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US4012543A Expired / Lapsed US ⏱️ 0.0 years remaining

Coated paper and method of making same

Assignee: Warren SD Co
•
Filing: 1974-08-08
•
Granted: 1977-03-15
•
Expires: 1994-08-08
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Abstract

Abstract A coated paper having high gloss and high bulk and a method for producing the paper wherein a high-solids coating is applied to the paper and pressed against a heated finishing surface.

Inventors

  • 👤 Howard Lee Ranger
  • 👤 Mahlon Randall Kirk
  • 👤 Abbott Woodward Mosher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 15:21
CPC Classifications
D; D21; D21H; D21H17/00; D21H19/00; D21H19/80; D21H19/82; D21H19/822

Claims Analysis

Total Claims: 26
Claim 1
Independent Claim 406 words
A method for the preparation of a uniformly, densely coated paper substrate displaying excellent ink holdout properties, characterized by high bulk, increased brightness and opacity, and a gloss value of at least 50, which method essentially consists of: i. applying a coating of an aqueous top coating composition to at least one surface of a given fibrous cellulosic substrate; ii. said fibrous cellulosic substrate having been prepared to resist penetration of the said aqueous top coating composition; iii. said aqueous top coating composition having a total solids content of at least about 60 percent by weight, and said solids content thereof comprising a major proportion of a paper-coating grade pigment, a minor proportion of a thermoplastic binder and a minor amount of an anti-sticking agent; thence iv. gloss-calendering, temporarily plasticizing and molding said coated substrate by conveying same through a nip formed between a heated polished drum and a resilient backing roll to at least partially coalesce the thermoplastic binder content of the said aqueous top coating composition; v. the temperature of said heated polished drum ranging from between about 82° to 150° C. and the pressure exerted on said coated substrate in said nip ranging from between about 400 to 800 pounds per lineal inch; vi. the amount of water loss from the said top coating in that time interval between the application (i) thereof and the gloss-calendering and molding operation (iv) being less than that amount such as would effect substantial decrease in resultant high gloss; vii. the temperature of the said coated substrate not being elevated to a value substantially above about 60° C. in the said time interval between the application (i) and the gloss-calendering and molding operation (iv); viii. concomitantly, the water content of the said top coating, at the point of entry of the said coated substrate into the said nip, is such that, in the absence of the said minor proportion of anti-sticking agent, the substrate coating would stick to the surface of the said gloss-calendering, heated polished drum; and ix. removing the thus coated and gloss-calendered fibrous cellulosic substrate from contact with the said heated polished drum and resilient backing roll as same emerges from the said nip formed therebetween; x. whereby there is recovered a smooth, molded, polished, high gloss fibrous cellulosic substrate having the high bulk and density characteristics of lightly machine-calendered paper, albeit its said coating is itself dense, uniform and provides excellent ink holdout.
Claim 2
Independent Claim 406 words
A method for the preparation of a uniformly, densely coated paper substrate displaying excellent ink holdout properties, characterized by high bulk, increased brightness and opacity, and a gloss value of at least 50, which method essentially consists of: i. applying a coating of an aqueous top coating composition to at least one surface of a given fibrous cellulosic substrate; ii. said fibrous cellulosic substrate having been prepared to resist penetration of the said aqueous top coating composition; iii. said aqueous top coating composition having a total solids content of at least about 60 percent by weight, and said solids content thereof comprising a major proportion of a paper-coating grade pigment, a minor proportion of a thermoplastic binder and a minor amount of an anti-sticking agent; thence iv. gloss-calendering, temporarily plasticizing and molding said coated substrate by conveying same through a nip formed between a heated polished drum and a resilient backing roll to at least partially coalesce the thermoplastic binder content of the said aqueous top coating composition; v. the temperature of said heated polished drum ranging from between about 82° to 150° C. and the pressure exerted