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US4025694A Expired / Lapsed US ⏱️ 0.0 years remaining

Magnetic recording medium having segmented copolyester binder

Assignee: 3M Co
•
Filing: 1975-06-30
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Granted: 1977-05-24
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Expires: 1995-06-30
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Abstract

Abstract Magnetic recording tape, the binder of which is a segmented copolyester of crystallizable ester units ##STR1## and amorphous ester units ##STR2## where R 1 may be the divalent radical of adipic acid, R 2 may be the divalent radical of 1,4-cyclohexanedimethanol, R 3 may be R 1 or the divalent radical of C 36 dimer acid, R 4 may be R 2 or the divalent radical of a polyetherglycol of 200-4000 molecular weight.

Inventors

  • 👤 Wayne A. Pletcher
  • 👤 Russell L. Vermillion

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 21:05
CPC Classifications
C; C08; C08G; C08G63/00; C08G63/66; C08G63/668; C08G63/672; C08G63/02; C08G63/12; C08G63/16; C08G63/18; C08G63/199; C09; C09J; C09J167/00; C09J167/02; C09J167/025; Y; Y10; Y10S; Y10S428/00; Y10S428/90; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31678; Y10T428/31681; Y10T428/31786; Y10T428/31797

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 260 words
Magnetic recording medium comprising a nonmagnetizable backing member bearing a coating of magnetizable particles in a binder, which binder consists essentially of a thermoplastic segmented copolyester consisting essentially of about 25 to 75 percent by weight of amorphous ester units and 75 to 25 percent by weight of crystallizable ester units joined through ester linkages, the crystallizable ester units being of the formula ##STR5## and the amorphous ester units being of the formula ##STR6## wherein R 1 is primarily tetramethylene, phenylene and/or naphthalene, R 2 consists of divalent radicals remaining after removal of the hydroxyl groups of one or more saturated aliphatic diols containing 2-12 carbon atoms, R 3 is R 1 or R 5 where R 5 consists of divalent radicals remaining after removal of the carboxyl groups of saturated aliphatic dimer acids and contains 22-50 carbon atoms, and R 4 is R 2 or R 6 where R 6 consists of divalent radicals remaining after removal of the terminal hydroxyl groups of long chain aliphatic diols having average molecular weights of 200-4000, at least one of R 3 and R 4 in each amorphous ester unit is R 5 or R 6 , and where R 1 is essentially entirely aromatic, the copolyester contains at least 50 percent by weight of amorphous ester units, and said copolyester has a DTA melting temperature of from about 65° to 150° C., an inherent viscosity of at least 0.5 dl/g at 25° C., as measured in 0.3 g/dl solution in chloroform at 25° C., and a Tg less than 0° C.
Claim 2
Dependent Claim 260 words
Magnetic recording medium comprising a nonmagnetizable backing member bearing a coating of magnetizable particles in a binder, which binder consists essentially of a thermoplastic segmented copolyester consisting essentially of about 25 to 75 percent by weight of amorphous ester units and 75 to 25 percent by weight of crystallizable ester units joined through ester linkages, the crystallizable ester units being of the formula ##STR5## and the amorphous ester units being of the formula ##STR6## wherein R 1 is primarily tetramethylene, phenylene and/or naphthalene, R 2 consists of divalent radicals remaining after removal of the hydroxyl groups of one or more saturated aliphatic diols containing 2-12 carbon atoms, R 3 is R 1 or R 5 where R 5 consists of divalent radicals remaining after removal of the carboxyl groups of saturated aliphatic dimer acids and contains 22-50 carbon atoms, and R 4 is R 2 or R 6 where R 6 consists of divalent radicals remaining after removal of the terminal hydroxyl groups of long chain aliphatic diols having average molecular weights of 200-4000, at least one of R 3 and R 4 in each amorphous ester unit is R 5 or R 6 , and where R 1 is essentially entirely aromatic, the copolyester contains at least 50 percent by weight of amorphous ester units, and said copolyester has a DTA melting temperature of from about 65° to 150° C., an inherent viscosity of at least 0.5 dl/g at 25° C., as measured in 0.3 g/dl solution in chloroform at 25° C., and a Tg less than 0° C.
Claim 3
Dependent Claim 24 words
Magnetic recording medium as defined in claim 1 wherein only one of R 3 and R 4 is R 5 or R 6 .
Claim 4
Dependent Claim 19 words
Magnetic recording medium as defined in claim 1 wherein R 1 is primarily the divalent radical of adipic acid.
Claim 5
Dependent Claim 20 words
Magnetic recording medium as defined in claim 1 wherein R 2 is cycloaliphatic and contains up to 8 carbon atoms.
Claim 6
Dependent Claim 20 words
Magnetic recording medium as defined in claim 1 wherein R 3 is the divalent radical of C 36 dimer acid.
Claim 7
Dependent Claim 18 words
Magnetic recording medium as defined in claim 1 wherein R 4 is poly(oxyethylene)glycol, poly(oxypropylene)glycol, poly(oxytetramethylene)glycol and/or copolymers thereof.
Claim 8
Dependent Claim 15 words
Magnetic recording medium as defined in claim 1 wherein R 1 is essentially entirely aromatic.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-23 1980-11-22 1981-05-24 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-23 1984-11-22 1985-05-24 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-23 1988-11-22 1989-05-24 $7700.00 Window Closed / Lapsed

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