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US4024116A Expired / Lapsed US ⏱️ 0.0 years remaining

Hot-melt adhesive based on copolyamides from caprolactam and alkylene dicarboxylic acid salts of polyether diamine

Assignee: BASF SE
•
Filing: 1975-09-08
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Granted: 1977-05-17
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Expires: 1995-09-08
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Abstract

Abstract A hot-melt adhesive comprising copolyamides obtained from (a) ε-caprolactam, (b) diamine salts of adipic acid, sebacic acid and/or azelaic acid and (c) alkylenedicarboxylic acid salts of polyether-diamines gives e.g. textile laminates which are particularly resistant to washing and dry-cleaning.

Inventors

  • 👤 Peter Horn
  • 👤 Hans-Dietmar Haertl

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 10:57
CPC Classifications
B; B32; B32B; B32B7/00; B32B7/04; B32B7/12; C; C08; C08G; C08G69/00; C08G69/40; B32B5/00; B32B5/22; B32B5/24; B32B5/26; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31725; Y10T428/31739

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 152 words
A hot-melt adhesive consisting essentially of a copolyamide of A. from 20 to 60 parts by weight of ε-caprolactam, B. from 10 to 40 parts by weight of a salt of adipic acid, sebacid acid, azelaic acid or mixtures thereof with a diamine of the general formula H.sub.2 N--(CH.sub.2).sub.n --NH.sub.2 (I) in which n is a whole number from 2 to 6, and C. from 20 to 60 parts by weight of a salt of a dicarboxylic acid of the general formula HOOC--(CH.sub.2).sub.n --COOH (II) in which n is a whole number from 7 to 11, with a diamine of the general formula ##STR3## in which n, m and y are identical or different and each is from 2 to 6 and the individual radicals R 1 , R 2 , R 3 and R 4 are identical or different and each is H or alkyl of 1 to 3 carbon atoms.
Claim 2
Dependent Claim 152 words
A hot-melt adhesive consisting essentially of a copolyamide of A. from 20 to 60 parts by weight of ε-caprolactam, B. from 10 to 40 parts by weight of a salt of adipic acid, sebacid acid, azelaic acid or mixtures thereof with a diamine of the general formula H.sub.2 N--(CH.sub.2).sub.n --NH.sub.2 (I) in which n is a whole number from 2 to 6, and C. from 20 to 60 parts by weight of a salt of a dicarboxylic acid of the general formula HOOC--(CH.sub.2).sub.n --COOH (II) in which n is a whole number from 7 to 11, with a diamine of the general formula ##STR3## in which n, m and y are identical or different and each is from 2 to 6 and the individual radicals R 1 , R 2 , R 3 and R 4 are identical or different and each is H or alkyl of 1 to 3 carbon atoms.
Claim 3
Dependent Claim 32 words
A hot-melt adhesive as set forth in claim 1, wherein the copolyamide has a Fikentscher K value of from 50 to 80, measured in 0.5% strength solution in m-cresol at 20° C.
Claim 4
Dependent Claim 56 words
A hot-melt adhesive as set forth in claim 1 consisting essentially of a copolyamide of A. from 35 to 45 parts by weight of ε-caprolactam, B. from 10 to 30 parts by weight of the hexamethylenediamine salt of adipic acid and C. from 35 to 45 parts by weight of the 4,9-dioxadodecane-1,12-diamine salt of decane-1,10-dicarboxylic acid.

References Cited (Backward Citations)

US3850887A Cited
US3933762A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-16 1980-11-15 1981-05-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-16 1984-11-15 1985-05-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-16 1988-11-15 1989-05-17 $7700.00 Window Closed / Lapsed

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