← Back to Patent Explorer
US4011291A Expired / Lapsed US ⏱️ 0.0 years remaining

Apparatus and method of manufacture of articles containing controlled amounts of binder

Assignee: Vesuvius Crucible Co
•
Filing: 1975-09-02
•
Granted: 1977-03-08
•
Expires: 1995-09-02
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A method of forming articles containing a controlled amount of binder, i.e., a presintered ceramic article, utilizes mixing of base materials with a meltable binder such as paraffin wax. The mixture is then formed, as a slurry, into the configuration of the article and is allowed to solidify. The solidified mixture is then packed into a binder-absorptive material and controllably heated above the melting point of the binder but below the vaporization point of the binder. The excess binder in the material is drawn from the solidified mixture by wicking action. Subsequently, if the mixture is to form a sintered ceramic article, the solidified mixture is fired to a desired property.

Inventors

  • 👤 James D. Curry

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 23:34
CPC Classifications
B; B28; B28B; B28B1/00; B22; B22F; B22F3/00; B22F3/10; B22F3/1017; B22F3/1021; B22F3/1025; C; C04; C04B; C04B35/00; C04B35/622; C04B35/626; C04B35/63; C04B35/632; C04B35/638; C04B35/64

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 221 words
In a method of forming ceramic products containing a controlled amount of meltable binder comprising forming a mixture of a melted meltable wax binder which is solid at room temperature and ceramic forming base materials into a solid article of desired configuration by allowing said mixture to solidify in a mold, the improvement in said method comprising the steps of: packing said article into a binder-absorptive material for absorbing said binder when it is converted to a liquid state wherein said binder has a melting point less than the temperature at which said base material is undesirably heat altered and wherein said binder absorptive material has a melting point greater than the melting point of the binder, is non-reactive with said binder, and has a sufficiently small particle size so as to not yield imperfections when contacting the solidified mixture and elevating and maintaining the temperature of said article above the melting point of the meltable binder but below the vaporization temperature of said binder causing said binder to become liquid and allowing said binder to be drawn from said article into said binder-absorptive material by a wicking action until at least 45% of said binder is wicked out of said article and into said binder absorptive material; and thereafter firing said article in a kiln to produce a ceramic product.
Claim 2
Dependent Claim 221 words
In a method of forming ceramic products containing a controlled amount of meltable binder comprising forming a mixture of a melted meltable wax binder which is solid at room temperature and ceramic forming base materials into a solid article of desired configuration by allowing said mixture to solidify in a mold, the improvement in said method comprising the steps of: packing said article into a binder-absorptive material for absorbing said binder when it is converted to a liquid state wherein said binder has a melting point less than the temperature at which said base material is undesirably heat altered and wherein said binder absorptive material has a melting point greater than the melting point of the binder, is non-reactive with said binder, and has a sufficiently small particle size so as to not yield imperfections when contacting the solidified mixture and elevating and maintaining the temperature of said article above the melting point of the meltable binder but below the vaporization temperature of said binder causing said binder to become liquid and allowing said binder to be drawn from said article into said binder-absorptive material by a wicking action until at least 45% of said binder is wicked out of said article and into said binder absorptive material; and thereafter firing said article in a kiln to produce a ceramic product.
Claim 3
Dependent Claim 109 words
The method of claim 1 in which said step of forming said article comprises: forming a relatively thick walled article having a wall thickness of at least 1/2 inch; said step of elevating and maintaining the temperature of said article above the melting point of the meltable binder and below the vaporization temperature thereof is conducted until at least about 65% of said binder is wicked out of said article and into said binder absorptive material; and said method includes removing said article from said binder absorptive material after said wicking of at least about 65% of said binder out of said article and thereafter performing said firing step.
Claim 4
Dependent Claim 211 words
In a method of forming metal products containing a controlled amount of binder comprising forming a mixture of a melted meltable wax binder which is solid at room temperature and metal forming base materials into a solid article of desired configuration by allowing said mixture to solidify in a mold, the improvement in said method comprising the steps of: packing said article into a binder-absorptive material for absorbing said binder when it is converted to a liquid state wherein said binder has a melting point less than the temperature at which said base material is undesirably heat altered and wherein said binder absorptive material has a melting point greater than that of the binder, is non-reactive with said binder, and has a sufficiently small particle size so as to not yield imperfections when contacting the solidified mixture; and elevating and maintaining the temperature of said article above the melting point of the meltable binder but below the vaporization temperatures of said binder, causing said binder to be drawn from said article into said binder absorptive material by wicking action until at least 45% of said binder is wicked out of said article and into said binder absorptive material; and thereafter firing said article in a kiln to produce a metal product.
Claim 5
Dependent Claim 211 words
