US4011298A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for simultaneous removal of SOx and NOx
Assignee: Chiyoda Corp
•
Filing: 1974-12-16
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Granted: 1977-03-08
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Expires: 1994-12-16
Abstract
Abstract Waste gas containing sulfur oxide (SO x ) and nitrogen oxide (NO x ) is mixed with an ozone-containing gas to have the value x of NO x fall in the range of 1.2 to 2.5 and thereafter brought into contact with an aqueous solution containing sulfuric acid, nitric acid and an iron compound to be deprived of SO x and NO x . To the solution with which the waste gas has been brought into contact, air or oxygen is added to effect oxidation of the part of said oxides still remaining therein in an unoxidized state and regenerate the activity of the iron compound functioning as a catalyst. Part of the solution to which the addition of air or oxygen has been made is recycled as the solution for the purpose of contact with waste gas.
Inventors
- 👤 Suguru Fukui
- 👤 Haruo Nishino
- 👤 Yohji Kameoka
- 👤 Junichi Miyazaki
- 👤 Toshio Kuroda
- 👤 Shinichi Konishi
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-02 06:59
CPC Classifications
B; B01; B01D; B01D53/00; B01D53/34
Claims Analysis
Total Claims: 5
Claim 1
Independent Claim
258 words
A method fo simultaneous removal of SO x and NO x from the waste gas containing said oxides, which method comprises the steps of: A. adding an ozone-containing gas to said waste gas at temperatures between about 15° C and about 100° C to oxidize the NO x so that the value x in NO x in the waste gas is in the range of 1.2 to 2.5, B. bringing said waste gas which has undergone treatment in step (A) into contact in a first zone with a solution containing sulfuric acid, nitric acid and ferric ion as a catalyst to remove SO x and NO x from said waste gas, said ferric ion content being in the range of from about 50 to 6,000 ppm by weight, and said nitric acid and sulfuric acid content bent being in the range of from about 0.05 to about 4% and from about 0.5 to about 10% respectively, C. passing said solution resulting from step (B) from said first zone to a second zone, D. introducing air or oxygen into the solution passed to said second zone in step (C) to effect oxidation of said SO x and NO x and activate the catalyst in said solution, E. recycling the solution of the second zone into contact with waste gas in the first zone thereby establishing a circulation system between the first zone and second zone, F. removing part of the solution from the circulation system, and G. supplying make up water and make up catalyst to said circulation system.
Claim 2
Independent Claim
258 words
A method fo simultaneous removal of SO x and NO x from the waste gas containing said oxides, which method comprises the steps of: A. adding an ozone-containing gas to said waste gas at temperatures between about 15° C and about 100° C to oxidize the NO x so that the value x in NO x in the waste gas is in the range of 1.2 to 2.5, B. bringing said waste gas which has undergone treatment in step (A) into contact in a first zone with a solution containing sulfuric acid, nitric acid and ferric ion as a catalyst to remove SO x and NO x from said waste gas, said ferric ion content being in the range of from about 50 to 6,000 ppm by weight, and said nitric acid and sulfuric acid content bent being in the range of from about 0.05 to about 4% and from about 0.5 to about 10% respectively, C. passing said solution resulting from step (B) from said first zone to a second zone, D. introducing air or oxygen into the solution passed to said second zone in step (C) to effect oxidation of said SO x and NO x and activate the catalyst in said solution, E. recycling the solution of the second zone into contact with waste gas in the first zone thereby establishing a circulation system between the first zone and second zone, F. removing part of the solution from the circulation system, and G. supplying make up water and make up catalyst to said circulation system.
Claim 3
Dependent Claim
27 words
The method of claim 1, wherein said ferric ion is obtained from at least one member selected from the group consisting of iron sulfate and iron nitrate.
Claim 4
Dependent Claim
40 words
The method of claim 1, wherein the part of the solution removed from the circulation system is treated with lime to have the contained sulfuric acid converted into gypsum, and the formed gypsum is recovered by separation from the gypsum-slurry.
Claim 5
Dependent Claim
27 words
The method of claim 3, wherein the mother liquid remaining after the removal of gypsum is returned to the absorption solution for use in the first zone.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-07 | 1980-09-06 | 1981-03-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-07 | 1984-09-06 | 1985-03-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-07 | 1988-09-06 | 1989-03-08 | $7700.00 | Window Closed / Lapsed |