US4013600A
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US
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Aqueous compositions of polyimides containing hetero-polysaccharide
Assignee: Rhone Poulenc Industries SA
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Filing: 1975-05-16
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Granted: 1977-03-22
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Expires: 1995-05-16
Abstract
Abstract Pseudoplastic aqueous suspensions are provided having good storage stability. These suspensions are of a prepolymer powder prepared from A. A imide group-containing compound chosen from the group consisting of:
Inventors
- 👤 Robert Cassat
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-24 19:39
CPC Classifications
B; B32; B32B; B32B5/00; B32B5/22; B32B5/24; B32B5/26; B32B5/02; B32B5/024; C; C08; C08J; C08J3/00; C08J3/02; C08J3/03; C08J3/05; C08J5/00; C08J5/24; C08J5/241; C08J5/244; C08J5/249; C08L; C08L79/00; C08L79/04; C08L79/08; C08L79/085; B32B2260/00; B32B2260/02; B32B2260/021; B32B2305/00; B32B2305/07; B32B2305/076; C08J2379/00; C08J2379/04; C08J2379/08; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24149
Claims Analysis
Total Claims: 8
Claim 1
Independent Claim
225 words
A pseudoplastic aqueous suspension of a prepolymer powder prepared from: A. a imide group-containing compound chosen from the group consisting of: a. a bis-imide of the formula: ##STR14## in which D represents a divalent radical which has the formula: ##STR15## wherein Y represents H, CH 3 or Cl and m is equal to 0 or 1, and A represents a divalent organic radical containing 2 to 30 carbon atoms, and b. a mixture of a bis-imide of formula (I) and a monoimide of the formula: ##STR16## in which D is as defined above and R represents a hydrogen atom or a monovalent organic radical containing 1 to 20 carbon atoms, and B. an amino compound chosen from the group consisting of: a. one or more polyamines containing 2 to 5 primary or secondary amino groups, at least one of these groups being primary, b. a mixture comprising one or more polyamines as defined under a) and one or more primary and/or secondary mono-amines and/or one or more secondary polyamines, and c. a polyamine of the general formula: ##STR17## in which x represents a number from 0.1 to 2 and R' represents a divalent hydrocarbon radical with 1 to 8 carbon atoms, the suspension also comprising, based on the weight of the powder, 0.01 to 8% by weight of a heteropolysaccharide of very high molecular weight.
Claim 2
Dependent Claim
225 words
A pseudoplastic aqueous suspension of a prepolymer powder prepared from: A. a imide group-containing compound chosen from the group consisting of: a. a bis-imide of the formula: ##STR14## in which D represents a divalent radical which has the formula: ##STR15## wherein Y represents H, CH 3 or Cl and m is equal to 0 or 1, and A represents a divalent organic radical containing 2 to 30 carbon atoms, and b. a mixture of a bis-imide of formula (I) and a monoimide of the formula: ##STR16## in which D is as defined above and R represents a hydrogen atom or a monovalent organic radical containing 1 to 20 carbon atoms, and B. an amino compound chosen from the group consisting of: a. one or more polyamines containing 2 to 5 primary or secondary amino groups, at least one of these groups being primary, b. a mixture comprising one or more polyamines as defined under a) and one or more primary and/or secondary mono-amines and/or one or more secondary polyamines, and c. a polyamine of the general formula: ##STR17## in which x represents a number from 0.1 to 2 and R' represents a divalent hydrocarbon radical with 1 to 8 carbon atoms, the suspension also comprising, based on the weight of the powder, 0.01 to 8% by weight of a heteropolysaccharide of very high molecular weight.
Claim 3
Dependent Claim
32 words
A suspension according to claim 1 in which the heteropolysaccharide is one produced by fermentation of a carbohydrate by bacteria of the Xanthomonas or Arthrobacter genus or yeasts of the Cryptococcus genus.
Claim 4
Dependent Claim
39 words
A suspension according to claim 1, which also comprises a polar organic solvent which is miscible with water, has a boiling point from 110° to 270° C, in an amount up to 15% by weight of the liquid phase.
Claim 5
Dependent Claim
13 words
A suspension according to claim 3, in which the organic solvent is N-methylpyrrolidone.
Claim 6
Dependent Claim
22 words
A suspension according to claim 1 in which the prepolymer represents, by weight, 5 to 60% of the weight of the composition.
Claim 7
Dependent Claim
20 words
A suspension according to claim 1, in which the prepolymer is a product of the reaction of N,N'-4,4'-diphenylmethane-bis-maleimide and 4,4'-diamino-diphenylmethane.
Claim 8
Dependent Claim
28 words
Process for the preparation of a suspension as defined in claim 1 which comprises dispersing the prepolymer in the liquid phase containing the heteropolysaccharide, dissolved therein, by agitation.
References Cited (Backward Citations)
US3018290A
Cited
US3349077A
Cited
US3562787A
Cited
US3447940A
Cited
US3717615A
Cited
US3894976A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-21 | 1980-09-20 | 1981-03-22 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-21 | 1984-09-20 | 1985-03-22 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-21 | 1988-09-20 | 1989-03-22 | $7700.00 | Window Closed / Lapsed |