Electrodes for electrochemical cells

Claim 2

In a fuel cell comprising an anode electrode, a cathode electrode, spaced apart and forming an electrolyte compartment therebetween, and means constructed and arranged to define a reactant gas passage on the nonelectrolyte side of each electrode, an improvement to said cell wherein at least one of said electrodes includes a carbon paper substrate comprising carbon fibers each coated with pyrolytic carbon, said pyrolytic carbon forming electrically conductive bonds between said fibers, said substrate including a hydrophobic polymer dispersed therein for wet-proofing the substrate, and a layer disposed on said wet-proofed substrate consisting of a catalyst and a hydrophobic polymer.

Claim 3

The fuel cell as defined in claim 1 wherein said hydrophobic polymer dispersed in said substrate is a hydrophobic fluorocarbon polymer.

Claim 4

The fuel cell as defined in claim 1 wherein said hydrophobic polymer dispersed in said substrate is polytetrafluoroethylene.

Claim 5

The fuel cell according to claim 1 wherein said hydrophobic polymer dispersed in said substrate comprises substantially 5% to 40% by weight of said substrate.

Claim 6

The fuel cell as defined in claim 1 wherein said electrode is a cathode electrode and said layer comprises about 4 mg/cm 2 and 75% platinum and 25% polytetrafluoroethylene by weight.

Claim 7

The fuel cell as defined in claim 1 wherein said electrode is an anode electrode and said layer comprises about 2 mg/cm 2 of 32% platinum, 32% rhodium, 16% tungsten oxide and 20% polytetrafluoroethylene by weight.

Claim 8

The fuel cell as defined in claim 1 wherein said electrode is a cathode electrode and said layer comprises a catalyst of about 1/4 mg/cm 2 of platinum supported on graphite in about the proportions of 5% platinum and 95% graphite, by weight, and polytetrafuoroethylene in the proportions of 45% to 55% and 55% to 45% polytetrafluoroethylene, by weight of said second layer.

Claim 9

The fuel cell as defined in claim 1 wherein said electrode is an anode electrode and said second layer comprises a catalyst of about 1/4 mg/cm 2 of platinum supported on graphite and tungsten oxide in about the proportions of 5% platinum, 47 1/2% graphite and 47 1/2% tungsten oxide, by weight, and polytetrafluoroethylene in the proportions of 65% to 80% catalyst and 35% to 20% polytetrafluoroethylene by weight of said second layer.

Claim 10

In a fuel cell comprising an anode electrode, a cathode electrode, spaced apart and forming an electrolyte compartment therebetween, and means constructed and arranged to define a reactant gas passage on the nonelectrolyte side of each electrode, an improvement to said cell wherein at least one of said electrodes includes a carbon paper substrate comprising carbon fibers each coated with pyrolytic carbon, said pyrolytic carbon forming electrically conductive bonds between said fibers, said substrate including 5% to 40% by weight polytetrafluoroethylene dispersed therein for wetproofing the substrate, and a layer disposed on said wetproofed substrate consisting of a catalyst and polytetrafluoroethylene.

Claim 11

In a fuel cell comprising an anode electrode, a cathode electrode, spaced apart and forming an electrolyte compartment therebetween, and means constructed and arranged to define a reactant gas passage on the nonelectrolyte side of each electrode, an improvement to said cell wherein at least one of said electrodes includes a carbon paper substrate comprising carbon fibers each coated with pyrolytic carbon, said pyrolytic carbon forming electrically conductive bonds between said fibers, said substrate including 5% to 40% by weight polytetrafluoroethylene dispersed therein for wetproofing the substrate, and a layer disposed on said wetproofed substrate consisting of a catalyst and polytetrafluoroethylene.