US4025580A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Modified styrenepolymers
Assignee: OI Glass Inc
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Filing: 1972-12-18
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Granted: 1977-05-24
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Expires: 1992-12-18
Abstract
Abstract There is disclosed a process for preparing chemically modified styrene polymers and copolymers which comprises treating a polystyrene or a styrene copolymer with an acyl halide in the presence of a Lewis acid so as to introduce ketone groups into the treated polymer or copolymer in an amount sufficient to promote environmental photodegradation of the treated polymer or copolymer. The resulting modified polymers may be used as degradable packaging materials, or as additives to promote the environmental degradation of polystyrene and related materials.
Inventors
- 👤 Lynn J. Taylor
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-01 01:38
CPC Classifications
C; C08; C08F; C08F8/00; C08F8/10; C08F8/50; Y; Y10; Y10S; Y10S260/00; Y10S260/43
Claims Analysis
Total Claims: 11
Claim 1
Independent Claim
122 words
A process for preparing mixtures of chemically modified styrene polymers or copolymers and unmodified polystyrene which comprises preparing said chemically modified styrene polymers or copolymers by reacting a styrene polymer or copolymer with an acylating agent in the presence of a Lewis Acid catalyst so as to introduce ketone groups into positions in the polymer or copolymer which are not adjacent to the atoms of the molecular chain, the amount of said acylating agent being sufficient to cause said ketone groups to form free radical intermediates upon photo-excitation and promote environmental photo-oxidative degradation of the polymer or copolymer; and subsequently incorporating said chemically modified polymers or copolymers into unmodified polystyrene in an amount sufficient to promote environmental photodegradation of the unmodified polymer.
Claim 2
Dependent Claim
122 words
A process for preparing mixtures of chemically modified styrene polymers or copolymers and unmodified polystyrene which comprises preparing said chemically modified styrene polymers or copolymers by reacting a styrene polymer or copolymer with an acylating agent in the presence of a Lewis Acid catalyst so as to introduce ketone groups into positions in the polymer or copolymer which are not adjacent to the atoms of the molecular chain, the amount of said acylating agent being sufficient to cause said ketone groups to form free radical intermediates upon photo-excitation and promote environmental photo-oxidative degradation of the polymer or copolymer; and subsequently incorporating said chemically modified polymers or copolymers into unmodified polystyrene in an amount sufficient to promote environmental photodegradation of the unmodified polymer.
Claim 3
Dependent Claim
33 words
The invention of claim 1 wherein the acylating agent is selected from the group consisting of organic monofunctional acyl halides, organic difunctional acyl halides, organic acid anhydrides and alkyl halides containing ketone groups.
Claim 4
Dependent Claim
25 words
As a composition of matter, a mixture of a chemically modified styrene polymer or copolymer and unmodified polystyrene, prepared by the process of claim 1.
Claim 5
Dependent Claim
71 words
The invention of claim 2 wherein said organic monofunctional acyl halides are selected from the group consisting of acetyl chloride, acetyl bromide, propionyl chloride, butyryl chloride, isobutyryl chloride, hexanoyl chloride, decanoyl chloride, 2-ethylhexanoyl chloride, lauroyl chloride, 10-undecenoyl chloride, oleoyl chloride, palmitoyl chloride, phenylacetyl chloride, phenoxyacetyl chloride, benzoyl chloride, benzoyl bromide, p-anisoyl chloride, p-tert-butylbenzoyl chloride, methoxyacetyl chloride, chloroacetyl chloride, p-toluoyl chloride, acryloyl chloride, methacryloyl chloride, crotonyl chloride, cinnamoyl chloride, and phenothiazine-10-carbonyl chloride.
Claim 6
Dependent Claim
31 words
The invention of claim 2 wherein said organic difunctional acyl halides are selected from the group consisting of phthaloyl chloride, isophthaloyl chloride, terephthaloyl chloride, oxalyl chloride, malonyl dichloride, and sebacoyl chloride.
Claim 7
Dependent Claim
30 words
The invention of claim 2 wherein said organic acid anhydrides are selected from the group consisting of phthalic anhydride, succinic anhydride, maleic anhydride, acetic anhydride, propionic anhydride, and benzoic anhydride.
Claim 8
Dependent Claim
27 words
The invention of claim 2 wherein said alkyl halides containing ketone groups are selected from the group consisting of phenacyl chloride, phenacyl bromide, beta-chloropropiophenone, gamma-chlorobutyrophenone, and 2-chloro-2-phenylacetophenone.
Claim 9
Dependent Claim
21 words
The invention of claim 4 wherein said styrene polymers are selected from the group consisting of polystyrene, alphamethylstyrene, and vinyl toluene.
Claim 10
Dependent Claim
29 words
The invention of claim 4 wherein said styrene copolymers are copolymers of styrene and other ethylenically unsaturated monomers selected from the group consisting of acrylonitrile, butadiene and methyl methacrylate.
Claim 11
Dependent Claim
54 words
The invention of claim 4 wherein said Lewis Acid catalyst is selected from the group consisting of aluminum chloride, aluminum bromide, ferric chloride, stannic chloride, mercuric chloride, beryllium chloride, zinc chloride, titanium tetrachloride, borontrifluoride, boron trichloride, iodine, phosphorus pentoxide sulfur trioxide, hydrogen fluoride, hydrogen chloride, sulfuric acid, phosphoric acid, polyphosphoric acid, and trifluoromethanesulfonic acid.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-23 | 1980-11-22 | 1981-05-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-23 | 1984-11-22 | 1985-05-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-23 | 1988-11-22 | 1989-05-24 | $7700.00 | Window Closed / Lapsed |