US4011167A
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Lubricant compositions containing metal complexes as detergents
Assignee: Mobil Oil AS
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Filing: 1975-07-09
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Granted: 1977-03-08
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Expires: 1995-07-09
Abstract
Abstract Lubricant compositions are provided containing a detergency improving amount of a metal complex prepared by (a) reacting a salt or oxide of a metal capable of forming a Werner complex with a compound containing at least one phenolic group to yield the metal salt of said compound; (b) reacting the resulting metal salt with a polyamine having the formula H 2 N(C 2 H 4 NH) x H where x is 1 to 5; and (c) reacting the resulting product with an alkenylsuccinic anhydride characterized by a molecular weight between about 400 and about 3,000.
Inventors
- 👤 Sheldon Chibnik
- 👤 Ferdinand P. Otto
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 07:42
CPC Classifications
C; C10; C10M; C10M159/00; C10M159/12; C10M159/18; C10M2205/00; C10M2205/02; C10M2205/026; C10M2205/028; C10M2207/00; C10M2207/02; C10M2207/023; C10M2207/027; C10M2207/04; C10M2207/28; C10M2207/281; C10M2207/282; C10M2207/283; C10M2207/286; C10M2207/34; C10M2209/00; C10M2209/02; C10M2209/08; C10M2209/084; C10M2209/10; C10M2209/103; C10M2209/104; C10M2209/105; C10M2215/00; C10M2215/02; C10M2215/04; C10M2215/086; C10M2215/10; C10M2215/102; C10M2215/22; C10M2215/221; C10M2215/225; C10M2215/226; C10M2215/24; C10M2215/26; C10M2215/28; C10M2215/30; C10M2217/00; C10M2217/04; C10M2217/046; C10M2217/06; C10M2219/00; C10M2219/04; C10M2219/044; C10M2219/08; C10M2219/082; C10M2219/087; C10M2219/088; C10M2219/089; C10M2223/00; C10M2223/02; C10M2223/04; C10M2223/042; C10M2223/045; C10M2227/00; C10M2227/02; C10M2227/04; C10M2227/08; C10M2227/081; C10N; C10N2010/00; C10N2010/04; C10N2010/08; C10N2010/14; C10N2010/16; C10N2050/00; C10N2050/10
Claims Analysis
Total Claims: 14
Claim 1
Independent Claim
209 words
A lubricant composition comprising a major proportion of a base oil selected from the group consisting of oils lubricating viscosity and grease thereof and a minor amount sufficient to improve detergency properties thereof of a metal complex prepared by (a) reacting a metal compound capable of forming a Werner complex selected from the group consisting essentially of zinc oxide, zinc carbonate, zinc acetate, zinc nitrate, nickel acetate, and nickel carbonate, at a temperature of from about 40° to about 150° C with a phenolic compound selected from the group consisting essentially of alkyl phenols containing from about 4 to about 30 carbon atoms, the reaction product of said alkyl phenols and a sulfur halide, dimers of said alkyl phenols, and said alkyl phenols which have been crosslinked with an aldehyde, to yield the metal salt of said phenolic compound; (b) reacting the resulting metal salt at a temperature of from about 25° to about 250° C with a polyamine having the formula H 2 N(C 2 H 4 NH) x H where x is 1 to 5; and (c) reacting the resulting product at a temperature of from about 70° to about 250° C with an alkenylsuccinic anhydride characterized by a molecular weight between about 400 and about 3,000.
Claim 2
Dependent Claim
209 words
A lubricant composition comprising a major proportion of a base oil selected from the group consisting of oils lubricating viscosity and grease thereof and a minor amount sufficient to improve detergency properties thereof of a metal complex prepared by (a) reacting a metal compound capable of forming a Werner complex selected from the group consisting essentially of zinc oxide, zinc carbonate, zinc acetate, zinc nitrate, nickel acetate, and nickel carbonate, at a temperature of from about 40° to about 150° C with a phenolic compound selected from the group consisting essentially of alkyl phenols containing from about 4 to about 30 carbon atoms, the reaction product of said alkyl phenols and a sulfur halide, dimers of said alkyl phenols, and said alkyl phenols which have been crosslinked with an aldehyde, to yield the metal salt of said phenolic compound; (b) reacting the resulting metal salt at a temperature of from about 25° to about 250° C with a polyamine having the formula H 2 N(C 2 H 4 NH) x H where x is 1 to 5; and (c) reacting the resulting product at a temperature of from about 70° to about 250° C with an alkenylsuccinic anhydride characterized by a molecular weight between about 400 and about 3,000.
