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US4023976A Expired / Lapsed US ⏱️ 0.0 years remaining

Manufacture of glass using briquettes

Assignee: FMC Corp
•
Filing: 1976-01-23
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Granted: 1977-05-17
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Expires: 1996-01-23
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Abstract

Abstract An improved process is described for producing glass in which a glass batch is mixed with a binder, aged, compacted, and compressed into briquettes, which are heated to partially react the contents of the batch in a prereaction stage. Prereacted briquettes are then placed in a fuel-fired furnace and heated at a temperature not above 2,600° F (1,430° C) to refine them into glass.

Inventors

  • 👤 William C. Bauer
  • 👤 Richard Irving Howard, deceased

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 15:20
CPC Classifications
C; C03; C03C; C03C1/00; C03C1/02; C03C1/026

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 203 words
A process for the continuous manufacture of glass from glass batch comprising silicon dioxide, soda ash and a calcium carbonate or calcium oxide in a glass furnace comprising: a. adding to the glass batch a binder selected from the group consisting of water and an aqueous caustic soda solution, in amounts up to 10% by weight of the batch, b. aging the glass batch and binder for a period of at least 10 minutes, c. compacting the glass batch and binder by compressing same in a prebriquetting stage, d. dividing the compacted glass batch and binder into particulate form, e. briquetting the particulates of glass batch and binder by compressing same into discrete briquetted shapes, f. heating the briquetted shapes to temperatures of from about 750° C to about 900° C for a time sufficient to convert said silicon dioxide through a fluid state to a solid state to obtain substantial conversion of said silicon dioxide in the glass batch to silicates, g. introducing the heat-treated briquetted shapes of step (f) into a glass furnace at a temperature not above 2,600° F (1,430° C) whereby volatilization of sodium values from the furnace is reduced, and h. recovering refined molten glass from the furnace.
Claim 2
Dependent Claim 203 words
A process for the continuous manufacture of glass from glass batch comprising silicon dioxide, soda ash and a calcium carbonate or calcium oxide in a glass furnace comprising: a. adding to the glass batch a binder selected from the group consisting of water and an aqueous caustic soda solution, in amounts up to 10% by weight of the batch, b. aging the glass batch and binder for a period of at least 10 minutes, c. compacting the glass batch and binder by compressing same in a prebriquetting stage, d. dividing the compacted glass batch and binder into particulate form, e. briquetting the particulates of glass batch and binder by compressing same into discrete briquetted shapes, f. heating the briquetted shapes to temperatures of from about 750° C to about 900° C for a time sufficient to convert said silicon dioxide through a fluid state to a solid state to obtain substantial conversion of said silicon dioxide in the glass batch to silicates, g. introducing the heat-treated briquetted shapes of step (f) into a glass furnace at a temperature not above 2,600° F (1,430° C) whereby volatilization of sodium values from the furnace is reduced, and h. recovering refined molten glass from the furnace.
Claim 3
Dependent Claim 21 words
Process of claim 1 wherein the glass batch and binder are aged for a period of 10 minutes to 60 minutes.
Claim 4
Dependent Claim 28 words
Process of claim 1 wherein the heat-treated briquetted shapes are heated in the glass furnace at a temperature of about 2,400° to 2,600° F (1,315° to 1,430° C).
Claim 5
Dependent Claim 29 words
Process of claim 1 wherein the aging of the glass batch and binder in step (b) is carried out after it has been compacted in the prebriquetting stage (c).
Claim 6
Dependent Claim 21 words
Process of claim 1 wherein the glass batch contains silicon dioxide sand having a size from about 16 to -325 mesh.
Claim 7
Dependent Claim 19 words
Process of claim 5 wherein the silicon dioxide sand has a size of from about 16 to 200 mesh.
Claim 8
Dependent Claim 13 words
Process of claim 1 wherein the glass batch is a soda-lime glass batch.
Claim 9
Dependent Claim 16 words
Process of claim 1 wherein the glass batch contains calcium oxide and the binder is water.
Claim 10
Dependent Claim 20 words
Process of claim 1 wherein the glass batch contains calcium carbonate and the binder is an aqueous caustic soda solution.
Claim 11
Dependent Claim 21 words
Process of claim 1 wherein the briquetted shapes are heated in step (f) for a period of up to twelve hours.
Claim 12
Dependent Claim 175 words
Process of producing partially reacted, strong, shock-resistant briquetted shapes, suitable as a glass batch feed to a glass furnace comprising: a. adding to a glass batch comprising silicon dioxide, soda ash and a calcium carbonate or calcium oxide a binder selected from the group consisting of water and an aqueous caustic soda solution, in amounts up to 10% by weight of the batch, b. aging the glass batch and binder for a period of at least 10 minutes, c. compacting the glass batch and binder by compressing same in a prebriquetting stage, d. dividing the compacted glass batch and binder into particulate form, e. briquetting the particulates of glass batch and binder by compressing same into discrete briquetted shapes, f. heating the briquetted shapes to temperatures of from about 750° C to about 900° C for a time sufficient to convert said silicon dioxide through a fluid state to a solid state to obtain substantial conversion of said silicon dioxide in the glass batch to silicates, and g. recovering partially reacted, strong, shock-resistant briquetted shapes.
