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US4017557A Expired / Lapsed US ⏱️ 0.0 years remaining

Novel elastomeric graft copolymers

Assignee: EIDP Inc
•
Filing: 1974-11-13
•
Granted: 1977-04-12
•
Expires: 1994-11-13
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Abstract

Abstract 6-Nylons and 12-nylons having primary amino end-groups and an average degree of polymerization of about 5-60 are grafted onto elastomeric trunk polymers having anhydride groups, vicinal carboxylic groups, or carboxylic groups adjacent to alkoxycarbonyl groups by heating a mixture of the nylon and the trunk polymer, preferably under high shear conditions for about 1 minute or less to 30 minutes or more above the melting temperature of the nylon. The resulting elastomeric graft polymers are suitable for fabricating into a variety of articles, such as, for example, wire jacketing, hose, belts, seals, gaskets, and low pressure tires.

Inventors

  • 👤 Clarence Frederick Hammer
  • 👤 Harold King Sinclair

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 17:33
CPC Classifications
C; C08; C08G; C08G81/00; C08G81/02; C08G81/024; C08G81/028

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 278 words
An elastomeric, thermoplastic graft copolymer consisting essentially of A. an elastomeric trunk copolymer derived from at least two monomers, at least one of said monomers providing amine-reactive sites selected from the class consisting of an anhydride group, a vicinal pair of carboxylic groups, and a carboxylic group adjacent to an alkoxy-, phenoxy-, napthoxy-, substituted phenoxy-, or substituted naphthoxycarbonyl group, where the alkyl of the alkoxycarbonyl group has 1-10 carbon atoms, and the substituents of substituted phenoxycarbonyl and naphthoxycarbonyl groups can be a C 1 -C 10 alkyl, halogen, or a C 1 -C 10 alkoxy group; at least one of said monomers containing no amine-reactive sites and none of said monomers containing hydroxyl or amino groups; and B. a side chain polymer derived from a short chain polyamide represented by the formula ##STR9##where Z is ##STR10##R 1 and R 2 being independently selected from hydrogen, a C 1 -C 18 alkyl, benzyl, and C 5 -C 6 cycloalkyl; or taken together, being --(CH 2 ) 4 -, --(CH 2 ) 5 --, --(CH 2 ) 2 --O--(CH 2 ) 2 --, or ##STR11##where R 3 is a C 1 -C 6 alkyl; with the proviso that only one of R 1 and R 2 can be hydrogen; m is 5 and 11; and x is a positive number having an average value of 5-60; said side chain polymer being attached to said trunk copolymer through amide or imide linkages resulting from a reaction of the terminal primary amino group of said short chain polyamide with the amine-reactive sites of said trunk copolymer; the proportion of said elastomeric trunk copolymer in the graft copolymer being about 45-85 weight percent.
Claim 2
Dependent Claim 278 words
An elastomeric, thermoplastic graft copolymer consisting essentially of A. an elastomeric trunk copolymer derived from at least two monomers, at least one of said monomers providing amine-reactive sites selected from the class consisting of an anhydride group, a vicinal pair of carboxylic groups, and a carboxylic group adjacent to an alkoxy-, phenoxy-, napthoxy-, substituted phenoxy-, or substituted naphthoxycarbonyl group, where the alkyl of the alkoxycarbonyl group has 1-10 carbon atoms, and the substituents of substituted phenoxycarbonyl and naphthoxycarbonyl groups can be a C 1 -C 10 alkyl, halogen, or a C 1 -C 10 alkoxy group; at least one of said monomers containing no amine-reactive sites and none of said monomers containing hydroxyl or amino groups; and B. a side chain polymer derived from a short chain polyamide represented by the formula ##STR9##where Z is ##STR10##R 1 and R 2 being independently selected from hydrogen, a C 1 -C 18 alkyl, benzyl, and C 5 -C 6 cycloalkyl; or taken together, being --(CH 2 ) 4 -, --(CH 2 ) 5 --, --(CH 2 ) 2 --O--(CH 2 ) 2 --, or ##STR11##where R 3 is a C 1 -C 6 alkyl; with the proviso that only one of R 1 and R 2 can be hydrogen; m is 5 and 11; and x is a positive number having an average value of 5-60; said side chain polymer being attached to said trunk copolymer through amide or imide linkages resulting from a reaction of the terminal primary amino group of said short chain polyamide with the amine-reactive sites of said trunk copolymer; the proportion of said elastomeric trunk copolymer in the graft copolymer being about 45-85 weight percent.
Claim 3
Dependent Claim 10 words
A graft copolymer of claim 1 wherein m is 5.
Claim 4
Dependent Claim 16 words
A graft copolymer of claim 2 wherein R 1 is hydrogen and R 2 is octadecyl.
Claim 5
Dependent Claim 16 words
A graft copolymer of claim 2 wherein R 1 is hydrogen and R 2 is octyl.
Claim 6
Dependent Claim 10 words
A graft copolymer of claim 1 wherein m is 11.
Claim 7
Dependent Claim 16 words
A graft copolymer of claim 5 wherein R 1 is hydrogen and R 2 is octyl.
Claim 8
Dependent Claim 17 words
A graft copolymer of claim 1 wherein the weight proportion of the trunk polymer is about 64.5-74%.
Claim 9
Dependent Claim 17 words
A graft copolymer of claim 1 wherein the weight proportion of the trunk polymer is about 52.5-67%.
Claim 10
Dependent Claim 71 words
A graft copolymer of claim 1 wherein the trunk polymer is a copolymer of an active site monomer selected from maleic anhydride, maleic acid, fumaric acid, and monoesters of maleic or fumaric acids with alcohols having up to about 20 carbon atoms with at least one monomer selected from α-olefins; conjugated or nonconjugated dienes; styrene, and its ring-substituted derivatives; acrylic and methacrylic acids, esters, and nitriles; vinyl esters; and vinyl ethers.
Claim 11
Dependent Claim 19 words
A graft copolymer of claim 9 wherein the trunk polymer is a copolymer of ethylene, methyl acrylate, and monoethylmaleate.
Claim 12
Dependent Claim 20 words
A graft copolymer of claim 9 wherein the trunk polymer is a copolymer of ethylene, vinyl acetate and maleic anhydride.
Claim 13
Dependent Claim 22 words
A graft copolymer of claim 9 wherein the trunk polymer is a copolymer of ethylene, ethyl acrylate, allyl acrylate, and maleic anhydride.
Claim 14
Dependent Claim 31 words
A graft copolymer of claim 1 wherein the trunk polymer is an ethylene/α-olefin/diene monomer (EODM) polymer, having grafted thereon at least one of maleic anhydride and ethyl hydrogen maleate active sites.
Claim 15
Dependent Claim 16 words
A graft copolymer of claim 12 wherein the EODM polymer is an ethylene/propylene/diene monomer (EPDM) polymer.
Claim 16
Dependent Claim 14 words
A graft copolymer of claim 13 wherein the EPDM polymer is an ethylene/propylene/1,4-hexadiene polymer.

References Cited (Backward Citations)

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US3388186A Cited
US3337648A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-11 1980-10-11 1981-04-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-11 1984-10-11 1985-04-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-11 1988-10-11 1989-04-12 $7700.00 Window Closed / Lapsed

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