US4012553A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Resinous repair pad
Assignee: 3M Co
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Filing: 1975-07-07
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Granted: 1977-03-15
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Expires: 1995-07-07
Abstract
Abstract An adherent reinforced resinous pad, consisting of a fibrous mat or fabric impregnated with a soft sticky resinous composition which hardens on exposure to ultraviolet radiation, enclosed between removable protective coverings. Resin flow is inhibited, without destroying adhesion, by controlled gelatinization.
Inventors
- 👤 Lawrence M. Clemens
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-23 22:42
CPC Classifications
B; B29; B29C; B29C73/00; Y; Y10; Y10T; Y10T428/00; Y10T428/20; Y10T428/31504; Y10T428/31551; Y10T428/31616; Y10T428/31725; Y10T428/31736; Y10T428/31786; Y10T442/00; Y10T442/20; Y10T442/2738; Y10T442/2754; Y10T442/2861; Y10T442/2893; Y10T442/2926; Y10T442/2992
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
164 words
Method of making a stable exudation-resistant resin-impregnated adherent fibrous sheet material which when pressed against a receptive substrate and then exposed to actinic radiation will cure to a hard, non-tacky, solvent-resistant state and remain firmly adhered to said substrate, comprising impregnating a porous, fibrous mat with a radiation-curable sticky fluid resinous composition comprising unsaturated polyester, unsaturated liquid monomer copolymerizable therewith, and an acyloin photoinitiator, said resinous composition being present in an amount sufficient to provide the impregnated mat with a sticky surface, enclosing the impregnated mat between a transparent film and another protective supporting web, and then exposing the product to a non-reaction-sustaining amount of actinic radiation sufficient to gelatinize, but not to rigidify, the resinous composition wherein said composition remains in a stable condition substantially free of reaction-sustaining free radicals in which a portion of the composition swells, but does not dissolve when suspended for 18 hours in 1:1 acetone-toluene and in which it exhibits a decrease in penetration value of approximately one-half.
Claim 2
Dependent Claim
164 words
Method of making a stable exudation-resistant resin-impregnated adherent fibrous sheet material which when pressed against a receptive substrate and then exposed to actinic radiation will cure to a hard, non-tacky, solvent-resistant state and remain firmly adhered to said substrate, comprising impregnating a porous, fibrous mat with a radiation-curable sticky fluid resinous composition comprising unsaturated polyester, unsaturated liquid monomer copolymerizable therewith, and an acyloin photoinitiator, said resinous composition being present in an amount sufficient to provide the impregnated mat with a sticky surface, enclosing the impregnated mat between a transparent film and another protective supporting web, and then exposing the product to a non-reaction-sustaining amount of actinic radiation sufficient to gelatinize, but not to rigidify, the resinous composition wherein said composition remains in a stable condition substantially free of reaction-sustaining free radicals in which a portion of the composition swells, but does not dissolve when suspended for 18 hours in 1:1 acetone-toluene and in which it exhibits a decrease in penetration value of approximately one-half.
Claim 3
Dependent Claim
29 words
A method according to claim 1 wherein the nonreaction-sustaining amount of actinic radiation is about 2 watts per square inch for a period of about 1 to 12 minutes.
Claim 4
Dependent Claim
118 words
A stable exudation-resistant resin-impregnated sticky fibrous sheet material capable, when pressed against a receptive substrate and then exposed to actinic radiation, of curing to a hard, non-tacky, solvent-resistant state and of then remaining firmly adhered to said substrate, comprising a porous, fibrous mat impregnated with a gelatinized radiation-curable sticky fluid resinous composition comprising unsaturated polyester, unsaturated liquid monomer copolymerizable therewith, and an acyloin photoinitiator, said composition being substantially free of reaction-sustaining free radicals, wherein at least a portion of the resinous composition in said sheet swells but does not dissolve when the sheet is suspended for 18 hours in a 1:1 acetone-toluene mixture, said sheet material being enclosed between a transparent film and a second protective supporting web.
Claim 5
Dependent Claim
118 words
A stable exudation-resistant resin-impregnated sticky fibrous sheet material capable, when pressed against a receptive substrate and then exposed to actinic radiation, of curing to a hard, non-tacky, solvent-resistant state and of then remaining firmly adhered to said substrate, comprising a porous, fibrous mat impregnated with a gelatinized radiation-curable sticky fluid resinous composition comprising unsaturated polyester, unsaturated liquid monomer copolymerizable therewith, and an acyloin photoinitiator, said composition being substantially free of reaction-sustaining free radicals, wherein at least a portion of the resinous composition in said sheet swells but does not dissolve when the sheet is suspended for 18 hours in a 1:1 acetone-toluene mixture, said sheet material being enclosed between a transparent film and a second protective supporting web.
Claim 6
Dependent Claim
15 words
A sheet material according to claim 3 wherein said porous, fibrous mat comprises glass fibers.
Claim 7
Dependent Claim
15 words
A sheet material according to claim 3 wherein said porous, fibrous mat comprises polyester fibers.
Claim 8
Dependent Claim
15 words
A sheet material according to claim 3 wherein said porous, fibrous mat comprises nylon fibers.
Claim 9
Dependent Claim
16 words
A method according to claim 1 wherein the protective supporting web is a silicone-treated paper sheet.
Claim 10
Dependent Claim
17 words
A sheet material according to claim 3 wherein the protective supporting web is a silicone-treated paper sheet.
Claim 11
Dependent Claim
13 words
A sheet material according to claim 3 wherein the acyloin photoinitiator is benzoin.
Claim 12
Dependent Claim
15 words
A sheet material according to claim 3 wherein the acyloin photoinitiator is benzoin ethyl ether.
References Cited (Backward Citations)
US3108902A
Cited
US3271182A
Cited
US3658620A
Cited
US3770491A
Cited
US3810816A
Cited
US3867153A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-14 | 1980-09-13 | 1981-03-15 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-14 | 1984-09-13 | 1985-03-15 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-14 | 1988-09-13 | 1989-03-15 | $7700.00 | Window Closed / Lapsed |