US4017416A
Expired / Lapsed
US
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P-cyanophenyl 4-alkyl-4'-biphenylcarboxylate, method for preparing same and liquid crystal compositions using same
Assignee: JNC Corp
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Filing: 1975-10-03
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Granted: 1977-04-12
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Expires: 1995-10-03
Abstract
Abstract Novel nematic liquid crystal compounds having a broad nematic temperature range and a positive dielectric anisotropy by themselves, that is, p-cyanophenyl 4-alkyl-4'-biphenylcarboxylates wherein the alkyl is a straight chain alkyl group having 4-8 carbon atoms or a branched alkyl group having 4-7 carbon atoms and having methyl group as branched group, and a method for preparing the same are provided. Further, novel nematic liquid crystal compositions having a broader nematic temper range i.e. a sufficiently lower nematic limit and a sufficiently higher upper nematic limit is provided by using said compounds.
Inventors
- 👤 Takashi Inukai
- 👤 Hideo Sato
- 👤 Shigeru Sugimori
- 👤 Tetsuya Ishibe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 23:03
CPC Classifications
C; C07; C07C; C07C255/00; C09; C09K; C09K19/00; C09K19/04; C09K19/06; C09K19/08; C09K19/10; C09K19/20; C09K19/2007; C09K2019/2035
Claims Analysis
Total Claims: 3
Claim 1
Independent Claim
241 words
A liquid crystal composition comprising the following 4 groups of (A)-(D) in the proportions specified: A. 35-50% by mol, based upon the total amount of the composition, of two or three compounds selected from the group consisting of 4-alkylbenzoic acid-4'-cyanophenyl esters expressed by the general formula ##STR37## (wherein R is a straight chain alkyl group having 4-8 carbon atoms or a straight chain alkoxy group having 5-8 carbon atoms), said two or at least two of said three compounds each having R as a straight chain alkyl group, B. 20-30% by mol, based upon the total amount of the composition, of ##STR38## or a mixture thereof with ##STR39##C. 8-13% by mol, based upon the total amount of the composition, of one or two or more of compounds selected from the group consisting of 4-alkylbiphenylcarboxylic acid-4'-cyanobiphenyls expressed by the general formula ##STR40## . (wherein C n H 2n +1 is a straight chain alkyl group having 4-8 carbon atoms or a methyl branched alkyl group having 5-7 carbon atoms, and D. 15-30% by mol, based upon the total amount of the composition, of one or more compounds selected from the group consisting of 4-n-butylbenzoic acid-4'-alkyl esters (wherein R is n-heptyl group, n-hexyloxy group or n-heptyloxy group) expressed by the general formula ##STR41## and 4-anisic acid-4'-n-pentylphenyl ester having a formula of ##STR42## alone or in admixture with said one or more compounds selected from the group consisting of the above 4-n-butylbenzoic acid-4'-alkyl esters.
Claim 2
Dependent Claim
241 words
A liquid crystal composition comprising the following 4 groups of (A)-(D) in the proportions specified: A. 35-50% by mol, based upon the total amount of the composition, of two or three compounds selected from the group consisting of 4-alkylbenzoic acid-4'-cyanophenyl esters expressed by the general formula ##STR37## (wherein R is a straight chain alkyl group having 4-8 carbon atoms or a straight chain alkoxy group having 5-8 carbon atoms), said two or at least two of said three compounds each having R as a straight chain alkyl group, B. 20-30% by mol, based upon the total amount of the composition, of ##STR38## or a mixture thereof with ##STR39##C. 8-13% by mol, based upon the total amount of the composition, of one or two or more of compounds selected from the group consisting of 4-alkylbiphenylcarboxylic acid-4'-cyanobiphenyls expressed by the general formula ##STR40## . (wherein C n H 2n +1 is a straight chain alkyl group having 4-8 carbon atoms or a methyl branched alkyl group having 5-7 carbon atoms, and D. 15-30% by mol, based upon the total amount of the composition, of one or more compounds selected from the group consisting of 4-n-butylbenzoic acid-4'-alkyl esters (wherein R is n-heptyl group, n-hexyloxy group or n-heptyloxy group) expressed by the general formula ##STR41## and 4-anisic acid-4'-n-pentylphenyl ester having a formula of ##STR42## alone or in admixture with said one or more compounds selected from the group consisting of the above 4-n-butylbenzoic acid-4'-alkyl esters.
Claim 3
Dependent Claim
32 words
A liquid crystal composition according to claim 1 wherein the content of two or three of said 4-alkylbenzoic acid-4'-cyanophenyl esters is 40-47% by mol, based upon the total amount of the composition.
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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