Multi-layered photoconductive member

Claim 2

An electrophotographic imaging member having a composite photoconductive insulating film wherein one layer of said film comprises a photoconductive material capable of substantial spectral response in the visible region of the electromagnetic spectrum and a second layer of electronically active insulating polymer contiguous with said photoconductive layer, said electronically active insulating polymer comprising recurring structural units of the formula: ##STR2##wherein X is oxygen or dicyanomethylene; Y and Z are independently selected from the group consisting of NO 2 , halogen, --CN and --CF 3 ; R is a hydrocarbylene radical having from 1 to 10 carbon atoms; R' is oxygen or sulfur; m is 0 or 1; and n and n' can range from 0 to 3 said electronically active insulating polymer film being transparent, capable of facile transport of electrons which are injected into it upon photoexcitation of the contiguous photoconductive layer and incapable of substantial spectral response within the wavelength of spectral response of the photoconductive layer.

Claim 3

The imaging member of claim 1 wherein the electronically active insulating polymer is the product of the esterfication of ethylene glycol and 4,5-dinitrofluorenone-2,7-dicarboxylic acid chloride.

Claim 4

The imaging member of claim 1 wherein the electronically active insulating polymer is the product of the esterfication of 1,3-propane diol and 4,5-dinitrofluorenone-2,7-dicarboxylic acid chloride.

Claim 5

The imaging member of claim 1 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and 4,5-dinitrofluorenone-2,6-dicarboxylic acid chloride.

Claim 6

The imaging member of claim 1 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and 9-dicyanomethylene fluorene-2,7-dicarboxylic acid chloride.

Claim 7

The imaging member of claim 1 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and fluorenone-2,7-dicarboxylic acid chloride.

Claim 8

The imaging member of claim 1 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and 4,5-dinitro-9-dicyanomethylene fluorenone-2,7-dicarboxylic acid chloride.

Claim 9

The imaging member of claim 1 wherein the electronically active insulating polymer is the product of the esterfication of 1,2-eicosane diol and 4,5-dinitrofluorenone-2,7-dicarboxylic acid chloride.

Claim 10

An electrophotographic imaging member having a composite photoconductive insulating film wherein on layer of said film has a thickness in the range of from about 0.2 to about 20 microns and comprises a photoconductive material capable of substantial spectral response in the visible region of the electromagnetic spectrum and a second layer which has a thickness in the range of from about 5 to about 100 microns and comprises an electronically active insulating polymer contiguous with said photoconductive layer, the ratio of thickness of said photoconductive layer to said transport layer being in the range of from about 1:2 to about 1:200, said electronically active insulating polymer comprising recurring structural units of the formula: ##STR3## wherein X is oxygen or dicyanomethylene; Y and Z are independently selected from the group consisting of No 2 , halogen --CN and --CF 3 ; R is a hydrocarbylene radical having from 1 to 10 carbon atoms; R' is oxygen or sulfur; m is 0 or 1; and n and n'can range from 0 to 3 said electronically active insulating polymers film being transparent, capable of facile transport of electrons which are injected into it upon photoexcitation of the contiguous photoconductive layer and incapable of substantial spectral response within the wavelength of spectral response of the photoconductive layer.

Claim 11

An electrophotographic imaging member having a composite photoconductive insulating film wherein on layer of said film has a thickness in the range of from about 0.2 to about 20 microns and comprises a photoconductive material capable of substantial spectral response in the visible region of the electromagnetic spectrum and a second layer which has a thickness in the range of from about 5 to about 100 microns and comprises an electronically active insulating polymer contiguous with said photoconductive layer, the ratio of thickness of said photoconductive layer to said transport layer being in the range of from about 1:2 to about 1:200, said electronically active insulating polymer comprising recurring structural units of the formula: ##STR3## wherein X is oxygen or dicyanomethylene; Y and Z are independently selected from the group consisting of No 2 , halogen --CN and --CF 3 ; R is a hydrocarbylene radical having from 1 to 10 carbon atoms; R' is oxygen or sulfur; m is 0 or 1; and n and n'can range from 0 to 3 said electronically active insulating polymers film being transparent, capable of facile transport of electrons which are injected into it upon photoexcitation of the contiguous photoconductive layer and incapable of substantial spectral response within the wavelength of spectral response of the photoconductive layer.

Claim 12

The imaging member of claim 9 wherein the electronically active insulating polymer is the product of the esterfication of ethylene glycol and 4,5-dinitrofluorenone-2,7-dicarboxylic acid chloride.

Claim 13

The imaging member of claim 9 wherein the electronically active insulating polymer is the product of the esterfication of 1,3-propane diol and 4,5-dinitrofluorenone-2,7-dicarboxylic acid chloride.

Claim 14

The imaging member of claim 9 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and 4,5-dinitrofluorenone-2,6-dicarboxylic acid chloride.

Claim 15

The imaging member of claim 9 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and 9-dicyanomethylene fluorene-2,7-dicarboxylic acid chloride.

Claim 16

The imaging member of claim 9 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and fluorenone-2,7-dicarboxylic acid chloride.

Claim 17

The imaging member of claim 9 wherein the electronically active insulating polymer is the product of the esterfication of 1,6-hexane diol and 4,5-dinitro-9-dicyanomethylene fluorenone-2,7-dicarboxylic acid chloride.

