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US4020210A Expired / Lapsed US ⏱️ 0.0 years remaining

Encapsulated water paper

Assignee: Xerox Corp
•
Filing: 1975-12-15
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Granted: 1977-04-26
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Expires: 1995-12-15
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Abstract

Abstract Disclosed is a novel paper sheet adapted for the electrostatographic reproduction of images on both sides thereof. The paper bears a surface sizing material having dispersed therein a plurality of microcapsules comprising water or a hydrated salt encased in an impervious capsule wall of a solid material. As the paper is subjected to the electrostatographic fusing operation, water is released from the microcapsules to replenish that lost due to the heat of fusing. In this manner, the paper can be imaged on its other side without encountering the problems associated with dehydration of the paper.

Inventors

  • 👤 Loren E. Geer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-31 17:25
CPC Classifications
G; G03; G03G; G03G7/00; G03G7/006; G03G7/0066; G03G7/0073; G03G7/008; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/249921; Y10T428/249994; Y10T428/249995; Y10T428/249997; Y10T428/25; Y10T428/253; Y10T428/254; Y10T428/29; Y10T428/2982; Y10T428/2984; Y10T428/2985; Y10T428/2987; Y10T428/2989; Y10T428/31504; Y10T428/31971; Y10T428/31993

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 201 words
In a paper sheet adapted for the electrostatographic reproduction of images on both sides thereof by the deposition on its surface of toner particles in imagewise configuration and fusing the toner into the sheet by the application of heat and pressure thereto, the improvement which comprises a surface size on one or both sides of said sheet, said surface size comprising a binder material and a plurality of microcapsules which comprise a core of water or hydrated salt encased in an impervious capsule wall of a solid material capable of being ruptured by the heat and pressure applied to the sheet during the fusing of the image formed on the first side thereof and in the situation where a hydrated salt is employed as the microcapsule core the salt is selected from those hydrates which give up their water of hydration at a temperature equal to or below that to which the paper is subjected during the fusing operation, said microcapsules being present in an amount which will release sufficient water into the paper sheet so as to provide about two percent water by weight of the paper sheet after the fusing of the image formed on the first side thereof.
Claim 2
Dependent Claim 201 words
In a paper sheet adapted for the electrostatographic reproduction of images on both sides thereof by the deposition on its surface of toner particles in imagewise configuration and fusing the toner into the sheet by the application of heat and pressure thereto, the improvement which comprises a surface size on one or both sides of said sheet, said surface size comprising a binder material and a plurality of microcapsules which comprise a core of water or hydrated salt encased in an impervious capsule wall of a solid material capable of being ruptured by the heat and pressure applied to the sheet during the fusing of the image formed on the first side thereof and in the situation where a hydrated salt is employed as the microcapsule core the salt is selected from those hydrates which give up their water of hydration at a temperature equal to or below that to which the paper is subjected during the fusing operation, said microcapsules being present in an amount which will release sufficient water into the paper sheet so as to provide about two percent water by weight of the paper sheet after the fusing of the image formed on the first side thereof.
Claim 3
Dependent Claim 16 words
The paper sheet of claim 1 wherein the core of the microcapsule contains a hydrated salt.
Claim 4
Dependent Claim 51 words
The paper sheet of claim 2 wherein the hydrated salt is lithium chloride monohydrate, calcium chloride hexahydrate, zinc nitrate hexahydrate, potassium carbonate dihydrate, copper sulfate pentahydrate, magnesium sulfate heptahydrate, zinc sulfate heptahydrate, sodium tetraborate decahydrate, sodium sulfite heptahydrate, sodium sulfate decahydrate, barium hydroxide octahydrate, magnesium acetate tetrahydrate and magnesium nitrate hexahydrate.
Claim 5
Dependent Claim 27 words
The paper sheet of claim 3 wherein the hydrated salt is the heptahydrate of magnesium sulfate, the heptahydrate of zinc sulfate or the decahydrate of sodium tetraborate.
Claim 6
Dependent Claim 39 words
The paper sheet of claim 1 wherein the wall material of the microcapsule is gelatin, ethyl cellulose, poly(methyl methacrylate), starches, carboxymethylcellulose, rosin, paraffin, tristearin, poly(vinyl alcohol), polyethylene, polypropylene, polystyrene, polyacrylamides, polyethers, polyesters, polyamides, polybutadiene, polyisoprene, silicones, epoxies and polyurethanes.
Claim 7
Dependent Claim 20 words
The paper sheet of claim 1 wherein the size of the microcapsules is from 5 to 80 μ in diameter.
Claim 8
Dependent Claim 18 words
The paper sheet of claim 6 wherein the diameter of the microcapsules is from 20 to 30 μ.
Claim 9
Dependent Claim 22 words
The paper sheet of claim 1 wherein the binder material is starch, a starch derivative, polyvinyl alcohol, polystyrene or a mixture thereof.
Claim 10
Dependent Claim 18 words
The paper sheet of claim 1 wherein there is present a surface coating material in the surface size.
Claim 11
Dependent Claim 22 words
The paper sheet of claim 9 wherein the weight ratio of binder material to surface coating material is from 1:10 to 1:3.
Claim 12
Dependent Claim 13 words
The paper sheet of claim 9 wherein the surface coating material is clay.

References Cited (Backward Citations)

US3116147A Cited
US3645911A Cited
US3691090A Cited
US3578482A Cited
US3516846A Cited
US3884685A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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