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US4011358A Expired / Lapsed US ⏱️ 0.0 years remaining

Article having a coextruded polyester support film

Assignee: 3M Co
•
Filing: 1974-07-23
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Granted: 1977-03-08
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Expires: 1994-07-23
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Abstract

Abstract Coated sheet material having a support film which comprises a biaxially oriented, heat-set coextruded laminate formed from two or more polyester polymers, one layer of the laminate being highly crystalline and the coated layer being tough and non-crystalline. Coatings which normally adhere poorly to a biaxially oriented heat-set highly crystalline monofilm adhere firmly to the laminate. Coated sheet products include pressure-sensitive adhesive tape, lithographic printing plates, splicing tapes, and coated abrasives.

Inventors

  • 👤 Glenn E. Roelofs

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 08:24
CPC Classifications
B; B32; B32B; B32B7/00; B32B7/02; B32B27/00; B32B27/06; B32B27/08; B24; B24D; B24D11/00; B24D11/06; B32B27/36; B32B7/04; B32B7/12; C; C09; C09J; C09J7/00; C09J7/20; C09J7/22; C09J7/30; C09J7/35; B32B2307/00; B32B2307/50; B32B2307/514; B32B2307/518; B32B2307/70; B32B2307/704; B32B2367/00; B32B2405/00; B32B2413/00; Y; Y10; Y10S; Y10S428/00; Y10S428/91; Y10T; Y10T428/00; Y10T428/16; Y10T428/163; Y10T428/164; Y10T428/166; Y10T428/167; Y10T428/19; Y10T428/28; Y10T428/2848; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31551; Y10T428/31565; Y10T428/31652; Y10T428/31663; Y10T428/31786; Y10T428/31855; Y10T428/3188; Y10T428/31884; Y10T428/31895; Y10T428/31909; Y10T428/31913; Y10T428/31917; Y10T428/3192; Y10T428/31924; Y10T428/31928

