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US4013600A Expired / Lapsed US ⏱️ 0.0 years remaining

Aqueous compositions of polyimides containing hetero-polysaccharide

Assignee: Rhone Poulenc Industries SA
•
Filing: 1975-05-16
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Granted: 1977-03-22
•
Expires: 1995-05-16
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Abstract

Abstract Pseudoplastic aqueous suspensions are provided having good storage stability. These suspensions are of a prepolymer powder prepared from A. A imide group-containing compound chosen from the group consisting of:

Inventors

  • 👤 Robert Cassat

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 19:39
CPC Classifications
B; B32; B32B; B32B5/00; B32B5/22; B32B5/24; B32B5/26; B32B5/02; B32B5/024; C; C08; C08J; C08J3/00; C08J3/02; C08J3/03; C08J3/05; C08J5/00; C08J5/24; C08J5/241; C08J5/244; C08J5/249; C08L; C08L79/00; C08L79/04; C08L79/08; C08L79/085; B32B2260/00; B32B2260/02; B32B2260/021; B32B2305/00; B32B2305/07; B32B2305/076; C08J2379/00; C08J2379/04; C08J2379/08; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24149

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 225 words
A pseudoplastic aqueous suspension of a prepolymer powder prepared from: A. a imide group-containing compound chosen from the group consisting of: a. a bis-imide of the formula: ##STR14## in which D represents a divalent radical which has the formula: ##STR15## wherein Y represents H, CH 3 or Cl and m is equal to 0 or 1, and A represents a divalent organic radical containing 2 to 30 carbon atoms, and b. a mixture of a bis-imide of formula (I) and a monoimide of the formula: ##STR16## in which D is as defined above and R represents a hydrogen atom or a monovalent organic radical containing 1 to 20 carbon atoms, and B. an amino compound chosen from the group consisting of: a. one or more polyamines containing 2 to 5 primary or secondary amino groups, at least one of these groups being primary, b. a mixture comprising one or more polyamines as defined under a) and one or more primary and/or secondary mono-amines and/or one or more secondary polyamines, and c. a polyamine of the general formula: ##STR17## in which x represents a number from 0.1 to 2 and R' represents a divalent hydrocarbon radical with 1 to 8 carbon atoms, the suspension also comprising, based on the weight of the powder, 0.01 to 8% by weight of a heteropolysaccharide of very high molecular weight.
Claim 2
Dependent Claim 225 words
A pseudoplastic aqueous suspension of a prepolymer powder prepared from: A. a imide group-containing compound chosen from the group consisting of: a. a bis-imide of the formula: ##STR14## in which D represents a divalent radical which has the formula: ##STR15## wherein Y represents H, CH 3 or Cl and m is equal to 0 or 1, and A represents a divalent organic radical containing 2 to 30 carbon atoms, and b. a mixture of a bis-imide of formula (I) and a monoimide of the formula: ##STR16## in which D is as defined above and R represents a hydrogen atom or a monovalent organic radical containing 1 to 20 carbon atoms, and B. an amino compound chosen from the group consisting of: a. one or more polyamines containing 2 to 5 primary or secondary amino groups, at least one of these groups being primary, b. a mixture comprising one or more polyamines as defined under a) and one or more primary and/or secondary mono-amines and/or one or more secondary polyamines, and c. a polyamine of the general formula: ##STR17## in which x represents a number from 0.1 to 2 and R' represents a divalent hydrocarbon radical with 1 to 8 carbon atoms, the suspension also comprising, based on the weight of the powder, 0.01 to 8% by weight of a heteropolysaccharide of very high molecular weight.
Claim 3
Dependent Claim 32 words
A suspension according to claim 1 in which the heteropolysaccharide is one produced by fermentation of a carbohydrate by bacteria of the Xanthomonas or Arthrobacter genus or yeasts of the Cryptococcus genus.
Claim 4
Dependent Claim 39 words
A suspension according to claim 1, which also comprises a polar organic solvent which is miscible with water, has a boiling point from 110° to 270° C, in an amount up to 15% by weight of the liquid phase.
Claim 5
Dependent Claim 13 words
A suspension according to claim 3, in which the organic solvent is N-methylpyrrolidone.
Claim 6
Dependent Claim 22 words
A suspension according to claim 1 in which the prepolymer represents, by weight, 5 to 60% of the weight of the composition.
Claim 7
Dependent Claim 20 words
A suspension according to claim 1, in which the prepolymer is a product of the reaction of N,N'-4,4'-diphenylmethane-bis-maleimide and 4,4'-diamino-diphenylmethane.
Claim 8
Dependent Claim 28 words
Process for the preparation of a suspension as defined in claim 1 which comprises dispersing the prepolymer in the liquid phase containing the heteropolysaccharide, dissolved therein, by agitation.

References Cited (Backward Citations)

US3018290A Cited
US3349077A Cited
US3562787A Cited
US3447940A Cited
US3717615A Cited
US3894976A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-21 1980-09-20 1981-03-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-21 1984-09-20 1985-03-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-21 1988-09-20 1989-03-22 $7700.00 Window Closed / Lapsed

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