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US4014957A Expired / Lapsed US ⏱️ 0.0 years remaining

Thermoplastic polyamide moulding compositions

Assignee: Hoechst AG
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Filing: 1975-09-02
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Granted: 1977-03-29
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Expires: 1995-09-02
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Abstract

Abstract The present invention relates to thermoplastic moulding compositions of (A) 99.5 to 80% by weight, of at least one amorphous linear polyamide and (B) 0.5 to 20% by weight of at least one segmented thermoplastic elastomeric copolyester. These novel moulding compositions combine good toughness and hardness with good elongation and stiffness properties as well as good flowing properties of the molten material.

Inventors

  • 👤 Gunther Kirsch
  • 👤 Harald Cherdron
  • 👤 Walter Herwig

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 11:20
CPC Classifications
C; C08; C08L; C08L77/00

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 379 words
A thermoplastic molding composition consisting essentially of: A. 99.5 to 80% by weight of an amorphous linear polyamide derived from α 1 . 5 to 50 mole percent of a cycloaliphatic or aromatic aliphatic diamine. α 2 . 0 to 45 percent of an aliphatic diamine of 4 to 20 carbon atoms in which the amino groups are separated by at least four carbon atoms, β 1 . 5 to 50 mole percent of an aromatic dicarboxylic acid of 7 to 20 carbon atoms, β 2 . 0 to 45 mole percent of a saturated aliphatic dicarboxylic acid of 6 to 20 carbon atoms, the carboxy groups of which are separated by at least four carbon atoms, and γ. 0 to 80 mole percent of an aliphatic aminocarboxylic acid of 2 to 20 carbon atoms, the sum of the mole percent of α 1 and α 2 being equal to the sum of the mole percent of β 1 and β 2 , the sum of the mole percent of components α 1 , α 2 , β 1 , β 2 and γ being 100 mole percent, the sum of α 1 and β 1 being from 20 to 95 mole percent and the sum of α 2 , β 2 and γ being from 5 to 80 mole percent, said polyamide having a second order transition temperature of at least 100° C. and a reduced specific viscosity of 0.7 to 1.8 dl/g, and B. 0.5 to 20% by weight of at least one segmented thermoplastic elastomeric copolyester comprising a. long chain ester units derived from a dicarboxylic acid or its equivalent ester-forming derivatives having a molecular weight of less than about 300 and a long chain glycol or its equivalent ester-forming derivative having a molecular weight of more than about 350, and b. short chain ester units derived from a dicarboxylic acid or its equivalent ester-forming derivatives having a molecular weight of less than about 300 and a low molecular weight diol or its equivalent ester-forming derivatives having a molecular weight of less than about 250, the ester units being linked head-to-tail by ester linkages and the short chain ester units B) being present to the extent of about 25% to 65% by weight of the copolyester.
Claim 2
Dependent Claim 379 words
A thermoplastic molding composition consisting essentially of: A. 99.5 to 80% by weight of an amorphous linear polyamide derived from α 1 . 5 to 50 mole percent of a cycloaliphatic or aromatic aliphatic diamine. α 2 . 0 to 45 percent of an aliphatic diamine of 4 to 20 carbon atoms in which the amino groups are separated by at least four carbon atoms, β 1 . 5 to 50 mole percent of an aromatic dicarboxylic acid of 7 to 20 carbon atoms, β 2 . 0 to 45 mole percent of a saturated aliphatic dicarboxylic acid of 6 to 20 carbon atoms, the carboxy groups of which are separated by at least four carbon atoms, and γ. 0 to 80 mole percent of an aliphatic aminocarboxylic acid of 2 to 20 carbon atoms, the sum of the mole percent of α 1 and α 2 being equal to the sum of the mole percent of β 1 and β 2 , the sum of the mole percent of components α 1 , α 2 , β 1 , β 2 and γ being 100 mole percent, the sum of α 1 and β 1 being from 20 to 95 mole percent and the sum of α 2 , β 2 and γ being from 5 to 80 mole percent, said polyamide having a second order transition temperature of at least 100° C. and a reduced specific viscosity of 0.7 to 1.8 dl/g, and B. 0.5 