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US4020193A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of forming a non-glossy film

Assignee: PPG Industries Inc
•
Filing: 1973-07-10
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Granted: 1977-04-26
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Expires: 1993-07-10
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Abstract

Abstract A novel method of preparing a strong, non-glossy material comprises subjecting a composition comprising an unsaturated polyester, an ethylenically unsaturated monomer and a peroxide catalyst to actinic light to cure. In the preferred embodiment, the material comprises pigments and accelerators for room temperature cure of polyester resins. The materials are useful as films and coatings.

Inventors

  • 👤 Marco Wismer
  • 👤 Earl E. Parker

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 20:16
CPC Classifications
C; C08; C08F; C08F299/00; C08F299/02; C08F299/04; C08F299/0478; C08F2/00; C08F2/46; C08F2/48; C08F20/00; C08F20/02; C08F20/10; C08F20/20; C08F299/0407; C08F299/0421

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 108 words
The method of preparing a cured, non-glossy film comprising A. applying to a substrate a layer of a composition consisting essentially of 1. a polyester resin comprising a. from about 40 percent to about 90 percent by weight of unsaturated polyester prepared from an alpha,beta-ethylenically unsaturated polycarboxylic acid and polyhydric alcohol; and b. from about 10 percent to about 60 percent by weight of copolymerizable ethylenically unsaturated monomer; 2. at least about 5 percent by weight of ultraviolet-absorbing pigment; and 3. a peroxide catalyst selected from the group consisting of organic peroxides, organic hydroperoxides and esters thereof; and B. curing said layer by subjecting it to actinic light.
Claim 2
Independent Claim 108 words
The method of preparing a cured, non-glossy film comprising A. applying to a substrate a layer of a composition consisting essentially of 1. a polyester resin comprising a. from about 40 percent to about 90 percent by weight of unsaturated polyester prepared from an alpha,beta-ethylenically unsaturated polycarboxylic acid and polyhydric alcohol; and b. from about 10 percent to about 60 percent by weight of copolymerizable ethylenically unsaturated monomer; 2. at least about 5 percent by weight of ultraviolet-absorbing pigment; and 3. a peroxide catalyst selected from the group consisting of organic peroxides, organic hydroperoxides and esters thereof; and B. curing said layer by subjecting it to actinic light.
Claim 3
Dependent Claim 11 words
The method of claim 1 wherein the unsaturated monomer is styrene.
Claim 4
Dependent Claim 14 words
The method of claim 1 wherein the peroxide catalyst is methyl ethyl ketone peroxide.
Claim 5
Dependent Claim 11 words
The method of claim 1 wherein the pigment is titanium dioxide.
Claim 6
Dependent Claim 19 words
The method of claim 1 wherein the composition also comprises an accelerator for the cure of the polyester resin.
Claim 7
Dependent Claim 12 words
The method of claim 5 wherein the accelerator is a cobalt salt.
Claim 8
Dependent Claim 12 words
The method of claim 1 wherein the composition also comprises a photosensitizer.
Claim 9
Dependent Claim 12 words
The method of claim 7 wherein the photosensitizer is benzoin methyl ether.

References Cited (Backward Citations)

US2985615A Cited
US2949361A Cited
US3664861A Cited
US3582487A Cited
US3766111A Cited
US3699022A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-25 1980-10-25 1981-04-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-25 1984-10-25 1985-04-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-25 1988-10-25 1989-04-26 $7700.00 Window Closed / Lapsed

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