US4025694A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Magnetic recording medium having segmented copolyester binder
Assignee: 3M Co
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Filing: 1975-06-30
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Granted: 1977-05-24
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Expires: 1995-06-30
Abstract
Abstract Magnetic recording tape, the binder of which is a segmented copolyester of crystallizable ester units ##STR1## and amorphous ester units ##STR2## where R 1 may be the divalent radical of adipic acid, R 2 may be the divalent radical of 1,4-cyclohexanedimethanol, R 3 may be R 1 or the divalent radical of C 36 dimer acid, R 4 may be R 2 or the divalent radical of a polyetherglycol of 200-4000 molecular weight.
Inventors
- 👤 Wayne A. Pletcher
- 👤 Russell L. Vermillion
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 21:05
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/672; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/199; C09; C09J; C09J167/00; C09J167/02; C09J167/025; Y; Y10; Y10S; Y10S428/00; Y10S428/90; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31681; Y10T428/31786; Y10T428/31797
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
260 words
Magnetic recording medium comprising a nonmagnetizable backing member bearing a coating of magnetizable particles in a binder, which binder consists essentially of a thermoplastic segmented copolyester consisting essentially of about 25 to 75 percent by weight of amorphous ester units and 75 to 25 percent by weight of crystallizable ester units joined through ester linkages, the crystallizable ester units being of the formula ##STR5## and the amorphous ester units being of the formula ##STR6## wherein R 1 is primarily tetramethylene, phenylene and/or naphthalene, R 2 consists of divalent radicals remaining after removal of the hydroxyl groups of one or more saturated aliphatic diols containing 2-12 carbon atoms, R 3 is R 1 or R 5 where R 5 consists of divalent radicals remaining after removal of the carboxyl groups of saturated aliphatic dimer acids and contains 22-50 carbon atoms, and R 4 is R 2 or R 6 where R 6 consists of divalent radicals remaining after removal of the terminal hydroxyl groups of long chain aliphatic diols having average molecular weights of 200-4000, at least one of R 3 and R 4 in each amorphous ester unit is R 5 or R 6 , and where R 1 is essentially entirely aromatic, the copolyester contains at least 50 percent by weight of amorphous ester units, and said copolyester has a DTA melting temperature of from about 65° to 150° C., an inherent viscosity of at least 0.5 dl/g at 25° C., as measured in 0.3 g/dl solution in chloroform at 25° C., and a Tg less than 0° C.
Claim 2
Dependent Claim
260 words
Magnetic recording medium comprising a nonmagnetizable backing member bearing a coating of magnetizable particles in a binder, which binder consists essentially of a thermoplastic segmented copolyester consisting essentially of about 25 to 75 percent by weight of amorphous ester units and 75 to 25 percent by weight of crystallizable ester units joined through ester linkages, the crystallizable ester units being of the formula ##STR5## and the amorphous ester units being of the formula ##STR6## wherein R 1 is primarily tetramethylene, phenylene and/or naphthalene, R 2 consists of divalent radicals remaining after removal of the hydroxyl groups of one or more saturated aliphatic diols containing 2-12 carbon atoms, R 3 is R 1 or R 5 where R 5 consists of divalent radicals remaining after removal of the carboxyl groups of saturated aliphatic dimer acids and contains 22-50 carbon atoms, and R 4 is R 2 or R 6 where R 6 consists of divalent radicals remaining after removal of the terminal hydroxyl groups of long chain aliphatic diols having average molecular weights of 200-4000, at least one of R 3 and R 4 in each amorphous ester unit is R 5 or R 6 , and where R 1 is essentially entirely aromatic, the copolyester contains at least 50 percent by weight of amorphous ester units, and said copolyester has a DTA melting temperature of from about 65° to 150° C., an inherent viscosity of at least 0.5 dl/g at 25° C., as measured in 0.3 g/dl solution in chloroform at 25° C., and a Tg less than 0° C.
Claim 3
Dependent Claim
24 words
Magnetic recording medium as defined in claim 1 wherein only one of R 3 and R 4 is R 5 or R 6 .
Claim 4
Dependent Claim
19 words
Magnetic recording medium as defined in claim 1 wherein R 1 is primarily the divalent radical of adipic acid.
Claim 5
Dependent Claim
20 words
Magnetic recording medium as defined in claim 1 wherein R 2 is cycloaliphatic and contains up to 8 carbon atoms.
Claim 6
Dependent Claim
20 words
Magnetic recording medium as defined in claim 1 wherein R 3 is the divalent radical of C 36 dimer acid.
Claim 7
Dependent Claim
18 words
Magnetic recording medium as defined in claim 1 wherein R 4 is poly(oxyethylene)glycol, poly(oxypropylene)glycol, poly(oxytetramethylene)glycol and/or copolymers thereof.
Claim 8
Dependent Claim
15 words
Magnetic recording medium as defined in claim 1 wherein R 1 is essentially entirely aromatic.
References Cited (Backward Citations)
CA793254A
Cited
US3023192A
Cited
US3512930A
Cited
US3651014A
Cited
US3832314A
Cited
US3941904A
Cited
US3766146A
Cited
US3763109A
Cited
US3775373A
Cited
US3775374A
Cited
US3775375A
Cited
US3932326A
Cited
US3891604A
Cited
US3890279A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-23 | 1980-11-22 | 1981-05-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-23 | 1984-11-22 | 1985-05-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-23 | 1988-11-22 | 1989-05-24 | $7700.00 | Window Closed / Lapsed |