Process for the recovery of amides

Claim 2

A solvent extraction-distillation process for the recovery of a water-soluble amide selected from the group consisting of an aliphatic amide having 1 to 8 carbon atoms, epsilon-caprolactam, N-methyl-epsilon-caprolactam, 1,5-dimethyl-2-pyrrolidone, 2-pyrrolidone and mixtures thereof, from an aqueous solution thereof wherein the concentration of the amide is in the range of about 0.25 percent by weight to about 25 percent by weight, based on the weight of the solution, and the solvent is a compound having the following structural formula: ##STR4## wherein M is OH or CH 2 OH, R is hydrogen or an alkyl radical, there being at least one alkyl radical, and the total number of carbon atoms in all of said alkyl radicals taken together is 3 to 12, or a mixture of isomers thereof, said compound or mixture of isomers having a boiling point higher than the amide and less than about 350° C. and being non-azeotropic with the amide, comprising the following steps: a. contacting the aqueous solution of said amide in an extraction zone with the solvent in a solvent to aqueous solution feed ratio of from about 0.05 to about 1 part by volume of solvent per part by volume of aqueous solution, to provide an extract comprising solvent, amide, and no more than about 5 percent by weight of water based on the weight of the solution, and a raffinate comprising at least about 95 percent by weight of water based on the weight of the solution and less than about 5 percent by weight of solvent based on the weight of the solvent; b. introducing the extract from step (a) into a distillation zone, wherein the pressure is less than about 500 millimeters of mercury and the temperature is less than the decomposition temperatures of the amide and the solvent at said pressure, to separate the solvent from a mixture of amide and water; and c. recovering the mixture of amide and water.

Claim 3

A solvent extraction-distillation process for the recovery of a water-soluble amide selected from the group consisting of an aliphatic amide having 1 to 8 carbon atoms, epsilon-caprolactam, N-methyl-epsilon-caprolactam, 1,5-dimethyl-2-pyrrolidone, 2-pyrrolidone and mixtures thereof, from an aqueous solution wherein the concentration of the amide is in the range of about 0.25 percent by weight to about 25 percent by weight, based on the weight of the solution, and the solvent is a compound having the following structural formula: ##STR5## wherein M is OH or CH 2 OH, R is hydrogen or an alkyl radical, there being at least one alkyl and the total number of carbon atoms in all of said alkyl radicals taken together is 3 to 12, or a mixture of isomers thereof, said compound or mixture of isomers having a boiling point higher than the amide and less than about 350° C. and being non-azeotropic with the amide, comprising the following steps: a. contacting the aqueous solution of said amide in an extraction zone with the solvent in a solvent to aqueous solution feed ratio of from about 0.05 to about 1 part by volume of solvent per part by volume of aqueous solution, to provide an extract comprising solvent, amide, and no more than about 5 percent by weight of water based on the weight of the solution and a raffinate comprising at least about 95 percent by weight of water based on the weight of the solution and less than about 5 percent by weight of solvent based on the weight of the solvent; b. introducing the extract from step (a) into a first distillation zone, wherein the pressure is no greater than about 760 millimeters of mercury and the temperature is less than the decomposition temperatures of the amide and the solvent at said pressure, to separate the water from a mixture of amide and solvent; c. introducing the mixture of amide and solvent from step (b) into a second distillation zone, wherein the pressure is less than about 500 millimeters of mercury and the temperature is less than the decomposition temperatures of the amide and the solvent at said pressure, to separate the amide from the solvent; and d. recovering the amide.

Claim 4

A solvent extraction-distillation process for the recovery of a water-soluble amide selected from the group consisting of an aliphatic amide having 1 to 8 carbon atoms, epsilon-caprolactam, N-methyl-epsilon-caprolactam, 1,5-dimethyl-2-pyrrolidone, 2-pyrrolidone and mixtures thereof, from an aqueous solution wherein the concentration of the amide is in the range of about 0.25 percent by weight to about 25 percent by weight, based on the weight of the solution, and the solvent is a compound having the following structural formula: ##STR5## wherein M is OH or CH 2 OH, R is hydrogen or an alkyl radical, there being at least one alkyl and the total number of carbon atoms in all of said alkyl radicals taken together is 3 to 12, or a mixture of isomers thereof, said compound or mixture of isomers having a boiling point higher than the amide and less than about 350° C. and being non-azeotropic with the amide, comprising the following steps: a. contacting the aqueous solution of said amide in an extraction zone with the solvent in a solvent to aqueous solution feed ratio of from about 0.05 to about 1 part by volume of solvent per part by volume of aqueous solution, to provide an extract comprising solvent, amide, and no more than about 5 percent by weight of water based on the weight of the solution and a raffinate comprising at least about 95 percent by weight of water based on the weight of the solution and less than about 5 percent by weight of solvent based on the weight of the solvent; b. introducing the extract from step (a) into a first distillation zone, wherein the pressure is no greater than about 760 millimeters of mercury and the temperature is less than the decomposition temperatures of the amide and the solvent at said pressure, to separate the water from a mixture of amide and solvent; c. introducing the mixture of amide and solvent from step (b) into a second distillation zone, wherein the pressure is less than about 500 millimeters of mercury and the temperature is less than the decomposition temperatures of the amide and the solvent at said pressure, to separate the amide from the solvent; and d. recovering the amide.

