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Photocurable compositions containing s-aryl arylcarbothioic acid esters as photoinitiators

Assignee: Eastman Kodak Co
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Filing: 1976-02-17
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Granted: 1977-03-15
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Expires: 1996-02-17
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Abstract

Abstract Compositions comprising a photocurable ethylenically unsaturated compound and an S-aryl arylcarbothioic acid ester or a bis-S-aryl aryl-dicarbothioic acid ester.

Inventors

  • 👤 Richard H. S. Wang
  • 👤 James G. Pacifici
  • 👤 Gordon C. Newland

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 15:43
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/031; C; C08; C08F; C08F299/00; C08F299/02; C08F299/04; C08F299/0407; C08F299/0421; C08F299/0428; C08F299/0435; C09; C09D; C09D11/00; C09D11/02; C09D11/10; C09D11/101; C09D4/00; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/114; Y10S430/122; Y10S525/00; Y10S525/92

Claims Analysis

Total Claims: 9
Claim 1
Independent Claim 70 words
A composition comprising a photocurable ethylenically unsaturated compound and an S-aryl arylcarbothioic acid ester or a bis-S-aryl aryldicarbothioic acid ester photoinitiating effective amount of a compound having the formula: ##STR2##wherein n is 1 or 2 and R 1 and R 2 are the same or different and are hydrogen, alkyl of up to about 12 carbon atoms, alkoxy of up to about 12 carbon atoms, halogen, phenyl, phenoxy or 2-benzoxazolyl.
Claim 2
Dependent Claim 70 words
A composition comprising a photocurable ethylenically unsaturated compound and an S-aryl arylcarbothioic acid ester or a bis-S-aryl aryldicarbothioic acid ester photoinitiating effective amount of a compound having the formula: ##STR2##wherein n is 1 or 2 and R 1 and R 2 are the same or different and are hydrogen, alkyl of up to about 12 carbon atoms, alkoxy of up to about 12 carbon atoms, halogen, phenyl, phenoxy or 2-benzoxazolyl.
Claim 3
Dependent Claim 40 words
A composition according to claim 1 wherein n is 1, R 1 is hydrogen or lower alkyl containing up to about 4 carbon atoms, and R 2 is hydrogen, lower alkyl containing up to about 4 carbon atoms or 2-benzoxazolyl.
Claim 4
Dependent Claim 23 words
A composition according to claim 1 wherein the photocurable ethylenically unsaturated compound is a derivative of acrylic acid or an unsaturated polyester resin.
Claim 5
Dependent Claim 29 words
A composition according to claim 1 wherein the ester is present in a concentration of about 0.1 to 15 weight percent based on the total weight of the composition.
Claim 6
Dependent Claim 29 words
A composition according to claim 1 wherein the photoinitiating effective amount is a concentration of about 0.5 to 10 weight percent based on the total weight of the composition.
Claim 7
Dependent Claim 42 words
A composition comprising a photocurable ethylenically unsaturated compound and about 0.5 to 10 weight percent based on the weight of the photocurable ethylenically unsaturated compound, of a compound having the formula ##STR3##wherein R 1 and R 2 each is hydrogen or methyl.
Claim 8
Dependent Claim 42 words
A composition comprising a photocurable ethylenically unsaturated compound and about 0.5 to 10 weight percent based on the weight of the photocurable ethylenically unsaturated compound, of a compound having the formula ##STR3##wherein R 1 and R 2 each is hydrogen or methyl.
Claim 9
Dependent Claim 23 words
A composition according to claim 6 wherein the photocurable ethylenically unsaturated compound is an ester of acrylic acid or an unsaturated polyester resin.

References Cited (Backward Citations)

US3827957A Cited
US3903322A Cited
US3962056A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-14 1980-09-13 1981-03-15 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-14 1984-09-13 1985-03-15 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-14 1988-09-13 1989-03-15 $7700.00 Window Closed / Lapsed

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