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US4017416A Expired / Lapsed US ⏱️ 0.0 years remaining

P-cyanophenyl 4-alkyl-4'-biphenylcarboxylate, method for preparing same and liquid crystal compositions using same

Assignee: JNC Corp
•
Filing: 1975-10-03
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Granted: 1977-04-12
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Expires: 1995-10-03
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Abstract

Abstract Novel nematic liquid crystal compounds having a broad nematic temperature range and a positive dielectric anisotropy by themselves, that is, p-cyanophenyl 4-alkyl-4'-biphenylcarboxylates wherein the alkyl is a straight chain alkyl group having 4-8 carbon atoms or a branched alkyl group having 4-7 carbon atoms and having methyl group as branched group, and a method for preparing the same are provided. Further, novel nematic liquid crystal compositions having a broader nematic temper range i.e. a sufficiently lower nematic limit and a sufficiently higher upper nematic limit is provided by using said compounds.

Inventors

  • 👤 Takashi Inukai
  • 👤 Hideo Sato
  • 👤 Shigeru Sugimori
  • 👤 Tetsuya Ishibe

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 23:03
CPC Classifications
C; C07; C07C; C07C255/00; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/08; C09K19/10; C09K19/20; C09K19/2007; C09K2019/2035

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 241 words
A liquid crystal composition comprising the following 4 groups of (A)-(D) in the proportions specified: A. 35-50% by mol, based upon the total amount of the composition, of two or three compounds selected from the group consisting of 4-alkylbenzoic acid-4'-cyanophenyl esters expressed by the general formula ##STR37## (wherein R is a straight chain alkyl group having 4-8 carbon atoms or a straight chain alkoxy group having 5-8 carbon atoms), said two or at least two of said three compounds each having R as a straight chain alkyl group, B. 20-30% by mol, based upon the total amount of the composition, of ##STR38## or a mixture thereof with ##STR39##C. 8-13% by mol, based upon the total amount of the composition, of one or two or more of compounds selected from the group consisting of 4-alkylbiphenylcarboxylic acid-4'-cyanobiphenyls expressed by the general formula ##STR40## . (wherein C n H 2n +1 is a straight chain alkyl group having 4-8 carbon atoms or a methyl branched alkyl group having 5-7 carbon atoms, and D. 15-30% by mol, based upon the total amount of the composition, of one or more compounds selected from the group consisting of 4-n-butylbenzoic acid-4'-alkyl esters (wherein R is n-heptyl group, n-hexyloxy group or n-heptyloxy group) expressed by the general formula ##STR41## and 4-anisic acid-4'-n-pentylphenyl ester having a formula of ##STR42## alone or in admixture with said one or more compounds selected from the group consisting of the above 4-n-butylbenzoic acid-4'-alkyl esters.
Claim 2
Dependent Claim 241 words
A liquid crystal composition comprising the following 4 groups of (A)-(D) in the proportions specified: A. 35-50% by mol, based upon the total amount of the composition, of two or three compounds selected from the group consisting of 4-alkylbenzoic acid-4'-cyanophenyl esters expressed by the general formula ##STR37## (wherein R is a straight chain alkyl group having 4-8 carbon atoms or a straight chain alkoxy group having 5-8 carbon atoms), said two or at least two of said three compounds each having R as a straight chain alkyl group, B. 20-30% by mol, based upon the total amount of the composition, of ##STR38## or a mixture thereof with ##STR39##C. 8-13% by mol, based upon the total amount of the composition, of one or two or more of compounds selected from the group consisting of 4-alkylbiphenylcarboxylic acid-4'-cyanobiphenyls expressed by the general formula ##STR40## . (wherein C n H 2n +1 is a straight chain alkyl group having 4-8 carbon atoms or a methyl branched alkyl group having 5-7 carbon atoms, and D. 15-30% by mol, based upon the total amount of the composition, of one or more compounds selected from the group consisting of 4-n-butylbenzoic acid-4'-alkyl esters (wherein R is n-heptyl group, n-hexyloxy group or n-heptyloxy group) expressed by the general formula ##STR41## and 4-anisic acid-4'-n-pentylphenyl ester having a formula of ##STR42## alone or in admixture with said one or more compounds selected from the group consisting of the above 4-n-butylbenzoic acid-4'-alkyl esters.
Claim 3
Dependent Claim 32 words
A liquid crystal composition according to claim 1 wherein the content of two or three of said 4-alkylbenzoic acid-4'-cyanophenyl esters is 40-47% by mol, based upon the total amount of the composition.

References Cited (Backward Citations)

US3923857A Cited
JPS4934488A Cited
BE807165A Cited
US3947375A Cited
DE2415929A1 Cited
BE814291A Cited
US3952046A Cited
DE2502904A1 Cited
US3925238A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-04-11 1980-10-11 1981-04-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-04-11 1984-10-11 1985-04-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-04-11 1988-10-11 1989-04-12 $7700.00 Window Closed / Lapsed

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