Claim 5

The process defined in claim 1 wherein the concentration of the amide is in the range of about 0.5 percent to about 5 percent; the extract of step (a) contains no more than about 3 percent water; the raffinate of step (a) contains at least about 97 percent water and less than about 2 percent solvent; and the pressure in step (b) is in the range of about 5 to about 250 millimeters of mercury.

Claim 6

The process defined in claim 2 wherein the concentration of the amide is in the range of about 0.5 percent to about 5 percent; the extract of step (a) contains no more than 3 percent water; the raffinate of step (a) contains at least about 97 percent water and less than about 2 percent solvent; and the pressure in step (c) is in the range of about 5 to about 250 millimeters of mercury.

Claim 7

The process defined in claim 3 wherein the amide is epsilon-caprolactam.

Claim 8

The process defined in claim 4 wherein the amide is epsilon-caprolactam.

Claim 9

The process defined in claim 5 wherein the solvent is a mixture of isomers of dodecylphenol.

Claim 10

The process defined in claim 6 wherein the solvent is a mixture of isomers of dodecylphenol.

Claim 11

A solvent extraction-distillation process for the recovery of epsilon-caprolactam from an aqueous solution thereof wherein the concentration of epsilon-caprolactam is in the range of about 0.25 percent by weight to about 25 percent by weight, based on the weight of the solution, and the solvent is dodecylphenol, which comprises the following steps: a. introducing dodecylphenol and the aqueous solution of epsilon-caprolactam to an extraction zone at a volumetric ratio from about 0.05 to about 1 part of dodecylphenol per part of aqueous solution of epsilon-caprolactam, in said extraction zone contacting the aqueous solution of epsilon-caprolactam with dodecylphenol to provide an extract comprising dodecylphenol, epsilon-caprolactam and no more than about 5 percent by weight of water based on the weight of said aqueous solution of epsilon-caprolactam, and a raffinate comprising at least about 95 percent by weight of water based on the weight of said aqueous solution of epsilon-caprolactam and less than about 5 percent by weight of dodecylphenol based on the total weight of dodecylphenol fed to the extraction zone; b. introducing the mixture of epsilon-caprolactam and dodecylphenol from step (a) into a distillation zone wherein the pressure is less than about 500 millimeters of mercury and the temperature is less than the decomposition temperatures of the epsilon-caprolactam and dodecylphenol at said pressure, to separate epsilon-caprolactam from the dodecylphenol; and c. recovering the epsilon-caprolactam.

Claim 12

A solvent extraction-distillation process for the recovery of epsilon-caprolactam from an aqueous solution thereof wherein the concentration of epsilon-caprolactam is in the range of about 0.25 percent by weight to about 25 percent by weight, based on the weight of the solution, and the solvent is dodecylphenol, which comprises the following steps: a. introducing dodecylphenol and the aqueous solution of epsilon-caprolactam to an extraction zone at a volumetric ratio from about 0.05 to about 1 part of dodecylphenol per part of aqueous solution of epsilon-caprolactam, in said extraction zone contacting the aqueous solution of epsilon-caprolactam with dodecylphenol to provide an extract comprising dodecylphenol, epsilon-caprolactam and no more than about 5 percent by weight of water based on the weight of said aqueous solution of epsilon-caprolactam, and a raffinate comprising at least about 95 percent by weight of water based on the weight of said aqueous solution of epsilon-caprolactam and less than about 5 percent by weight of dodecylphenol based on the total weight of dodecylphenol fed to the extraction zone; b. introducing the mixture of epsilon-caprolactam and dodecylphenol from step (a) into a distillation zone wherein the pressure is less than about 500 millimeters of mercury and the temperature is less than the decomposition temperatures of the epsilon-caprolactam and dodecylphenol at said pressure, to separate epsilon-caprolactam from the dodecylphenol; and c. recovering the epsilon-caprolactam.

Claim 13

The process defined in claim 9 wherein the volumetric ratio of the dodecylphenol and aqueous solution of epsilon-caprolactam fed to the extraction zone is no more than about 0.5 part of dodecylphenol per part of said aqueous solution.