N-Butane/acetone separation using sulfolane

Claim 2

A process to separate a first mixture of n-butane and from about 0.7 to 4.5 weight percent acetone, which method comprises a. contacting said mixture in a fluid contacting zone with a sulfolane having the formula ##STR3##in which the radicals R which can be the same or different are individually selected from the group consisting of hydrogen, alkyl radicals having 1 to 4 carbon atoms, cycloalkyl radicals having 3 to 6 carbon atoms, and phenyl, which radicals R in turn can be unsubstituted or substituted by alkyl, cycloalkyl and aryl radicals, said sulfolane having 4 to 12 carbon atoms per molecule, and b. removing a first stream consisting essentially of n-butane and being essentially free of acetone and a second stream consisting essentially of sulfolane and acetone from said contacting zone.

Claim 3

A process in accordance with claim 1 wherein said second stream is fractionally distilled to produce a third stream consisting essentially of acetone and a fourth stream consisting essentially of sulfolane and being essentially acetone-free.

Claim 4

A process in accordance with claim 1 wherein a liquid mixture of n-butane and acetone is contacted with liquid sulfolane.

Claim 5

A process in accordance with claim 1 further comprising a. extractively distilling a second mixture consisting essentially of n-butane and butylenes in an extractive distillation zone with an extractive solvent consisting essentially of a mixture of acetone and a sulfolane having the general formula ##STR4##wherein the radicals R which can be the same or different are individually selected from the group consisting of hydrogen, alkyl radicals having 1 to 4 carbon atoms, cycloalkyl radicals having 3 to 6 carbon atoms, and phenyl, which radicals R in turn can be unsubstituted or substituted by alkyl, cycloalkyl and aryl radicals, said sulfolane having 4 to 12 carbon atoms per molecule, to produce an overhead stream consisting essentially of n-butane and some acetone and a fifth stream consisting essentially of sulfolane, acetone and butylenes, and b. contacting said overhead stream as said first mixture with said sulfolane in said contacting zone to produce said first and second streams.

Claim 6

A process in accordance with claim 4 wherein said extractive solvent consists essentially of 60 to 80 weight percent sulfolane and 40 to 20 weight percent of acetone.

Claim 7

A process in accordance with claim 4 wherein said fifth stream is fractionated into a hydrocarbon stream consisting essentially of butylenes and a sixth stream consisting essentially of sulfolane and acetone.

Claim 8

A process in accordance with claim 6 wherein said sixth stream is recycled into said extractive distillation zone as part of said extractive solvent.

Claim 9

A process in accordance with claim 7 wherein said second stream is fractionally distilled to produce a third stream consisting essentially of acetone and a fourth stream consisting essentially of sulfolane, and wherein said third stream consisting essentially of acetone and said sixth stream consisting essentially of sulfolane and acetone are mixed to form a seventh stream, and wherein said seventh stream is introduced into said extractive distillation as said extractive solvent.