrations of the materials dissolved and dispersed in the aqueous liquid relative to the time-temperature exposure of fluid flowed into contact with the subterranean earth formation and the extent and duration selected for the viscosity of a fluid temporarily plugging the earth formation; and flowing the aqueous liquid into contact with the subterranean earth formation so that the selected extent of viscosity is exhibited for the selected time while the solution is in contact with the subterranean earth formation.
Claim 2
Dependent Claim
225 words
A process for temporarily plugging a subterranean earth formation in or around the borehole of a well, comprising: buffering an aqueous solution to retain a pH of from about 2 to 6 while a selected amount of hydroxyl ions are being added to the solution; dissolving in the aqueous solution a reactive compound that gradually yields enough hydroxyl ions to overcome the buffering and make the solution at least substantially alkaline; dissolving in the aqueous solution a reactive compound that reacts more slowly than the hydroxyl ion-yielding reactant but yields enough hydrogen ions to subsequently make the solution significantly acidic; dispersing in the aqueous solution an unhydrated cellulose ether which hydrates relatively slowly in a significantly acidic aqueous liquid, hydrates relatively rapidly in a substantially alkaline aqueous liquid and, when hydrated, dissolves in an aqueous liquid to form a relatively viscous solution; adjusting the compositions and concentrations of the materials dissolved and dispersed in the aqueous liquid relative to the time-temperature exposure of fluid flowed into contact with the subterranean earth formation and the extent and duration selected for the viscosity of a fluid temporarily plugging the earth formation; and flowing the aqueous liquid into contact with the subterranean earth formation so that the selected extent of viscosity is exhibited for the selected time while the solution is in contact with the subterranean earth formation.
Claim 3
Dependent Claim
17 words
The process of claim 1 in which the fluid described is used as a formation fracturing fluid.
Claim 4
Dependent Claim
21 words
The process of claim 1 in which the fluid described is used as a temporary diverting fluid in a well treatment.
Claim 5
Dependent Claim
16 words
The process of claim 1 in which the fluid described is used as a workover fluid.
Claim 6
Dependent Claim
37 words
The process of claim 1 in which the fluid described is used to temporarily plug one permeable formation while another fluid is injected into a second permeable formation both of which are in communication with a well.
Claim 7
Dependent Claim
15 words
The process of claim 1 in which the hydroxyl ion-yielding compound is a water-soluble amide.
Claim 8
Dependent Claim
20 words
The process of claim 1 in which the hydrogen ion-yielding compound is a water-soluble alcohol ester of a water-soluble acid.
Claim 9
Dependent Claim
28 words
The process of claim 1 in which the solution is buffered with equimolar amounts of acetic acid and sodium acetate and the hydroxyl ion-yielding compound is sodium cyanate.
Claim 10
Dependent Claim
14 words
The process of claim 8 in which the hydrogen ion-yielding compound is methyl formate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-30 | 1980-11-29 | 1981-05-31 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-30 | 1984-11-29 | 1985-05-31 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-30 | 1988-11-29 | 1989-05-31 | $7700.00 | Window Closed / Lapsed |