In a method of forming metal products containing a controlled amount of binder comprising forming a mixture of a melted meltable wax binder which is solid at room temperature and metal forming base materials into a solid article of desired configuration by allowing said mixture to solidify in a mold, the improvement in said method comprising the steps of: packing said article into a binder-absorptive material for absorbing said binder when it is converted to a liquid state wherein said binder has a melting point less than the temperature at which said base material is undesirably heat altered and wherein said binder absorptive material has a melting point greater than that of the binder, is non-reactive with said binder, and has a sufficiently small particle size so as to not yield imperfections when contacting the solidified mixture; and elevating and maintaining the temperature of said article above the melting point of the meltable binder but below the vaporization temperatures of said binder, causing said binder to be drawn from said article into said binder absorptive material by wicking action until at least 45% of said binder is wicked out of said article and into said binder absorptive material; and thereafter firing said article in a kiln to produce a metal product.
Claim 6
Dependent Claim 13 words
The method of claim 2 wherein said meltable binder is a paraffinic wax.
Claim 7
Dependent Claim 25 words
The method of claim 2 wherein said base material and said meltable binder are mixed in the presence of a surfactant and under a vacuum.
Claim 8
Dependent Claim 14 words
The method of claim 2 wherein said forming step comprises low pressure injection molding.
Claim 9
Dependent Claim 31 words
The method of claim 2 wherein said binder-absorptive material consists essentially of granular, inorganic solids, said solids having a melting point greater than the sintering temperature of said ceramic base material.
Claim 10
Dependent Claim 92 words
The method of claim 1 which further comprises unpacking said article from said binder-absorptive material prior to said firing step and after said step of elevating and maintaining the temperature above the melting point of said binder and below the vaporization temperature thereof; regenerating said binder-absorptive material after removal of said article by heating said binder-absorptive material to a temperature greater than the temperature at which said binder will volatilize; and recycling said regenerated binder-absorptive material as a source of binder-absorptive material for repeating the method on subsequent ones of said article.
Claim 11
Independent Claim 189 words
A method of forming sintered ceramic products of predetermined form comprising batching a mixture of a granular ceramic material capable of being sintered with a melted paraffinic wax binder and a surfactant and casting said mixture into a solid green piece, the improvement in said method comprising: closely packing said green piece into a paraffinic wax absorptive material wherein said binder has a melting point less than the temperature at which said base material is undesirably heat altered and wherein said binder absorptive material has a melting point greater than the melting point of the binder, is non-reactive with said binder, and has a sufficiently small particle size so as to not yield imperfections when contacting the solidified mixture for drawing liquid paraffinic wax from said green piece; and below the vaporization temperature of said paraffinic wax binder for a period of time to allow at least about 45% to 65% of said paraffinic wax binder in its liquid state to be drawn from said green piece into said absorptive material by a wicking action; and removing said green piece from said absorptive material and firing said green piece.
Claim 12
Independent Claim 189 words
A method of forming sintered ceramic products of predetermined form comprising batching a mixture of a granular ceramic material capable of being sintered with a melted paraffinic wax binder and a surfactant and casting said mixture into a solid green piece, the improvement in said method comprising: closely packing said green piece into a paraffinic wax absorptive material wherein said binder has a melting point less than the temperature at which said base material is undesirably heat altered and wherein said binder absorptive material has a melting point greater than the melting point of the binder, is non-reactive with said binder, and has a sufficiently small particle size so as to not yield imperfections when contacting the solidified mixture for drawing liquid paraffinic wax from said green piece; and below the vaporization temperature of said paraffinic wax binder for a period of time to allow at least about 45% to 65% of said paraffinic wax binder in its liquid state to be drawn from said green piece into said absorptive material by a wicking action; and removing said green piece from said absorptive material and firing said green piece.
Claim 13
Dependent Claim 53 words
The method of claim 1 in which said step of elevating and maintaining the temperature of said article above the melting point of the meltable binder and below the vaporization temperature thereof is conducted until at least about 65% of said binder is wicked out of said article and into said binder-absorptive material.
Claim 14
Dependent Claim 36 words
The method of claim 1 in which said article is removed from said binder-absorptive material after said wicking of at least about 45% of said binder out of said article, and thereafter performing said firing step.
Claim 15
Dependent Claim 12 words
The method of claim 1 wherein said wax binder is paraffinic wax.
Claim 16
Dependent Claim 32 words
The method of claim 12 wherein said binder-absorptive material consists essentially of particles of inorganic solids, said solids having a melting point greater than the sintering temperature of said ceramic base material.

References Cited (Backward Citations)

US3285873A Cited
US3351688A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1980-03-07 1980-09-06 1981-03-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1984-03-07 1984-09-06 1985-03-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1988-03-07 1988-09-06 1989-03-08 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag