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US4021501A Expired / Lapsed US ⏱️ 0.0 years remaining

Production of hydrocarbons

Assignee: Imperial Chemical Industries Ltd
•
Filing: 1975-08-12
•
Granted: 1977-05-03
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Expires: 1995-08-12
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Abstract

Abstract In the thermal cracking of a hydrocarbon feedstock, the quenching of the gases leaving the cracking zone is deliberately deferred for a very short time to permit continued endothermic reaction and thereby increase the ethylene yield.

Inventors

  • 👤 Peter Dyer
  • 👤 David Charles Alexander Waterman

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 22:10
CPC Classifications
C; C10; C10G; C10G9/00; C10G2400/00; C10G2400/20; C10G2400/30; Y; Y10; Y10S; Y10S585/00; Y10S585/909; Y10S585/911; Y10S585/919; Y10S585/921; Y10S585/924

Claims Analysis

Total Claims: 13
Claim 1
Independent Claim 79 words
A process of thermally cracking a hydrocarbon feedstock wherein, prior to abrupt quenching of the process stream, the process stream emerging from the radiant zone of a pyrolysis furnace at a temperature above 700° C. is allowed to undergo endothermic reaction beyond the radiant zone for a period of at least 0.03 seconds such that its temperature falls as a result of heat uptake by continued endothermic reactions from a value above 700° C. whereby to enhance ethylene yield.
Claim 2
Dependent Claim 79 words
A process of thermally cracking a hydrocarbon feedstock wherein, prior to abrupt quenching of the process stream, the process stream emerging from the radiant zone of a pyrolysis furnace at a temperature above 700° C. is allowed to undergo endothermic reaction beyond the radiant zone for a period of at least 0.03 seconds such that its temperature falls as a result of heat uptake by continued endothermic reactions from a value above 700° C. whereby to enhance ethylene yield.
Claim 3
Dependent Claim 29 words
A process as claimed in claim 1 in which the emergent process stream is allowed to undergo endothermic reaction for a period in the range 0.03 to 1 second.
Claim 4
Dependent Claim 27 words
A process as claimed in claim 1 in which the process stream emerges from the radiant zone of the pyrolysis furnace at a temperature above 750° C.
Claim 5
Dependent Claim 19 words
A process as claimed in claim 1 in which the process is carried out in a thermally lagged conduit.
Claim 6
Dependent Claim 23 words
A process as claimed in claim 1 in which the process is carried out immediately beyond the radiant zone of the pyrolysis furnace.
Claim 7
Dependent Claim 17 words
A process as claimed in claim 1 in which a diluent is added to the process stream.
Claim 8
Dependent Claim 15 words
A process as claimed in claim 6 in which the diluent is steam or hydrogen.
Claim 9
Dependent Claim 19 words
A process as claimed in claim 1 in which an additional hydrocarbon stream is added to the process stream.
Claim 10
Dependent Claim 37 words
A process as claimed in claim 1 in which the process stream emerging from the radiant zone of the pyrolysis furnace is derived from a thermal cracking process employing a process stream diluent, preferably steam or hydrogen.
Claim 11
Dependent Claim 99 words
In a process of thermally cracking a hydrocarbon feedstock, comprising (a) a thermal cracking step and (b) an abrupt quenching of the process stream of said cracking step, the improvement consisting essentially of an additional step (c) which comprises directing the process stream to an endothermic reaction zone, which process stream remains in the endothermic reaction zone for a period of time ranging from 0.03 to 1 second, in which zone endothermic reactions occur with concomitant heat uptake and decrease in temperature, said additional step being undertaken prior to said quenching, said additional step resulting in enhanced ethylene yields.
Claim 12
Dependent Claim 99 words
In a process of thermally cracking a hydrocarbon feedstock, comprising (a) a thermal cracking step and (b) an abrupt quenching of the process stream of said cracking step, the improvement consisting essentially of an additional step (c) which comprises directing the process stream to an endothermic reaction zone, which process stream remains in the endothermic reaction zone for a period of time ranging from 0.03 to 1 second, in which zone endothermic reactions occur with concomitant heat uptake and decrease in temperature, said additional step being undertaken prior to said quenching, said additional step resulting in enhanced ethylene yields.
Claim 13
Dependent Claim 14 words
The process of claim 10, wherein said process stream is admixed with a diluent.

References Cited (Backward Citations)

US2852440A Cited
US3103485A Cited
US3487121A Cited
US3579438A Cited
US3842138A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-05-02 1980-11-01 1981-05-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-05-02 1984-11-01 1985-05-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-05-02 1988-11-01 1989-05-03 $7700.00 Window Closed / Lapsed

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