on said coated substrate in said nip ranging from between about 400 to 800 pounds per lineal inch; vi. the amount of water loss from the said top coating in that time interval between the application (i) thereof and the gloss-calendering and molding operation (iv) being less than that amount such as would effect substantial decrease in resultant high gloss; vii. the temperature of the said coated substrate not being elevated to a value substantially above about 60° C. in the said time interval between the application (i) and the gloss-calendering and molding operation (iv); viii. concomitantly, the water content of the said top coating, at the point of entry of the said coated substrate into the said nip, is such that, in the absence of the said minor proportion of anti-sticking agent, the substrate coating would stick to the surface of the said gloss-calendering, heated polished drum; and ix. removing the thus coated and gloss-calendered fibrous cellulosic substrate from contact with the said heated polished drum and resilient backing roll as same emerges from the said nip formed therebetween; x. whereby there is recovered a smooth, molded, polished, high gloss fibrous cellulosic substrate having the high bulk and density characteristics of lightly machine-calendered paper, albeit its said coating is itself dense, uniform and provides excellent ink holdout.
Claim 3
Dependent Claim 27 words
The method as defined by claim 1, wherein the time interval between the said application (i) and the said gloss-calendering (iv) does not exceed about 5 seconds.
Claim 4
Dependent Claim 24 words
The method as defined by claim 2, wherein the said method is conducted at speeds of from about 1,000 to 3,000 feet per minute.
Claim 5
Dependent Claim 26 words
The method as defined by claim 1, wherein the preparation (ii) is by internally or externally sizing the base stock comprising the given fibrous cellulosic substrate.
Claim 6
Dependent Claim 54 words
The method as defined by claim 4, wherein the said base stock is externally sized by applying to at least one face surface thereof, an intermediate coating composition comprising a paper-coating grade pigment, the particle size thereof being less than about 5 microns, and a non-thermoplastic binder therefor, and thence drying said intermediate coating.
Claim 7
Dependent Claim 25 words
The method as defined by claim 1, wherein the weight of the said given fibrous cellulosic substrate is greater than 30 grams per square meter.
Claim 8
Dependent Claim 28 words
The method as defined by claim 1, wherein the said aqueous top coating composition (iii) has a total solids content of from 60 to 70 percent by weight.
Claim 9
Dependent Claim 45 words
The method as defined by claim 1, wherein the temperature of said heated polished drum ranges from between about 107° to 135° C. and the pressure exerted on said coated substrate in said nip ranges from between about 450 to 700 pounds per lineal inch.
Claim 10
Dependent Claim 31 words
The method as defined by claim 1, wherein the amount of top coating composition applied ranges from between about 5.0 to 18 grams per square meter of said fibrous cellulosic substrate.
Claim 11
Dependent Claim 27 words
The method as defined by claim 1, wherein the amount of water loss (vi) from the said top coating is less than about 23 percent by weight.
Claim 12
Dependent Claim 27 words
The method as defined by claim 10, wherein the amount of water loss (vi) from the said top coating does not exceed about 10 percent by weight.
Claim 13
Dependent Claim 32 words
The method as defined by claim 1, wherein the paper-coating grade pigment comprising the aqueous top coating composition (iii), comprises from about 10 to 90 percent by weight of a glossing pigment.
Claim 14
Dependent Claim 37 words
The method as defined by claim 12, wherein the said glossing pigment comprises a mixture of coating clay and a member selected from the group consisting of aluminum hydrate, precipitated calcium carbonate, titanium dioxide and admixtures thereof.
Claim 15
Dependent Claim 24 words
The method as defined by claim 13, wherein the coating clay comprises at least about 60 percent by weight of the total glossing pigment.
Claim 16
Dependent Claim 43 words
The method as defined by claim 12, wherein the paper-coating grade pigment comprising the aqueous top coating composition (iii) comprises up to about 20 percent by weight of a non-glossing pigment having an average equivalent spherical diameter in excess of about 2 microns.
Claim 17
Dependent Claim 22 words
The method as defined by claim 1, wherein the thermoplastic binder comprising the aqueous top coating composition (iii) comprises an elastomeric latex.
