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US4020246A Expired / Lapsed US ⏱️ 0.0 years remaining

Low temperature primary electrolyte cell

Assignee: Northrop Grumman Space and Mission Systems Corp
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Filing: 1976-01-21
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Granted: 1977-04-26
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Expires: 1996-01-21
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Abstract

Abstract A cell is fabricated using a solid alkali metal anode and a fluid cathode which are separated by a modified aluminate solid barrier which permits the flow of only the alkali metal ions. The fluid cathode can contain a solid, gaseous, or liquid oxidizer in a liquid electrolyte. Operating temperatures for these cells range from less than -40° C to approximately 95° C. At ambient temperatures, energy densities of the cells range from approximately 0.7 to 1.8 watt-hour per cubic centimeter. These cells are electrically rechargeable by raising their temperature above the melting point of sodium.

Inventors

  • 👤 Eddie T. Seo
  • 👤 Herbert P. Silverman
  • 👤 Robert J. Day

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 22:22
CPC Classifications
H; H01; H01M; H01M10/00; H01M10/36; H01M10/39; H01M12/00; H01M12/04; H01M12/06; H01M6/00; H01M6/14; Y; Y02; Y02E; Y02E60/00; Y02E60/10

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 60 words
A primary cell comprising an enclosed container having: A. a solid alkali metal anode; B. a ceramic electrolyte separator; C. a liquid cathode; D. means to conduct electric current to the exterior of said container; and wherein said anode is in intimate contact with said separator, and said cathode is in intimate contact with the opposite side of said separator.
Claim 2
Dependent Claim 60 words
A primary cell comprising an enclosed container having: A. a solid alkali metal anode; B. a ceramic electrolyte separator; C. a liquid cathode; D. means to conduct electric current to the exterior of said container; and wherein said anode is in intimate contact with said separator, and said cathode is in intimate contact with the opposite side of said separator.
Claim 3
Dependent Claim 19 words
A primary cell according to claim 1 wherein the ceramic electrolyte separator is ionic conductive crystalline sodium aluminate compound.
Claim 4
Dependent Claim 23 words
A primary cell according to claim 1 wherein said alkali metal anode is selected from the group consisting of lithium, sodium, and potassium.
Claim 5
Dependent Claim 44 words
A primary cell according to claim 1 wherein said cathode is a fluid oxidizer selected from the group consisting of air, oxygen, chlorine, iodine, fluorine, bromine, nitrogen oxides, ozone, tetracyanoethylene, quinones, nitrobenzene, tetracyanoquinodimethan, and phenazinium salts dissolved in an organic solvent with sodium hexafluoroarsenate.
Claim 6
Dependent Claim 25 words
A primary cell according to claim 1 wherein said container is made from material selected from the group consisting of glass, plastic, and stainless steel.
Claim 7
Dependent Claim 62 words
A primary cell comprising an enclosed container having: A. a solid alkali metal anodic reactant; B. a ceramic electrolyte separator; C. a liquid cathodic reactant; D. a current collector in juxtaposition with the cathodic reactant and said separator; E. means to conduct electric current to the exterior of said container; and wherein said anodic reactant is in intimate contact with said separator.
Claim 8
Dependent Claim 62 words
A primary cell comprising an enclosed container having: A. a solid alkali metal anodic reactant; B. a ceramic electrolyte separator; C. a liquid cathodic reactant; D. a current collector in juxtaposition with the cathodic reactant and said separator; E. means to conduct electric current to the exterior of said container; and wherein said anodic reactant is in intimate contact with said separator.
Claim 9
Dependent Claim 18 words
A primary cell according to claim 6 wherein the ceramic electrolyte separator is a crystalline sodium aluminate compound.
Claim 10
Dependent Claim 22 words
A primary cell according to claim 6 wherein said anodic reactant is selected from the group consisting of lithium, sodium, and potassium.
Claim 11
Dependent Claim 43 words
A primary cell according to claim 6 wherein said liquid cathodic reactant is selected from the group consisting of air, oxygen, chlorine, fluorine, bromine, iodine, ozone, nitrogen oxides, tetracyanoethylene, quinones, nitrobenzene, tetracyanoquinodimethan, and phenazinium salts dissolved in an organic solvent with sodium hexafluoroarsenate.
Claim 12
Dependent Claim 25 words
A primary cell according to claim 6 wherein said container is made from material selected from the group consisting of glass, plastic, and stainless steel.

References Cited (Backward Citations)

US3463670A Cited
US3773558A Cited
US3874929A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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