Claim 18

The imaging member of claim 9 wherein the electronically active insulating polymer is the product of the esterfication, of 1,2 eicosane-diol and 4,5-dinitrofluorenone-2,7-dicarboxylic acid chloride.

Claim 19

In an electrophotographic imaging process involving the sensitization and imagewise exposure of an electrophotographic imaging member having a composite photoconductive insulating layer comprising a layer of photoconductive material contiguous with a layer of change carrier transport material, the improvement comprising: providing an electrophotographic imaging member having a composite photoconductive insulating film wherein one layer of said film comprises a photoconductive material capable of substantial spectral response in the visible region of the electromagnetic spectrum and a second layer of electronically active insulating polymer contiguous with said photocondutive layer, said electronically active insulating polymer comprising recurring structural units of the formula: ##STR4## wherein X is oxygen or dicyanomethylene; Y and Z are independently selected from the group consisting of NO 2 , halogen, --CN and --CF 3 ; R is a hydrocarbylene radical having from 1 to 10 carbon atoms; R' is oxygen or sulfur; m is 0 to 1; and n and n'can range from 0 to 3 said electronically active insulating polymer film being transparent, capable of facile transport of electrons which are injected into it upon photoexcitation of the contiguous photoconductive layer and incapable of substantial spectral response within the wavelength of spectral response of the photoconductive layer.

Claim 20

In an electrophotographic imaging process involving the sensitization and imagewise exposure of an electrophotographic imaging member having a composite photoconductive insulating layer comprising a layer of photoconductive material contiguous with a layer of change carrier transport material, the improvement comprising: providing an electrophotographic imaging member having a composite photoconductive insulating film wherein one layer of said film comprises a photoconductive material capable of substantial spectral response in the visible region of the electromagnetic spectrum and a second layer of electronically active insulating polymer contiguous with said photocondutive layer, said electronically active insulating polymer comprising recurring structural units of the formula: ##STR4## wherein X is oxygen or dicyanomethylene; Y and Z are independently selected from the group consisting of NO 2 , halogen, --CN and --CF 3 ; R is a hydrocarbylene radical having from 1 to 10 carbon atoms; R' is oxygen or sulfur; m is 0 to 1; and n and n'can range from 0 to 3 said electronically active insulating polymer film being transparent, capable of facile transport of electrons which are injected into it upon photoexcitation of the contiguous photoconductive layer and incapable of substantial spectral response within the wavelength of spectral response of the photoconductive layer.

Claim 21

In an electrophotographic imaging process involving the sensitization and imagewise exposure of an electrophotographic imaging member having a composite photoconductive insulating layer comprising a layer of photoconductive material contiguous with a layer of charge carrier transport material, the improvement comprising: providing an electrophotographic imaging member having a composite photoconductive insulating film wherein one layer of said film has a thickness in the range of from about 0.2 to about 20 microns and comprises a photoconductive material capable of substantial spectral response in the visible region of the electromagnetic spectrum and a second layer which has a thickness in the range of from about 5 to about 100 microns and comprises an electronically active insulating polymer contiguous with said photoconductive layer, the ratio of thickness of said photoconductive layer to said transport layer being in the range of from about 1:2 to about 1:200, said electronically active insulating polymer comprising recurring structural units of the formula: ##STR5##wherein X is oxygen dicyanomethylene; Y and Z are independently selected from the group consisting of NO 2 , halogen --CN and --CF 3 ; R is hydrocarbylene radical having from 1 to 10 carbon atoms; R' is oxygen or sulfur; m is 0 or 1; and n and n'can range from 0 to 3 said electronically active insulating polymer film being transparent, capable of facile transport of electrons which are injected into it upon photoexcitation of the contiguous photoconductive layer and incapable of substantial spectral response within the wavelength of spectral response of the photoconductive layer.

Claim 22

In an electrophotographic imaging process involving the sensitization and imagewise exposure of an electrophotographic imaging member having a composite photoconductive insulating layer comprising a layer of photoconductive material contiguous with a layer of charge carrier transport material, the improvement comprising: providing an electrophotographic imaging member having a composite photoconductive insulating film wherein one layer of said film has a thickness in the range of from about 0.2 to about 20 microns and comprises a photoconductive material capable of substantial spectral response in the visible region of the electromagnetic spectrum and a second layer which has a thickness in the range of from about 5 to about 100 microns and comprises an electronically active insulating polymer contiguous with said photoconductive layer, the ratio of thickness of said photoconductive layer to said transport layer being in the range of from about 1:2 to about 1:200, said electronically active insulating polymer comprising recurring structural units of the formula: ##STR5##wherein X is oxygen dicyanomethylene; Y and Z are independently selected from the group consisting of NO 2 , halogen --CN and --CF 3 ; R is hydrocarbylene radical having from 1 to 10 carbon atoms; R' is oxygen or sulfur; m is 0 or 1; and n and n'can range from 0 to 3 said electronically active insulating polymer film being transparent, capable of facile transport of electrons which are injected into it upon photoexcitation of the contiguous photoconductive layer and incapable of substantial spectral response within the wavelength of spectral response of the photoconductive layer.