Claim 3
Dependent Claim
33 words
The lubricant composition of claim 1 wherein said alkenylsuccinic anhydride has the following general structure: ##STR5## wherein R is a hydrocarbon selected from the group consisting essentially of polypropylene, polyisobutylene, and ethylenepropylene copolymer.
Claim 4
Dependent Claim
45 words
The lubricant composition of claim 1 wherein the phenolic compound is the reaction product of said alkyl phenol and a sulfur halide to form a product of the formula: ##STR6## where R is an alkyl group containing from about 4 to about 30 carbon atoms.
Claim 5
Dependent Claim
38 words
The lubricant composition of claim 1 wherein the phenolic compound comprises alkyl phenols which have been dimerized to materials of the formula: ##STR7## where R is an alkyl group containing from about 4 to about 30 carbon atoms.
Claim 6
Dependent Claim
38 words
The lubricant composition of claim 1 wherein the phenolic compound has been crosslinked by reaction with aldehydes to compounds of the formula: ##STR8## where R is an alkyl group containing from about 4 to about 30 carbon atoms.
Claim 7
Dependent Claim
20 words
The lubricant composition of claim 1 wherein said alkenylsuccinic anhydride has a molecular weight from about 700 to about 2,500.
Claim 8
Dependent Claim
16 words
The lubricant composition of claim 1 wherein said base oil comprises an oil of lubricating viscosity.
Claim 9
Dependent Claim
13 words
The lubricant composition of claim 1 wherein said base oil comprises a grease.
Claim 10
Dependent Claim
25 words
The lubricant composition of claim 1 wherein said detergency improving metal complex is present in an amount from about 0.001% to about 20%, by weight.
Claim 11
Dependent Claim
25 words
The lubricant composition of claim 1 wherein said detergency improving metal complex is present in an amount from about 1% to about 10%, by weight.
Claim 12
Dependent Claim
179 words
A metal complex of an alkylsuccinimide prepared by (a) reacting a metal compound capable of forming a Werner complex selected from the group consisting essentially of zinc oxide, zinc carbonate, zinc acetate, zince nitrate, nickel acetate, and nickel carbonate, at a temperature of from about 40° to about 150° C, with a phenolic compound selected from the group consisting essentially of alkyl phenols containing from about 4 to about 30 carbon atoms, the reaction product of said alkyl phenols and a sulfur halide, dimers of said alkyl phenols, and said alkyl phenols which have been crosslinked with an aldehyde, to yield the metal salt of said phenolic compound; (b) reacting the resulting metal salt at a temperature of from about 25° to about 250° C with a polyamine having the formula H 2 N(C 2 H 4 NH) x H where x is 1 to 5; and (c) reacting the resulting product at a temperature of from about 70° to about 250° C with said alkenylsuccinic anhydride further characterized by a molecular weight between about 400 and about 3,000.
Claim 13
Dependent Claim
179 words
A metal complex of an alkylsuccinimide prepared by (a) reacting a metal compound capable of forming a Werner complex selected from the group consisting essentially of zinc oxide, zinc carbonate, zinc acetate, zince nitrate, nickel acetate, and nickel carbonate, at a temperature of from about 40° to about 150° C, with a phenolic compound selected from the group consisting essentially of alkyl phenols containing from about 4 to about 30 carbon atoms, the reaction product of said alkyl phenols and a sulfur halide, dimers of said alkyl phenols, and said alkyl phenols which have been crosslinked with an aldehyde, to yield the metal salt of said phenolic compound; (b) reacting the resulting metal salt at a temperature of from about 25° to about 250° C with a polyamine having the formula H 2 N(C 2 H 4 NH) x H where x is 1 to 5; and (c) reacting the resulting product at a temperature of from about 70° to about 250° C with said alkenylsuccinic anhydride further characterized by a molecular weight between about 400 and about 3,000.
Claim 14
Dependent Claim
21 words
The metal complex defined by claim 11 wherein said alkenylsuccinic anhydride has a molecular weight from about 700 to about 2,500.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1980-03-07 | 1980-09-06 | 1981-03-08 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1984-03-07 | 1984-09-06 | 1985-03-08 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1988-03-07 | 1988-09-06 | 1989-03-08 | $7700.00 | Window Closed / Lapsed |