to 20% by weight of at least one segmented thermoplastic elastomeric copolyester comprising a. long chain ester units derived from a dicarboxylic acid or its equivalent ester-forming derivatives having a molecular weight of less than about 300 and a long chain glycol or its equivalent ester-forming derivative having a molecular weight of more than about 350, and b. short chain ester units derived from a dicarboxylic acid or its equivalent ester-forming derivatives having a molecular weight of less than about 300 and a low molecular weight diol or its equivalent ester-forming derivatives having a molecular weight of less than about 250, the ester units being linked head-to-tail by ester linkages and the short chain ester units B) being present to the extent of about 25% to 65% by weight of the copolyester.
Claim 3
Dependent Claim 189 words
A thermoplastic molding composition according to claim 1 comprising 99 to 90% by weight of said polyamide and 1 to 10% by weight of said copolyester and wherein the polyamide A is derived from 10 to 35 mole percent of diamine α 1 , 0 to 35 mole percent of diamine α 2 containing 10 to 35 mole percent of dicarboxylic acid β 1 containing 0 to 35 mole percent of aliphatic acid β 2 containing 6 to 12 carbon atoms, and 0 to 50 mole percent of aminocarboxylic acid γ containing 6 to 12 carbon atoms, and wherein said copolyester comprises long chain ester units (Ba) derived from an aromatic dicarboxylic acid of 8 to 16 carbon atoms and having a molecular weight of 600 to 6,000, and a glycol having a molecular weight of 600 to 6,000, and short chain ester units (Bb) derived from a dicarboxylic acid having 8 to 16 carbon atoms and a diol of 2 to 15 carbon atoms, and said polyamide has a second order transition temperature of 120° to 180° C. and a reduced specific viscosity of 0.9 to 1.4 dl/g.
Claim 4
Dependent Claim 63 words
A thermoplastic molding composition according to claim 1 wherein the diamine α 1 is selected from 1,3-bis(aminomethyl-cyclohexane; 1,4-bis(aminomethyl)-cyclohexane; 2,5-bis-(aminomethyl)-bi-cyclo [2,2,1]-heptane; 2,6-bis(aminomethyl)-bi-cyclo [2,2,1]-heptane; m-xylylene-diamine; mixtures of p-xylylenediamine and at least 50 mole % of m-xylylene-diamine; bis-(4-aminocyclohexyl) derivatives of alkanes having 1 to 6 carbon atoms, and the dicarboxylic acid β 1 is a mononuclear dicarboxylic acid carrying carboxy groups in the meta- or para-position.
Claim 5
Dependent Claim 44 words
A thermoplastic molding composition according to claim 1 wherein the polyamide is derived from a mixture of terephthalic and isophthalic acids, 1,3-bis-aminomethyl-cyclohexane and ε-caprolactam; and the copolyester is derived from phthalic acid, butanediol and poly(tetramethylene oxide) glycol of a molecular weight of about 1,000.
Claim 6
Dependent Claim 18 words
Thermoplastic moulding composition as claimed in claim 1, wherein the aliphatic diamine of α 2 ) is hexamethylene-diamine.
Claim 7
Dependent Claim 23 words
Thermoplastic moulding compositions as claimed in claim 1, wherein the aromatic dicarboxylic acid(s) of β 1 ) is(are) terephthalic acid and/or isophthalic acid.
Claim 8
Dependent Claim 23 words
Thermoplastic moulding compositions as claimed in claim 1, wherein the aliphatic dicarboxylic acid(s) of β 2 ) is(are) adipic acid and/or decanedicarboxylic acid-1,10.
Claim 9
Dependent Claim 21 words
Thermoplastic moulding composition as claimed in claim 1, wherein the aliphatic aminocarboxylic acid(s) of γ) is(are) ε-aminocaproic acid and/or ω-aminolauric acid.
Claim 10
Dependent Claim 32 words
Thermoplastic moulding composition as claimed in claim 1, wherein the copolyester is derived from a poly(alkylene oxide)-glycol, dimethylterephthalate, dimethylisophthalate and an aliphatic diol of from 2 to 8 carbon atoms, preferably 1,4-butanediol.

References Cited (Backward Citations)

US3551278A Cited
US3636135A Cited
FR1603476A Cited
US3584074A Cited
US3896078A Cited
US3917743A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-28 1980-09-27 1981-03-29 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-28 1984-09-27 1985-03-29 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-28 1988-09-27 1989-03-29 $7700.00 Window Closed / Lapsed

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