Claim 18
Dependent Claim 20 words
The method as defined by claim 16, wherein the thermoplastic latex binder comprises a minor proportion of a non-thermoplastic adhesive.
Claim 19
Dependent Claim 43 words
The method as defined by claim 1, wherein the anti-sticking agent comprising the aqueous top coating composition (iii), comprises a member selected from the group consisting of sulfonated castor oil, potassium oleate, and a mixture of predispersed calcium stearate and emulsified oleic acid.
Claim 20
Dependent Claim 22 words
The method as defined by claim 18, wherein the anti-sticking agent comprises the mixture of predispersed calcium stearate and emulsified oleic acid.
Claim 21
Dependent Claim 37 words
The method as defined by claim 1, wherein the aqueous top coating composition (iii) further comprises a member selected from the group consisting of a defoaming agent, a dye, an insolubilizer, an optical brightener and mixtures thereof.
Claim 22
Dependent Claim 24 words
The method as defined by claim 1, further comprising passing the thus coated and gloss calendered substrate through at least one more gloss-calendering nip.
Claim 23
Dependent Claim 181 words
A smooth, molded, polished, uniformly densely coated paper substrate displaying excellent ink holdout properties, said coated substrate consisting essentially of a coated article of: i. a sized, fibrous cellulosic substrate having a weight greater than about 30 grams per square meter, said substrate bearing on at least one face surface thereof; ii. a smooth, molded, uniformly dense, high gloss coating having increased brightness, opacity and a gloss value of at least 50, said coating comprising a major proportion of a paper-coating grade pigment, a minor proportion of an at least partially coalesced thermoplastic binder and a minor amount of an anti-sticking agent; iii. said coated article displaying the high bulk and density characteristics of lightly machine-calendered paper, with the said coating (ii) comprising the same being itself dense and uniform; and iv. whereby the total amount of bodystock material comprising the said fibrous cellulosic substrate (i) is significantly lighter in weight than that amount required for a high-quality supercalendered enamel coated substrate having comparable gloss characteristics and printing properties, as respectively illustrated in the FIGS. 1 to 4 of the drawing.
Claim 24
Dependent Claim 181 words
A smooth, molded, polished, uniformly densely coated paper substrate displaying excellent ink holdout properties, said coated substrate consisting essentially of a coated article of: i. a sized, fibrous cellulosic substrate having a weight greater than about 30 grams per square meter, said substrate bearing on at least one face surface thereof; ii. a smooth, molded, uniformly dense, high gloss coating having increased brightness, opacity and a gloss value of at least 50, said coating comprising a major proportion of a paper-coating grade pigment, a minor proportion of an at least partially coalesced thermoplastic binder and a minor amount of an anti-sticking agent; iii. said coated article displaying the high bulk and density characteristics of lightly machine-calendered paper, with the said coating (ii) comprising the same being itself dense and uniform; and iv. whereby the total amount of bodystock material comprising the said fibrous cellulosic substrate (i) is significantly lighter in weight than that amount required for a high-quality supercalendered enamel coated substrate having comparable gloss characteristics and printing properties, as respectively illustrated in the FIGS. 1 to 4 of the drawing.
Claim 25
Dependent Claim 27 words
The coated paper substrate as defined by claim 22, wherein the said fibrous cellulosic substrate (i) bears a high gloss coating (ii) at both face surfaces thereof.
Claim 26
Dependent Claim 45 words
The coated paper substrate, as defined by claim 22, wherein the said fibrous cellulosic substrate (i) is externally sized by means of an intermediate interlayer comprising a paper-coated grade pigment, the particle sizes thereof being less than about 5 microns, and a non-thermoplastic binder thereof.

References Cited (Backward Citations)

US3028258A Cited
US3268354A Cited
US3296014A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-14 1980-09-13 1981-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-14 1984-09-13 1985-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-14 1988-09-13 1989-03-15 $7700.00 Window Closed / Lapsed

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