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US4020303A Expired / Lapsed US ⏱️ 0.0 years remaining

Polyimides prepared from amine terminated prepolymers and olefin containing anhydrides

Assignee: General Electric Co
•
Filing: 1971-12-16
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Granted: 1977-04-26
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Expires: 1991-12-16
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Abstract

Abstract New and useful polymers are prepared by reacting olefin-terminated prepolymeric materials with simple polyamine, by reacting simple olefins with amine-terminated prepolymers and by reacting olefin-terminated prepolymers with amine-terminated prepolymers. The new and useful polymeric materials so obtained can be cured as with heat, with or without catalyst, to provide products useful for preparing films, laminates, composites, prepregs, molding materials, varnishes, wire enamels and the like.

Inventors

  • 👤 Richard J. Jablonski
  • 👤 Daniel Kruh

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 20:12
CPC Classifications
C; C08; C08G; C08G73/00; C08G73/06; C08G73/10; C08G73/12; C08G73/121; C08G73/122

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 174 words
A polymer selected from (a) the reaction product of (1) amine terminated prepolymer prepared by reacting a material selected from dicarboxylic acid, dicarboxylic acid anhydride, tricarboxylic acid and tricarboxylic acid anhydride with simple polyamine having the formula I X --R"--NH.sub.2).sbsb.n where R" is an organic radical, n is at least 2 and X is selected from hydrogen, amino group, substituted organic groups and unsubstituted organic groups and (2) simple olefin selected from the group consisting of ##STR6## where D is an aliphatically unsaturated divalent organic radical and ##STR7## where R'" is a group containing at least two carbon atoms and D is as above, (b) the reaction product of (1) olefin terminated prepolymer prepared by reacting the amine terminated prepolymer of (a) above with simple olefin selected from the olefins of Formulas II and III above and (2) simple polyamine as in Formula I above, (c) the reaction product of amine terminated prepolymer as in (a) above and olefin terminated prepolymer as in (b), about equivalent proportions of the polymer forming reactants being used.
Claim 2
Dependent Claim 174 words
A polymer selected from (a) the reaction product of (1) amine terminated prepolymer prepared by reacting a material selected from dicarboxylic acid, dicarboxylic acid anhydride, tricarboxylic acid and tricarboxylic acid anhydride with simple polyamine having the formula I X --R"--NH.sub.2).sbsb.n where R" is an organic radical, n is at least 2 and X is selected from hydrogen, amino group, substituted organic groups and unsubstituted organic groups and (2) simple olefin selected from the group consisting of ##STR6## where D is an aliphatically unsaturated divalent organic radical and ##STR7## where R'" is a group containing at least two carbon atoms and D is as above, (b) the reaction product of (1) olefin terminated prepolymer prepared by reacting the amine terminated prepolymer of (a) above with simple olefin selected from the olefins of Formulas II and III above and (2) simple polyamine as in Formula I above, (c) the reaction product of amine terminated prepolymer as in (a) above and olefin terminated prepolymer as in (b), about equivalent proportions of the polymer forming reactants being used.
Claim 3
Dependent Claim 39 words
A polymer as in claim 1 wherein said amine terminated prepolymer is the reaction product of acidic containing material selected from diacid and tricarboxylic acid material and simple polyamine selected from metaphenylene diamine, methylene dianiline, diaminodiphenyl sulfone and oxydianiline.
Claim 4
Dependent Claim 41 words
A polymer as in claim 1 wherein said amine terminated prepolymer is the reaction product of material selected from oxalic, succinic, azelaic, adipic, glutaric, pimelic, sebacic, maleic, fumaric, terephthalic, isophthalic and trimellitic acid and anhydride and mixtures thereof and simple polyamine.
Claim 5
Dependent Claim 12 words
A polymer as in claim 1 wherein said simple olefin is bismaleimide.
Claim 6
Dependent Claim 12 words
A polymer as in claim 1 wherein said simple olefin is maleimide.
Claim 7
Dependent Claim 20 words
A polymer as in claim 1 wherein said amine terminated prepolymer is prepared by reacting trimellitic anhydride and metaphenylene diamine.
Claim 8
Dependent Claim 13 words
A polymer as in claim 1 wherein said simple amine is metaphenylene diamine.
Claim 9
Dependent Claim 13 words
A polymer as in claim 1 wherein said simple amine is methylene dianiline.
Claim 10
Dependent Claim 12 words
A polymer as in claim 1 wherein said simple amine is diaminodiphenylsulfone.

References Cited (Backward Citations)

US3352834A Cited
US3671490A Cited
US3625912A Cited
US3669930A Cited
US3652511A Cited
US3661852A Cited
US3708459A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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