US4025347A
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Fogged direct-positive silver halide emulsion containing a cyanine dye having an indole or indolenine nucleus substituted with a benzoyl or a phenylsulfonyl group
Assignee: 3M Co
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Filing: 1974-06-12
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Granted: 1977-05-24
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Expires: 1994-06-12
Abstract
Abstract New cyanine dyes, comprising at least one of the following nuclei (or derivatives thereof):
Inventors
- 👤 Paolo Beretta
- 👤 Luigi Valbusa
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 19:00
CPC Classifications
C; C09; C09B; C09B23/00; C09B23/02; C09B23/06; G; G03; G03C; G03C1/00; G03C1/005; G03C1/06; G03C1/08; G03C1/10; G03C1/12; G03C1/485; G03C1/48515; G03C1/48523; G03C1/4853
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
225 words
A light-sensitive, fogged direct positive silver halide emulsion characterized in that it contains a sensitizing amount of cyanine dye corresponding to one of the following formulae: ##STR55## wherein: m represents a positive integer of from 1 to 2; n represents a positive integer of from 2 to 4; R, r 6 each represent a benzoyl group or a phenylsulfonyl group; R 1 , r 1 ', r 2 and R 7 each represent a substituted or non-substituted acyclic hydrocarbon substituent; an alkyl-aryl substituent or an aryl substituent; R 3 represents an aryl or substituted aryl group; R 4 represents an hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, an aryl group, a thienyl group, with the proviso that at least one of the two substituents R 4 is an hydrogen atom; R 5 represents an hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an halogen atom, a nitro group, a benzoyl group or a phenylsulfonyl group; R 8 , r 9 each represent an alkyl group containing from 1 to 4 carbon atoms; X - represents an acid anion; and Z represents the non-metallic atoms necessary to complete a heterocyclic nucleus containing from 5 to 6 atoms in the heterocyclic ring, said non-metallic atoms being selected from the group consisting of carbon, oxygen, sulfur, nitrogen, and selenium atoms.
Claim 2
Dependent Claim
225 words
A light-sensitive, fogged direct positive silver halide emulsion characterized in that it contains a sensitizing amount of cyanine dye corresponding to one of the following formulae: ##STR55## wherein: m represents a positive integer of from 1 to 2; n represents a positive integer of from 2 to 4; R, r 6 each represent a benzoyl group or a phenylsulfonyl group; R 1 , r 1 ', r 2 and R 7 each represent a substituted or non-substituted acyclic hydrocarbon substituent; an alkyl-aryl substituent or an aryl substituent; R 3 represents an aryl or substituted aryl group; R 4 represents an hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, an aryl group, a thienyl group, with the proviso that at least one of the two substituents R 4 is an hydrogen atom; R 5 represents an hydrogen atom, an alkyl group, an alkoxy group, an aryloxy group, an halogen atom, a nitro group, a benzoyl group or a phenylsulfonyl group; R 8 , r 9 each represent an alkyl group containing from 1 to 4 carbon atoms; X - represents an acid anion; and Z represents the non-metallic atoms necessary to complete a heterocyclic nucleus containing from 5 to 6 atoms in the heterocyclic ring, said non-metallic atoms being selected from the group consisting of carbon, oxygen, sulfur, nitrogen, and selenium atoms.
Claim 3
Dependent Claim
21 words
Light-sensitive fogged direct 4(halide ) emulsions according to claim 1 characterized in that they contain a sensitizing amount of 1-methyl-3'-ethyl-5-phenyl-sulfonyl-6'-nitro-2-phenyl-3-indole-thiacarbocyanine iodide.
Claim 4
Dependent Claim
23 words
Light-sensitive, fogged direct positive silver halide emulsions according to claim 1 characterized in that they contain a sensitizing amount of 1,1'-diethyl-3,3,3', 3'-tetramethyl-5,5'-diphenylsulfonyl-indocarbocyanine iodide.
Claim 5
Dependent Claim
22 words
Light-sensitive, fogged direct positive silver halide emulsions according to claim 1 characterized in that they contain a sensitizing amount of 1,3'-diethyl-5-phenylsulfonyl-6'-nitro-3,3-dimethyl-indo-thiocarbocyanine iodide.
Claim 6
Dependent Claim
23 words
Light-sensitive, fogged direct positive silver halide emulsions, according to claim 1 characterized in that they contain a sensitizing amount of 1-methyl-1'-ethyl-2-phenyl-5-nitro-5'-phenylsulfonyl-3', 3'-dimethyl-indocarbocyanine iodide.
Claim 7
Dependent Claim
21 words
Direct positive photographic elements, characterized in that they contain at least one layer of light-sensitive emulsion as claimed in claim 1.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-05-23 | 1980-11-22 | 1981-05-24 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-05-23 | 1984-11-22 | 1985-05-24 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-05-23 | 1988-11-22 | 1989-05-24 | $7700.00 | Window Closed / Lapsed |