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US4013631A Expired / Lapsed US ⏱️ 0.0 years remaining

Monoazo dyestuffs containing an N-β-1,2,3-triazolylethyl anilino coupling component

Assignee: Bayer AG
•
Filing: 1966-11-01
•
Granted: 1977-03-22
•
Expires: 1986-11-01
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Abstract

Abstract Azo dyestuffs of the formula WHEREIN A stands for the residue of the diazo component, R stands for hydrogen or methyl, R1 is a non-ionic substituent, M is a number from 0 to 2, R2 stands for hydrogen or for an aliphatic, araliphatic, or aromatic radical, R3 and R4 are independently selected from the group consisting of hydrogen, alkyl, alkoxy methyl, aryl, carboxy, carboalkoxy, said dyestuff being free of sulphonic acid groups and being adapted for use in dyeing and printing synthetic fiber materials. The quaternary salts of the dyestuffs are also adapted for use in such dyeing and printing.

Inventors

  • 👤 Gerhard Wolfrum
  • 👤 Heinrich Gold

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-23 19:01
CPC Classifications
C; C09; C09B; C09B29/00; C09B29/06; C09B29/08; C07; C07D; C07D249/00; C07D249/02; C07D249/04; C09B29/0805; C09B29/0807; C09B29/0809; C09B29/0811; C09B29/0832; C09B44/00; C09B44/02; C09B44/04; Y; Y10; Y10S; Y10S534/00; Y10S534/01

Claims Analysis

Total Claims: 12
Claim 1
Independent Claim 213 words
An azo dyestuff selected from the group consisting of ##SPC20## wherein R stands for hydrogen or methyl; R 1 is a member selected from the group consisting of chloro, bromo, lower alkyl, trifluoro lower alkyl, lower alkoxy, and acetylamino; m is an integer from 0 to 2; R 2 stands for hydrogen, lower alkyl, or substituted lower alkyl, wherein the substituents are selected from the group consisting of cyano and ethoxy carbonyl; R 3 and R 4 are independently selected from the group consisting of hydrogen, lower alkyl, lower alkoxy methyl, phenyl, chlorophenyl, bromophenyl, lower alkyl phenyl, carboxylic acid, carbolower alkoxy; R 5 is selected from the group consisting of lower alkyl and benzyl; A is selected from the group consisting of phenyl, substituted phenyl, thiazol (1,3)-2-yl, 5-nitro thiazol (1,3)-2-yl, benzothiazol (1,3)-2-yl, 6-chloro benzothiazol (1,3)-2-yl, 6-ethoxy benzothiazol (1,3)-2-yl, 3-phenyl-thiadiazole (1,2,4)-5-yl, pyridin-3-yl, quinolin-8-yl, indazol-3-yl, and triazol (1,2,4)-3-yl, wherein the substituents on said phenyl radical are members of the group consisting of halogen, lower alkyl, lower alkoxy, nitro, cyano, carboxy, trifluoromethyl, carboxy lower alkyl, sulphoxy lower alkyl, carbonamide, lower alkyl carbonamide, dilower alkyl carbonamide, sulfonamide, lower alkyl sulfonamide, and dilower alkyl sulfonamide; X stands for an anion; and wherein the alkyl groups contain from 1-4 carbon atoms; said dyestuff being free of sulphonic acid groups.
Claim 2
Dependent Claim 213 words
An azo dyestuff selected from the group consisting of ##SPC20## wherein R stands for hydrogen or methyl; R 1 is a member selected from the group consisting of chloro, bromo, lower alkyl, trifluoro lower alkyl, lower alkoxy, and acetylamino; m is an integer from 0 to 2; R 2 stands for hydrogen, lower alkyl, or substituted lower alkyl, wherein the substituents are selected from the group consisting of cyano and ethoxy carbonyl; R 3 and R 4 are independently selected from the group consisting of hydrogen, lower alkyl, lower alkoxy methyl, phenyl, chlorophenyl, bromophenyl, lower alkyl phenyl, carboxylic acid, carbolower alkoxy; R 5 is selected from the group consisting of lower alkyl and benzyl; A is selected from the group consisting of phenyl, substituted phenyl, thiazol (1,3)-2-yl, 5-nitro thiazol (1,3)-2-yl, benzothiazol (1,3)-2-yl, 6-chloro benzothiazol (1,3)-2-yl, 6-ethoxy benzothiazol (1,3)-2-yl, 3-phenyl-thiadiazole (1,2,4)-5-yl, pyridin-3-yl, quinolin-8-yl, indazol-3-yl, and triazol (1,2,4)-3-yl, wherein the substituents on said phenyl radical are members of the group consisting of halogen, lower alkyl, lower alkoxy, nitro, cyano, carboxy, trifluoromethyl, carboxy lower alkyl, sulphoxy lower alkyl, carbonamide, lower alkyl carbonamide, dilower alkyl carbonamide, sulfonamide, lower alkyl sulfonamide, and dilower alkyl sulfonamide; X stands for an anion; and wherein the alkyl groups contain from 1-4 carbon atoms; said dyestuff being free of sulphonic acid groups.
Claim 3
Dependent Claim 10 words
An azo dyestuff of claim 1 of the formula ##SPC21##
Claim 4
Dependent Claim 10 words
An azo dyestuff of claim 1 of the formula ##SPC22##
Claim 5
Dependent Claim 18 words
A dyestuff of claim 2 wherein A is selected from the group consisting of phenyl and substituted phenyl.
Claim 6
Dependent Claim 18 words
A dyestuff of claim 3 wherein A is selected from the group consisting of phenyl and substituted phenyl.
Claim 7
Dependent Claim 10 words
A dyestuff of claim 2 corresponding to the formula ##SPC23##
Claim 8
Dependent Claim 10 words
A dyestuff of claim 4 corresponding to the formula ##SPC24##
Claim 9
Dependent Claim 10 words
A dyestuff of claim 2 corresponding to the formula ##SPC25##
Claim 10
Dependent Claim 10 words
A dyestuff of claim 5 corresponding to the formula ##SPC26##
Claim 11
Dependent Claim 10 words
A dyestuff of claim 5 corresponding to the formula ##SPC27##
Claim 12
Dependent Claim 10 words
A dyestuff of claim 3 corresponding to the formula ##SPC28##

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-21 1980-09-20 1981-03-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-21 1984-09-20 1985-03-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-21 1988-09-20 1989-03-22 $7700.00 Window Closed / Lapsed

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