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US4014985A Expired / Lapsed US ⏱️ 0.0 years remaining

Precipitation of aluminum oxide having low sodium oxide content

Assignee: Alcoa Corp
•
Filing: 1975-12-22
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Granted: 1977-03-29
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Expires: 1995-12-22
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Abstract

Abstract Aluminum oxide having a sodium oxide content after calcination of less than 0.1% by weight is continuously precipitated as aluminum hydroxide from a Bayer process liquor by a controlled slow precipitation. The controlled, slow precipitation rate required to create a low soda product is achieved by controlling the residence time of liquor in the precipitation vessel so as to provide a constant, low ratio of aluminum oxide to sodium oxide. Residence time control in a Bayer process plant is achieved by controlling green liquor flow rate to the tank, or by sizing the tank for a constant flow. The use of heavy seed charges to increase the seed surface area permits the production of a low soda product at a faster precipitation rate.

Inventors

  • 👤 Leonard W. Haleen
  • 👤 Alan Pearson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-26 21:13
CPC Classifications
C; C01; C01F; C01F7/00; C01F7/02; C01F7/04; C01F7/14; C01F7/144

Claims Analysis

Total Claims: 3
Claim 1
Independent Claim 207 words
The process of producing an aluminum oxide having a sodium oxide content after calcining of less than 0.1% by weight which comprises: a. continuously precipitating aluminum oxide in a first tank maintained at a temperature of 55°-80° C and an alumina-to-caustic ratio of 0.68 while 1. adding feed liquor at an alumina-to-caustic ratio of 1.04 into said tank at a flow rate in liters per minute equal to approximately 0.043% of the volume of said tank; and 2. simultaneously adding aluminum hydroxide seed slurry to said tank at a rate in meters 2 per hour to maintain a precipitation rate in said tank of less than 0.03 grams Al 2 O 3 per hour per meter 2 of said aluminum hydroxide seed added to the tank per hour; b. feeding the resultant precipitate slurry from said first tank to a second tank maintained at a temperature of about 70° C at a flow rate in liters per minute equal to 0.115% of the volume of said second tank to maintain an alumina-to-caustic ratio of about 0.61 in said second tank; and c. recovering a low soda aluminum hydroxide precipitate from said second tank characterized by a sodium oxide content after calcining of less than 0.1% by weight.
Claim 2
Dependent Claim 207 words
The process of producing an aluminum oxide having a sodium oxide content after calcining of less than 0.1% by weight which comprises: a. continuously precipitating aluminum oxide in a first tank maintained at a temperature of 55°-80° C and an alumina-to-caustic ratio of 0.68 while 1. adding feed liquor at an alumina-to-caustic ratio of 1.04 into said tank at a flow rate in liters per minute equal to approximately 0.043% of the volume of said tank; and 2. simultaneously adding aluminum hydroxide seed slurry to said tank at a rate in meters 2 per hour to maintain a precipitation rate in said tank of less than 0.03 grams Al 2 O 3 per hour per meter 2 of said aluminum hydroxide seed added to the tank per hour; b. feeding the resultant precipitate slurry from said first tank to a second tank maintained at a temperature of about 70° C at a flow rate in liters per minute equal to 0.115% of the volume of said second tank to maintain an alumina-to-caustic ratio of about 0.61 in said second tank; and c. recovering a low soda aluminum hydroxide precipitate from said second tank characterized by a sodium oxide content after calcining of less than 0.1% by weight.
Claim 3
Dependent Claim 18 words
The process of claim 1 wherein said temperature in said first tank is maintained at about 74° C.

References Cited (Backward Citations)

US2574008A Cited
US2657978A Cited
US2707669A Cited
US2653858A Cited
US3265466A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-28 1980-09-27 1981-03-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-28 1984-09-27 1985-03-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-28 1988-09-27 1989-03-29 $7700.00 Window Closed / Lapsed

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