Conversion of modified synthesis gas to oxygenated organic chemicals

Claim 1

In the process of converting synthesis gas to gasoline boiling range hydrocarbons by the sequential steps of converting said synthesis gas to a product comprising predominantly methanol and then converting at least the methanol portion of this product to gasoline boiling range hydrocarbons by contact thereof with a crystalline aluminosilicate zeolite having a silica to alumina ratio of at least about 12, a constraint index of 1 to 12 and a crystal density of not substantially below about 1.6 grams per cubic centimeter, at a temperature of at least about 500° F; the improvement, whereby increasing the proportion of synthesis gas converted to said product comprising predominantly methanol and dimethyl ether available for conversion to gasoline boiling range hydrocarbons by contact with said zeolite, which comprises adjusting the hydrogen-carbon monoxide mole ratio in said synthesis gas to about 0.8 to 1.7, which is a hydrogen deficiency with respect to methanol stoichiometry; converting said hydrogen deficient synthesis gas, at elevated pressures of about 500 to 4000 psig, space velocity of about 10,000 hv.sup. -1 to 40,000 hv.sup. -1 and temperatures of about 400 to 570° F in contact with a solid metallic methanol synthesis catalyst having a solid acid component incorporated therewith, to a product comprising a high ratio of dimethyl ether to methanol and representing a high conversion of synthesis gas thereto; and converting at least said dimethyl ether and methanol to gasoline boiling range hydrocarbons as aforesaid.