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 233 words
Composite coated sheet material comprising, in combination: 1. a biaxially oriented and heat-set coextruded support film consisting essentially of (A) a base layer of dimensionally stable crystalline first polyester selected from the group consisting of polyethylene terephthalate, polycyclohexane dimethyl terephthalate and polyethylene naphthalate (B) an adhesion-promoting layer having a thickness from about one-fourth of the total thickness of said support layer to about 1 mil thick of a second polyester having a minor degree of crystallinity between about 20° C and 230° C and melting at a temperature less than about 230° C wherein said adhesion-promoting layer is a polyester produced by the condensation reaction of a dicarboxylic acid component consisting of from about 10 to about 100 mole percent of a dicarboxylic acid selected from the group consisting of isophthalic acid, hexahydroterephthalic acid, sebaic acid, succinic acid, adipic acid, azelaic acid, suberic acid, pimelic acid, glutaric acid or mixtures thereof, or the diesters of such acids and correspondingly from 90 to zero mole percent of terephthalic acid, and a glycol component, in substantially equimolar proportions with the dicarboxylic acid component, wherein the glycol component is selected from the group consisting of polymethylene glycol of the formula HO(CH 2 ) n OH, wherein n is an integer of 2-10, neopentyl glycol, 1,4-cyclohexane dimethanol and bisphenol A; and 2. a coating of polymeric material firmly adherently bonded to the face of said (B) layer.
Claim 2
Dependent Claim 233 words
Composite coated sheet material comprising, in combination: 1. a biaxially oriented and heat-set coextruded support film consisting essentially of (A) a base layer of dimensionally stable crystalline first polyester selected from the group consisting of polyethylene terephthalate, polycyclohexane dimethyl terephthalate and polyethylene naphthalate (B) an adhesion-promoting layer having a thickness from about one-fourth of the total thickness of said support layer to about 1 mil thick of a second polyester having a minor degree of crystallinity between about 20° C and 230° C and melting at a temperature less than about 230° C wherein said adhesion-promoting layer is a polyester produced by the condensation reaction of a dicarboxylic acid component consisting of from about 10 to about 100 mole percent of a dicarboxylic acid selected from the group consisting of isophthalic acid, hexahydroterephthalic acid, sebaic acid, succinic acid, adipic acid, azelaic acid, suberic acid, pimelic acid, glutaric acid or mixtures thereof, or the diesters of such acids and correspondingly from 90 to zero mole percent of terephthalic acid, and a glycol component, in substantially equimolar proportions with the dicarboxylic acid component, wherein the glycol component is selected from the group consisting of polymethylene glycol of the formula HO(CH 2 ) n OH, wherein n is an integer of 2-10, neopentyl glycol, 1,4-cyclohexane dimethanol and bisphenol A; and 2. a coating of polymeric material firmly adherently bonded to the face of said (B) layer.
Claim 3
Dependent Claim 43 words
The article of claim 1 wherein said polymeric material is selected from the group consisting of polyurethane, ethylene:vinyl acetate polymer, acrylate polymer, phenolic resins, phenolic/rubbery resin mixtures, epoxy resins, vinyl chloride/vinyl acetate polymer compositions, styrene/acrylonitrile polymer compositions, and cellulose acetate butyrate polymer compositions.
Claim 4
Dependent Claim 13 words
The article of claim 1 wherein said polymeric material is a pressure-sensitive adhesive.
Claim 5
Dependent Claim 14 words
The article of claim 3 wherein said pressure-sensitive adhesive is an acrylate/acrylic acid copolymer.
Claim 6
Dependent Claim 17 words
The article of claim 1 wherein said polymeric material is a mixture of abrasive particles and binder.
Claim 7
Dependent Claim 12 words
The article of claim 5 wherein said binder is a phenolic resin.
Claim 8
Dependent Claim 13 words
The article of claim 1 wherein said polymeric material is a thermosetting adhesive.
Claim 9
Dependent Claim 11 words
The article of claim 7 wherein said thermosetting adhesive is polyurethane.
Claim 10
Dependent Claim 13 words
The article of claim 1 wherein said polymeric layer is a light-sensitive layer.
Claim 11
Dependent Claim 92 words
A composite coated sheet material comprising, in combination: 1. a biaxially oriented and heat-set coextruded support film consisting essentially of a dimensionally stable crystalline polyethylene terephthalate base layer and an adhesion-promoting layer having a thickness from about one-fourth of the total thickness of said support film to about 1 mil thick of poly(ethylene isophthalate/terephthalate), wherein the terephthalate:isophthalate molar proportion varies from 100% isophthalate and correspondingly no terephthalate to 10% isophthalate and correspondingly 90% terephthalate and 2. a coating of polymeric material firmly adherently bonded to the face of said adhesion promoting layer.
Claim 12
Dependent Claim 92 words
A composite coated sheet material comprising, in combination: 1. a biaxially oriented and heat-set coextruded support film consisting essentially of a dimensionally stable crystalline polyethylene terephthalate base layer and an adhesion-promoting layer having a thickness from about one-fourth of the total thickness of said support film to about 1 mil thick of poly(ethylene isophthalate/terephthalate), wherein the terephthalate:isophthalate molar proportion varies from 100% isophthalate and correspondingly no terephthalate to 10% isophthalate and correspondingly 90% terephthalate and 2. a coating of polymeric material firmly adherently bonded to the face of said adhesion promoting layer.
Claim 13
Dependent Claim 23 words
The composite coated sheet material of claim 10 wherein said isophthalate molar proportion is 20% and said terephthalate molar proportion is correspondingly 80%.
Claim 14
Dependent Claim 14 words
A composite coated sheet material of claim 11 wherein the polymeric material is polyurethane.

References Cited (Backward Citations)

US2961365A Cited
US3337364A Cited
US3515626A Cited
US3617352A Cited
US3607616A Cited
US3607354A Cited
US3767523A Cited
US3900653A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-07 1980-09-06 1981-03-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-07 1984-09-06 1985-03-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-07 1988-09-06 1989-03-08 $7700.00 Window Closed / Lapsed

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