Claim 13
Dependent Claim 175 words
Process of producing partially reacted, strong, shock-resistant briquetted shapes, suitable as a glass batch feed to a glass furnace comprising: a. adding to a glass batch comprising silicon dioxide, soda ash and a calcium carbonate or calcium oxide a binder selected from the group consisting of water and an aqueous caustic soda solution, in amounts up to 10% by weight of the batch, b. aging the glass batch and binder for a period of at least 10 minutes, c. compacting the glass batch and binder by compressing same in a prebriquetting stage, d. dividing the compacted glass batch and binder into particulate form, e. briquetting the particulates of glass batch and binder by compressing same into discrete briquetted shapes, f. heating the briquetted shapes to temperatures of from about 750° C to about 900° C for a time sufficient to convert said silicon dioxide through a fluid state to a solid state to obtain substantial conversion of said silicon dioxide in the glass batch to silicates, and g. recovering partially reacted, strong, shock-resistant briquetted shapes.
Claim 14
Dependent Claim 21 words
Process of claim 11 wherein the glass batch and binder are aged for a period of 10 minutes to 60 minutes.
Claim 15
Dependent Claim 29 words
Process of claim 11 wherein the aging of the glass batch and binder in step (b) is carried out after it has been compacted in the prebriquetting stage (c).
Claim 16
Dependent Claim 21 words
Process of claim 11 wherein the glass batch contains silicon dioxide sand having a size from about 16 to -325 mesh.
Claim 17
Dependent Claim 18 words
Process of claim 14 wherein the silicon dioxide sand has a size of from 16 to 200 mesh.
Claim 18
Dependent Claim 13 words
Process of claim 11 wherein the glass batch is a soda-lime glass batch.
Claim 19
Dependent Claim 16 words
Process of claim 11 wherein the glass batch contains calcium oxide and the binder is water.
Claim 20
Dependent Claim 20 words
Process of claim 11 wherein the glass batch contains calcium carbonate and the binder is an aqueous caustic soda solution.
Claim 21
Dependent Claim 21 words
Process of claim 11 wherein the briquetted shapes are heated in step (f) for a period of up to twelve hours.
Claim 22
Dependent Claim 176 words
A partially reacted, strong, shock-resistant briquetted shape, suitable as a glass batch feed to a glass furnace produced by: a. adding to a glass batch comprising silicon dioxide, soda ash and a calcium carbonate or calcium oxide a binder selected from the group consisting of water and an aqueous caustic soda solution, in amounts up to 10% by weight of the batch, b. aging the glass batch and binder for a period of at least 10 minutes, c. compacting the glass batch and binder by compressing same in a prebriquetting stage, d. dividing the compacted glass batch and binder into particulate form, e. briquetting the particulates of glass batch and binder by compressing same into a discrete briquetted shape, f. heating the briquetted shape to temperatures of from about 750° C to about 900° C for a time sufficient to convert said silicon dioxide through a fluid state to a solid state to obtain substantial conversion of said silicon dioxide in the glass batch to silicates, and g. recovering a partially reacted, strong, shock-resistant briquetted shape.
Claim 23
Dependent Claim 176 words
A partially reacted, strong, shock-resistant briquetted shape, suitable as a glass batch feed to a glass furnace produced by: a. adding to a glass batch comprising silicon dioxide, soda ash and a calcium carbonate or calcium oxide a binder selected from the group consisting of water and an aqueous caustic soda solution, in amounts up to 10% by weight of the batch, b. aging the glass batch and binder for a period of at least 10 minutes, c. compacting the glass batch and binder by compressing same in a prebriquetting stage, d. dividing the compacted glass batch and binder into particulate form, e. briquetting the particulates of glass batch and binder by compressing same into a discrete briquetted shape, f. heating the briquetted shape to temperatures of from about 750° C to about 900° C for a time sufficient to convert said silicon dioxide through a fluid state to a solid state to obtain substantial conversion of said silicon dioxide in the glass batch to silicates, and g. recovering a partially reacted, strong, shock-resistant briquetted shape.
Claim 24
Dependent Claim 26 words
Process of claim 1 wherein the binder is added to the glass batch in amounts of about 3 to about 7.5% by weight of the batch.
Claim 25
Dependent Claim 26 words
Process of claim 11 wherein the binder is added to the glass batch in amounts of about 3 to about 7.5% by weight of the batch.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-16 1980-11-15 1981-05-17 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-16 1984-11-15 1985-05-17 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-16 1988-11-15 1989-05-17 $7700.00 Window Closed / Lapsed

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