US4025790A
Expired / Lapsed
US
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Method for separating isotopes by means of lasers
Assignee: Uranit GmbH
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Filing: 1975-12-11
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Granted: 1977-05-24
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Expires: 1995-12-11
Abstract
Abstract In a procedure for selectively separating the isotopes of a multi-isotopic element by forming a gas of isotopic compounds of the element, selectively exciting the molecules of one isotopic compound by application of laser radiation thereto, and separating the excited molecules from the other components of the gas by physical or chemical means, the efficiency of the separation is improved by passing the gas, prior to laser excitation, through a nozzle to cause it to undergo adiabatic expansion to form an undercooled gas stream, and applying the laser radiation to the gas stream.
Inventors
- 👤 Heinz Leonhard Jetter
- 👤 Karl Gurs
- 👤 Wolfgang Englisch
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 17:56
CPC Classifications
B; B01; B01D; B01D59/00; B01D59/34
Claims Analysis
Total Claims: 24
Claim 1
Independent Claim
90 words
Method for separating the different isotopes of an element having a plurality of isotopes, by forming a gas from isotopic compounds of the element, selectively exciting the molecules of one isotopic compound of the gas by applying laser radiation thereto, and separating the excited molecules by physical or chemical means, wherein prior to laser excitation such gas is conducted through a nozzle to cause it to undergo adiabatic expansion to form an undercooled gas stream, and the step of exciting the molecules involves applying laser radiation to the gas stream.
Claim 2
Dependent Claim
90 words
Method for separating the different isotopes of an element having a plurality of isotopes, by forming a gas from isotopic compounds of the element, selectively exciting the molecules of one isotopic compound of the gas by applying laser radiation thereto, and separating the excited molecules by physical or chemical means, wherein prior to laser excitation such gas is conducted through a nozzle to cause it to undergo adiabatic expansion to form an undercooled gas stream, and the step of exciting the molecules involves applying laser radiation to the gas stream.
Claim 3
Dependent Claim
36 words
Method as defined in claim 1 wherein the step of forming the gas stream further includes stripping the edge regions of the undercooled gas stream away from the central portion thereof with the aid of baffles.
Claim 4
Dependent Claim
53 words
Method as defined in claim 1 wherein the nozzle is formed, and the expansion ratio is selected, for causing the temperature in the gas stream to be as low as possible and for producing substantial cooling of the inner degrees of freedom of the molecules while preventing annoying condensation and attendant dimer formation.
Claim 5
Dependent Claim
17 words
Method as defined in claim 1 wherein the isotopic compound gas is mixed with an additional gas.
Claim 6
Dependent Claim
47 words
Method as defined in claim 4 wherein the additional gas is a gas which has a high adiabatic coefficient, H = C p /C v , and thus produces increased cooling of the molecular gas in the gas stream with simultaneous suppression of condensation and dimer formation.
Claim 7
Dependent Claim
14 words
Method as defined in claim 5 wherein the additional gas is a noble gas.
Claim 8
Dependent Claim
70 words
Method as defined in claim 1 wherein the gas stream is given a selected velocity and said step of applying laser radiation includes orienting the laser radiation beam relative to the gas stream in a manner to shift the absorption spectrum of the gas in frequency as a result of the Doppler effect in a manner to cause substantially only molecules of the one isotopic compound to experience energy absorption.
Claim 9
Dependent Claim
58 words
Method as defined in claim 1 wherein said step of applying laser radiation is carried out by means of a laser with fixed emmission frequency and includes influencing the laser radiation by an optoacoustic modulator to set the wavelength of such radiation to a value favorable for selective energy absorption by the molecules of the one isotopic compound.
Claim 10
Dependent Claim
25 words
Method as defined in claim 1 wherein the isotopic compound gas is UF 6 and the laser radiation is produced by a hydrogen halide laser.
Claim 11
Dependent Claim
13 words
Method as defined in claim 9 wherein the laser is an HF laser.
Claim 12
Dependent Claim
13 words
Method as defined in claim 9 wherein the laser is an HC1 laser.
Claim 13
Dependent Claim
36 words
Method as defined in claim 1 wherein the isotopic compound gas is UF 6 and the laser radiation is produced by a laser which operates with a gaseous compound of carbon as the laser active material.
Claim 14
Dependent Claim
18 words
Method as defined in claim 12 wherein the laser active material is CO, COS or CS 2 .
Claim 15
Dependent Claim
43 words
Method as defined in claim 1 wherein the step of separating the excited molecules is effected by chemical conversion and includes providing a reactant for the chemical conversion by introducing a further gas stream containing such reactant into the isotopic compound gas stream.
Claim 16
Dependent Claim
24 words
Method as defined in claim 14 wherein the isotopic compound gas is UF 6 and the reactant is NH 3 , HCl, or HBr.
Claim 17
Dependent Claim
24 words
Method as defined in claim 14 wherein the step of separating further includes subjecting the reaction products to fractional condensation to effect separation thereof.
Claim 18
Dependent Claim
37 words
Method as defined in claim 1 wherein the step of separating the excited molecules is effected by chemical conversion and includes introducing the undercooled gas stream into a gas-dynamic condenser containing the reactant for the chemical conversion.
Claim 19
Dependent Claim
24 words
Method as defined in claim 17 wherein the isotopic compound gas is UF 6 and the reactant is NH 3 , HCl, or HBr.
Claim 20
Dependent Claim
24 words
Method as defined in claim 17 wherein the step of separating further includes subjecting the reaction products to fractional condensation to effect separation thereof.
Claim 21
Dependent Claim
38 words
Method as defined in claim 1 wherein the step of separating is carried by subjecting the gas stream, after selective excitation, to a plurality of optical excitation steps for selectively dissociating the molecules of the one isotopic compound.
Claim 22
Dependent Claim
39 words
Method as defined in claim 1 wherein the step of separating is carried out by subjecting the gas stream, after selective excitation, to a plurality of optical excitation steps for selectively ionizing the molecules of the one isotopic compound.
Claim 23
Dependent Claim
23 words
Method as defined in claim 21 further comprising separating the ionized molecules from the gas stream by the application of an electric field.
Claim 24
Dependent Claim
23 words
Method as defined in claim 21 further comprising separating the ionized molecules from the gas stream by the application of a magnetic field.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-23 | 1980-11-22 | 1981-05-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-23 | 1984-11-22 | 1985-05-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-23 | 1988-11-22 | 1989-05-24 | $7700.00 | Window Closed / Lapsed |